MSDS for 1,3-Dibutylimidazolium Chloride

Identification

Product Name: 1,3-Dibutylimidazolium Chloride
Chemical Family: Imidazolium-based ionic liquid
Synonyms: [Bbuim]Cl, Dibutylimidazolium chloride
CAS Number: 144089-75-0
Recommended Use: Solvent, research chemical, electrochemical applications
Supplier Information: Manufacturer details available on request
Emergency Contact: Local emergency response services or regional poison control center

Hazard Identification

GHS Classification: Not classified as hazardous under GHS guidelines
Physical Hazards: Can create slippery surfaces if spilled; not highly flammable
Health Hazards: Eye irritant, may cause discomfort on skin contact, inhalation of dust or aerosol may irritate respiratory tract
Environmental Hazards: Harmful to aquatic organisms if released in larger quantities, persistent in the environment
Signal Word: Warning
Hazard Statements: Causes mild skin irritation, serious eye irritation possible, inhalation of dust may result in mild respiratory irritation
Precautionary Statements: Avoid breathing dust, wash hands after handling, avoid discharge to the environment

Composition / Information on Ingredients

Chemical Name: 1,3-Dibutylimidazolium Chloride
Common Name: [Bbuim]Cl
CAS Number: 144089-75-0
Concentration: >99%
Impurities: Minor imidazole derivatives, residual solvents ← present at less than 1%
Additives: No additives purposely present

First Aid Measures

Inhalation: Move person to fresh air, support breathing if required, seek medical attention if breathing becomes difficult
Skin Contact: Remove any contaminated clothing, rinse skin immediately with plenty of water, wash thoroughly with soap, seek medical advice if irritation develops
Eye Contact: Rinse cautiously with water for several minutes, remove contact lenses if present and easy to do, continue rinsing, seek medical attention for persistent discomfort
Ingestion: Rinse mouth thoroughly, seek medical help; do not induce vomiting unless instructed by medical personnel
Symptoms: Eye stinging, skin dryness or redness, irritation in nose or throat after inhalation

Fire-Fighting Measures

Suitable Extinguishing Media: Foam, dry chemical, carbon dioxide, water spray—not a combustible substance but assist with extinguishing packaging or nearby combustibles
Hazards from Combustion: Hydrogen chloride, nitrogen oxides, small amounts of carbon monoxide and carbon dioxide
Protective Equipment: Wear self-contained breathing apparatus and full protective gear, keep upwind of fire
Special Procedures: Keep containers cool using water fog, prevent contaminated runoff from entering drains or waterways

Accidental Release Measures

Personal Protection: Wear gloves, chemical safety goggles, protective clothing, avoid breathing dust
Spill Cleanup: Evacuate area if large spill, avoid dust creation, collect spilled material in suitable, labeled container for disposal
Environmental Precautions: Prevent entry to waterways, storm drains, or soil; alert authorities if significant quantities enter environment
Decontamination: Clean spill area with water and mild detergent, contain water used for cleaning, avoid discharge into environment

Handling and Storage

Handling Advice: Handle with care to prevent accidental release or exposure, ensure good ventilation, avoid contact with skin, eyes, and clothing, do not eat, drink or smoke during use
Storage Conditions: Store in cool, dry, well-ventilated area, away from sources of ignition, oxidizers, and incompatible substances such as strong acids and bases
Container Requirements: Use tightly sealed, compatible containers, label containers clearly
Special Precautions: Inspect storage containers regularly for leaks or damage, store away from direct sunlight and moisture

Exposure Controls and Personal Protection

Exposure Limits: No occupational exposure limits established
Engineering Controls: Use local exhaust or general ventilation to control airborne concentrations
Personal Protective Equipment: Chemical-resistant gloves (nitrile or PVC), safety goggles with side shields, long-sleeved garment or lab coat, use a NIOSH-approved respirator for dust if ventilation is inadequate
Hygiene Measures: Wash hands and face after usage, remove contaminated clothing before meals, avoid touching face or exposed skin during handling

Physical and Chemical Properties

Appearance: White to off-white crystalline solid
Odor: Slight, faintly aromatic
Odor Threshold: Not available
pH: Slightly acidic to neutral aqueous solution
Melting Point: 55-65°C
Boiling Point: Decomposes before boiling
Flash Point: Not flammable
Evaporation Rate: Negligible
Flammability: Not classified as flammable
Vapor Pressure: Very low at room temperature
Solubility: Soluble in water and polar organic solvents
Partition Coefficient: Not established
Density: Around 1.05-1.20 g/cm³
Viscosity: Not available
Other Properties: Hygroscopic, absorbs moisture from air

Stability and Reactivity

Chemical Stability: Stable under normal storage and use conditions
Conditions to Avoid: Moisture, excessive heat, open flame, strong oxidizing or reducing agents
Incompatible Materials: Strong acids, strong bases, oxidizing and reducing agents
Hazardous Decomposition: Hydrogen chloride, nitrogen oxides, carbon monoxide, carbon dioxide on combustion
Polymerization: Does not occur under normal conditions

Toxicological Information

Acute Toxicity: Oral, dermal, and inhalation routes have low toxicity; specific data limited but not expected to pose serious acute effects in small doses
Skin Contact: May cause mild irritation, redness, dryness
Eye Contact: Causes discomfort or irritation, potential risk of temporary inflammation
Ingestion: May cause sore throat, nausea, or stomach upset
Chronic Exposure: No evidence of carcinogenic, mutagenic, or reproductive toxicity; long-term exposure still not fully tested
Sensitization: Not expected to cause skin sensitization based on structure
Medical Conditions Aggravated: Pre-existing dermatitis or respiratory conditions may worsen upon repeated exposure

Ecological Information

Ecotoxicity: Chronic exposure can present a hazard to aquatic environments, particularly invertebrates and algae
Persistence: Not readily biodegradable, persists in water and soil
Bioaccumulation: Low likelihood based on molecular structure, but data lacking
Mobility: Readily dissolves in water, potential for migration in soil
Other Adverse Effects: May disrupt aquatic biological processes in significant concentrations; avoid uncontrolled release

Disposal Considerations

Disposal Methods: Dispose of contents/container according to local, regional, national, and international regulations
Product Waste: Collect unused or contaminated material in sealed, labeled containers
Container Disposal: Do not reuse packaging, triple rinse and render unserviceable before landfill or incineration at approved facility
Special Instructions: Notify authorities in case of large or uncontrolled release; do not discard material in sewer or open environment

Transport Information

UN Number: Not regulated as dangerous goods for transport
Proper Shipping Name: Chemical, not otherwise specified
Transport Hazard Class: Not classified
Packing Group: Not applicable
Marine Pollutant: Not classified, but bulk shipments should avoid water release
Special Precautions: Prevent container damage during transport, secure upright and avoid tilting

Regulatory Information

TSCA: Listed or meets criteria
REACH Status: Registration details available for European Economic Area
SARA Title III: Not subject to reporting requirements
WHMIS Classification: Not regulated under Canadian WHMIS
OSHA: Not specifically regulated
Other Regulatory Status: No known restrictions on usage except standard chemical safety requirements; local regulations may apply