Product Name: 1-Allyl-3-Butylimidazolium Tetrafluoroborate
Chemical Formula: C10H17BF4N2
CAS Number: 174501-65-6
Synonyms: ABImBF4, 1-Allyl-3-Butylimidazolium BF4
Intended Use: Research laboratories, specialty solvents, catalysis, electrochemistry
Manufacturer: Reliable chemical suppliers with strict protocols
Emergency Contact: Facility safety office or regional poison control center
GHS Classification: Eye irritation (Category 2A), Skin irritation (Category 2), Acute toxicity (Category 4 - Oral/dermal), Environmental hazard (Chronic aquatic toxicity)
Signal Word: Warning
Hazard Statements: Causes skin and eye irritation, may be harmful if swallowed, toxic to aquatic life with long lasting effects
Pictograms: Exclamation mark, Environment
Precautionary Statements: Wear protective gloves, avoid discharge to soil and water, wash hands thoroughly after handling, call a poison center if feeling unwell
Routes of Exposure: Eyes, skin, ingestion, inhalation (fine dust or mist form)
Chemical Identity: 1-Allyl-3-Butylimidazolium Tetrafluoroborate
Common Name: ABImBF4
Concentration: >95% (main substance)
Impurities and Stabilizing Additives: May contain trace (<1%) unreacted starting materials
Molecular Weight: 252.06 g/mol
Relevant Inactive Materials: None expected
General advice: Move individual to fresh air, remove contaminated clothing and rinse affected areas
Inhalation: Remove to fresh air, provide oxygen if breathing is difficult, seek medical attention
Skin Contact: Wash skin with plenty of soap and water for 15 minutes, remove contaminated clothing
Eye Contact: Rinse eyes with water for at least 15 minutes, pull eyelids apart, do not rub, seek medical advice
Ingestion: Do not induce vomiting unless instructed by medical personnel, rinse mouth with water, get medical assistance
Most Noted Symptoms: Irritation, redness, possible chemical burns with prolonged contact
Recommendations to Physician: Symptomatic and supportive treatment, monitor for systemic effects
Flammability: Not highly flammable, can decompose at high temperature
Suitable Extinguishing Media: Dry chemical, CO2, foam, water spray (avoid strong water jets)
Special Hazards: May produce toxic fumes (hydrofluoric acid, nitrogen oxides, boron fluorides) under fire
Firefighting Precautions: Use full protective gear and self-contained breathing apparatus
Explosion Data: No known explosion hazards
Advice for Firefighters: Water runoff may cause environmental damage, contain and dispose as hazardous material
Combustion Products: Hydrogen fluoride, boron trifluoride, nitrogen oxides, carbon oxides
Personal Precautions: Avoid inhaling vapors/dust, use splash goggles and chemical-resistant gloves
Evacuation: Remove unnecessary personnel, ventilate area
Methods for Containment: Prevent entry into waterways, dike spill with inert material
Cleanup Procedure: Absorb liquid with inert materials (vermiculite, dry sand), collect into suitable container for disposal
Environmental Precautions: Prevent discharge into drains or waterways, report significant spills to proper authorities
Disposal of Collected Material: Label as hazardous waste, store for chemical disposal
Precautions for Safe Handling: Use chemical fume hood or well-ventilated area, avoid direct skin or eye contact
Hygiene Measures: Remove contaminated clothing, wash hands and any exposed skin before eating or drinking
Storage Requirements: Keep container tightly closed in a cool, dry location, protect from moisture and direct sunlight
Incompatible Storage: Separate from strong oxidizers, acids, moisture-sensitive materials
Container Material: Use high-density polyethylene or glass with corrosion-proof cap
Engineering Controls: Use proper exhaust (chemical fume hoods), minimize airborne levels
Monitoring: Regular environmental and personal exposure testing in work areas
Personal Protective Equipment (PPE): Chemical-resistant gloves (nitrile, neoprene), splash goggles, lab coat, long pants, closed footwear
Respiratory Protection: Wear NIOSH-approved respirator when airborne concentration is above recommended limits or in case of spill
Hand Protection: Inspect gloves before use, change regularly
