Material Safety Data Sheet: 1,3-Ditetradecylimidazolium Bromide

Identification

Product Name: 1,3-Ditetradecylimidazolium Bromide
Chemical Formula: C34H71BrN2
CAS Number: 369438-35-3
Synonyms: Imidazolium, 1,3-ditetradecyl-, bromide
Recommended Use: Laboratory chemical, research and development
Supplier Details: Supplier contact address, phone, and emergency contact number must appear here
Emergency Number: Local emergency or poison control center number for accidents and spills

Hazard Identification

Hazard Classification: Eye irritation Category 2, Skin irritation Category 3, Specific target organ toxicity (single exposure) Category 3, Aquatic chronic toxicity Category 2
Label Elements: Signal word “Warning”; hazard statements highlight skin/eye irritant characteristics, with specific pictograms for acute toxicity and aquatic hazard
Precautionary Statements: Avoid breathing dust or vapors, wash hands and face after handling, avoid release into environment, wear gloves, protective clothing, and eye protection
Hazard Pictograms: Exclamation mark, Environment
Health Hazards: Can cause redness, itching, swelling or irritation after skin or eye contact, may affect organs after inhalation of high concentrations, can irritate respiratory tract
Environmental Hazards: Toxic to aquatic life with prolonged effects, large spills can damage local water ecosystems
Fire Hazards: May emit toxic fumes of nitrogen oxides, hydrogen bromide, and carbon oxides if involved in fire

Composition / Information on Ingredients

Chemical Name: 1,3-Ditetradecylimidazolium Bromide
CAS Number: 369438-35-3
Concentration: ≥99% (by weight)
Other Ingredients: None known—no additional substances intentionally added
Impurities and Stabilizing Additives: Minimal levels of residual solvents as byproducts from synthesis may exist

First Aid Measures

Eye Contact: Rinse eyes cautiously with gentle water stream for at least 15 minutes, remove contact lenses, continue rinsing if irritation persists, seek medical advice if problems continue
Skin Contact: Remove contaminated clothing, wash skin thoroughly with soap and water, consult a health specialist if irritation or rash occurs
Inhalation: Move person to fresh air, keep individual comfortable for breathing, seek medical help for persistent symptoms like coughing, difficulty breathing, or chest pain
Ingestion: Rinse mouth thoroughly, do not induce vomiting, obtain immediate medical help, show label or container to responders
Most Important Symptoms: Eye redness, skin irritation, possible dizziness or breathing difficulty
Immediate Medical Attention: Necessary for severe eye exposure, breathing trouble, or if large amount is swallowed

Fire-Fighting Measures

Suitable Extinguishing Media: Use carbon dioxide, dry chemical powder, foam; large fires may require water spray to cool surfaces
Special Hazards: Can release nitrogen oxides, hydrogen bromide, carbon monoxide and dioxide when burning; fumes pose inhalation risks to responders
Protective Equipment for Firefighters: Wear full protective fire gear, self-contained breathing apparatus
Advice for Firefighters: Move containers away from fire if safe, prevent water runoff into sewers, remain upwind of fire

Accidental Release Measures

Personal Precautions: Wear personal protective equipment: gloves, goggles, respirator if dust is present; avoid skin and eye contact
Environmental Precautions: Prevent entry into drains, watercourses, or soil; alert local environmental authorities for large spills
Containment: For solid, sweep up without creating dust, place in sealed container; for liquid, absorb with inert material (sand, vermiculite)
Clean-up Methods: Collect spilled material in labeled containers for disposal; ventilate area thoroughly; wash spill site after material pickup is complete

Handling and Storage

Precautions for Safe Handling: Use in well-ventilated area, wear protective gloves, avoid skin and eye contact, avoid generating dust or aerosols, keep container tightly closed
Conditions for Safe Storage: Store in cool, dry, well-ventilated space, away from sources of ignition or incompatible substances (strong acids, strong bases, oxidizers)
Incompatible Materials: Keep away from strong oxidants or acids to avoid violent reactions
Special Handling Measures: Minimize direct handling, label all containers clearly, retain spill cleanup materials nearby during use

Exposure Controls and Personal Protection

Control Parameters: No established occupational exposure limits for this specific chemical, handle as potentially hazardous
Engineering Controls: Use chemical fume hood or local exhaust ventilation during handling
Personal Protective Equipment: Chemical-resistant gloves (nitrile, neoprene), protective goggles, lab coat or coveralls, appropriate respirator if dust or vapors become airborne
Hygiene Measures: Wash hands thoroughly after handling, avoid eating, drinking, or smoking in work area, remove and wash contaminated clothing before reuse
Environmental Controls: Prevent chemical release to environment; handle and dispose with care

Physical and Chemical Properties

Appearance: White to off-white crystalline solid
Odor: Mild, characteristic
Odor Threshold: Not available
pH: 5-7 (1% solution in water)
Melting Point: 60-70°C
Boiling Point: Decomposes
Flash Point: Not established
Evaporation Rate: Not applicable (solid at room temperature)
Flammability: May burn upon heating above decomposition point
Vapor Pressure: Negligible at ambient temperature
Vapor Density: Not relevant (solid form)
Solubility: Soluble in water, alcohol and slight in most organic solvents
Partition Coefficient (log Kow): Not available
Auto-Ignition Temperature: Not known
Decomposition Temperature: Above 200°C, with emission of toxic fumes
Viscosity: Not applicable
Other Properties: Forms stable solutions with typical laboratory solvents

Stability and Reactivity

Chemical Stability: Stable under normal laboratory and storage conditions
Reactivity: Reacts with strong acids, strong bases, oxidizing agents
Possibility of Hazardous Reactions: May form toxic gases during thermal decomposition or in contact with incompatible chemicals
Conditions to Avoid: Heating above decomposition temperature, contact with open flames or sources of ignition
Incompatible Materials: Strong oxidizers, acids, bases
Hazardous Decomposition Products: Nitrogen oxides, hydrogen bromide, carbon monoxide, carbon dioxide

Toxicological Information

Acute Toxicity: Oral LD50 (estimated for rats): >2000 mg/kg, low acute toxicity expected for single exposures by ingestion
Skin Corrosion/Irritation: May cause mild skin irritation upon contact
Serious Eye Damage/Irritation: Causes eye irritation, redness, watering possible
Respiratory or Skin Sensitization: Prolonged or repeated exposure may cause skin sensitization or asthma-like symptoms
Germ Cell Mutagenicity: No data
Carcinogenicity: Not listed by IARC, NTP, or OSHA
Reproductive Toxicity: No information found
STOT (Single/Repeated): May affect respiratory tract and mucous membranes after inhalation
Symptoms from Exposure: Irritation, redness, coughing, stomach upset or vomiting depending on exposure route

Ecological Information

Ecotoxicity: Toxic for aquatic organisms, can cause long-term negative effects in water habitats at higher concentrations
Persistence and Degradability: Not readily biodegradable, chemical remains in environment for long periods
Bioaccumulation: May have potential for bioaccumulation in aquatic organisms
Mobility in Soil: Moderately mobile, soluble in water but can bind to soil particles
Other Adverse Effects: Avoid environmental release, large accidental spills can disrupt aquatic ecosystems, harm plant and animal life

Disposal Considerations

Disposal Methods: Dispose as hazardous chemical waste in accordance with local, regional, or national regulations; preferred disposal route via incineration at approved facility
Contaminated Packaging: Empty containers must be disposed as hazardous waste, do not reuse containers for other purposes
Special Precautions: Prevent any release to environment through proper disposal practices, label waste containers accurately, consult environmental or waste disposal authorities for guidance

Transport Information

UN Number: Not assigned
Proper Shipping Name: Chemical not classified with specific shipping name under UN regulations
Transport Hazard Class: Not regulated as dangerous good for transport by IATA, IMDG, or DOT
Packing Group: Not applicable
Environmental Hazards: Marine pollutant precautions apply for bulk shipments
Special Precautions for User: Transport in original containers, keep tightly sealed, shield from heat, direct sunlight, and vibration, transport under ADR/RID/IMDG/IATA guidelines where applicable

Regulatory Information

OSHA Hazard Communication: Classified as hazardous chemical under OSHA HazCom Standard
TSCA Status: Not listed; use only in R&D as exempt chemical
SARA Title III Sections 302/304/311/312: Not subject to EPA emergency planning or reporting thresholds
International Inventories: Not listed on EINECS, DSL, or PICCS
Other Regulations: Users must comply with all applicable guidelines for handling hazardous laboratory substances; observe all further workplace and environmental safety laws