Eye/Face Protection: Splash goggles or face shield, especially during transfer and mixing
Skin Protection: Full protective clothing to avoid skin contact
Environmental Controls: Use spill trays, ensure proper waste containment
Appearance: Clear to pale yellow liquid
Odor: Slight, faintly sweet or chemical-like
pH: Neutral to slightly acidic (aqueous solution)
Melting Point: -40°C
Boiling Point: Decomposes before boiling above 200°C
Flash Point: >100°C (estimated)
Solubility: Miscible with water and most polar organic solvents
Vapor Pressure: Negligible at room temperature
Density: ~1.15 – 1.22 g/cm³ at 20°C
Viscosity: Moderate (varies with temperature)
Partition Coefficient (logKow): No data
Evaporation Rate: Very low
Chemical Stability: Usually stable under normal temperatures, decomposes at high heat
Thermal Decomposition: Risk of hydrofluoric acid, boron trifluoride, and other decomposition products
Reactivity: Reacts with strong oxidizers and strong acids, may create toxic or corrosive gases
Incompatible Materials: Strong acids, oxidizers, water-reactive substances
Hazardous Polymerization: Not expected under standard handling
Conditions to Avoid: Heat, flames, direct sunlight, humidity, contamination by incompatible chemicals
Potential Acute Effects: Skin, eye, and respiratory tract irritation, possible headaches or dizziness on exposure
Chronic Effects: Prolonged exposure may cause dermatitis or allergic response in sensitive individuals
LD50 Values: No reliable animal data specific for this compound, handle as potentially harmful
Carcinogenicity: Not classified as carcinogen by NTP, IARC or OSHA
Mutagenicity and Reproductive Effects: Data lacking, avoid unnecessary exposure
Routes of Exposure: Skin, eyes, respiratory tract, ingestion
Symptoms of Overexposure: Redness, burning, itching, coughing, gastrointestinal discomfort
Medical Conditions Aggravated: Pre-existing skin, eye, or respiratory disorders
Toxicity to Aquatic Life: Expected to be toxic to fish and aquatic invertebrates at low concentrations
Persistence and Degradability: Slow to degrade in soil or water, may persist in environment
Bioaccumulation: Potential for accumulation in aquatic organisms, no measured values
Mobility in Soil: High solubility, could migrate in wet soils
Other Adverse Effects: Avoid uncontrolled release, consider full life-cycle impact in labs/disposal sites
Special Precautions: Inform environmental agencies if significant release occurs
Waste Handling: Collect as hazardous waste, label container clearly
Method of Disposal: Incinerate at permitted chemical waste facility, use high-temperature combustion with gas scrubbing
Contaminated Packaging: Treat as hazardous, triple rinse and dispose according to local regulation
Relevant Codes: Review local, state, and federal guidelines for ionic liquid disposal
Animal or Environmental Disposal: Never release to sewage or natural bodies of water
UN Number: Not assigned for this material, treat as chemical, hazardous substance if in large quantity
Transport Hazard Class: Not officially classified under UN ADR/RID/IMDG/IATA
Packing Group: Not regulated but recommended to use secure, leak-proof packaging
Proper Shipping Name: Laboratory chemical, n.o.s. (contains ionic liquid)
Special Precautions: Secure container, avoid tipping or leaking during transport
Environmental Hazards During Shipping: Prevent leakages, spills, or contact with incompatible materials
Transport in Bulk: Discouraged, handle in limited quantities under supervision
OSHA: Not listed specifically, manage under hazard communication standards
SARA Title III: Not classified as extremely hazardous, reporting required for substantial spills
TSCA: May require registration or exemption based on production/import status
REACH: Potentially subject to pre-registration and notification for manufacture/import in European Union
Chemical Inventories: Confirm with relevant national databases
Labeling Requirements: Comply with GHS, include hazard pictograms, statements, handling guidelines
Other Rules: Inform supervisors of use, maintain inventory, keep usage log for regulatory review
