Product name: 1-Butyl-3-Methylimidazolium Bis((Trifluoromethyl)Sulfonyl)Imide
Synonyms: BMIM-TFSI, Ionic Liquid BMIM-TFSI, BMIM NTf2
Chemical Formula: C8H15F6N3O4S2
CAS Number: 174899-66-2
Recommended uses: Electrolyte solutions, catalyst, solvent in chemical synthesis, batteries research
Supplier: Custom chemical manufacturers, laboratory suppliers
Emergency contact: Local emergency services, Poison Control Center
Contact number: Found on product label, safety manual, supplier website
Hazard classification: Skin irritation, eye irritation, suspected reproductive toxicity, aquatic toxicity
GHS label elements: Exclamation mark for skin and eye irritation, environment pictogram for aquatic hazard
Signal word: Warning
Hazard statements: Causes skin irritation, causes serious eye irritation, toxic to aquatic life with long lasting effects
Precautionary statements: Wash hands thoroughly after handling, avoid release into environment, wear protective gloves, eye protection
Most important hazards: May irritate skin and eyes, prolonged exposure may affect reproductive health, may persist in aquatic systems
Chemical name: 1-Butyl-3-Methylimidazolium Bis((Trifluoromethyl)Sulfonyl)Imide
CAS number: 174899-66-2
EC number: Not assigned
Concentration: Pure substance
Impurities: May contain trace water or residual solvents from production
Other components: No additives or stabilizers listed
General advice: Move affected person to fresh air, remove contaminated clothing, keep person warm and at rest
If inhaled: Move to fresh air, seek medical attention if discomfort persists
If on skin: Rinse thoroughly with soap and water, remove contaminated clothing, seek medical attention for persistent irritation
If in eyes: Rinse cautiously with water for several minutes, remove contact lenses if present, seek medical care if irritation continues
If swallowed: Rinse mouth, do not induce vomiting, seek medical attention immediately
Special notes: Show this sheet to first responders and medical personnel
Suitable extinguishing media: Water spray, dry chemical, foam, carbon dioxide
Unsuitable extinguishing media: High volume water jets
Specific hazards: Potential formation of toxic and corrosive gases on heating or combustion (hydrogen fluoride, sulfur oxides, nitrogen oxides)
Protective equipment: Firefighters must use self-contained breathing apparatus and full protective gear
Special fire-fighting procedures: Evacuate area, contain runoff from firefighting to prevent environmental contamination, cool containers exposed to fire
Fire residues disposal: Dispose per local regulations regarding hazardous chemicals
Personal precautions: Avoid contact with eyes and skin, ventilate area, use personal protective equipment such as gloves and goggles
Environmental precautions: Prevent leakage to drains and surface water, avoid soil contamination, notify authorities if significant spillage occurs
Cleanup methods: Absorb with inert materials like sand, clay, or commercial absorbents, collect in closed containers for disposal, decontaminate area with soap and water
Reference to other sections: See exposure controls and disposal considerations for further guidance
Inadequate containment: Use diking to contain liquid, prevent runoff to water bodies
Safe handling tips: Handle with care, avoid generating aerosols, use only in well-ventilated areas, wear protective clothing
Avoid: Inhalation, ingestion, skin and eye contact
Do not eat or drink: In handling areas
Storage advice: Keep in tightly closed containers, store in cool, dry, and well-ventilated place, protect from moisture
Incompatible materials: Strong oxidizers, strong bases, reducing agents
Specific end uses: Consult technical guidelines before laboratory and industrial use
Engineering controls: Provide local exhaust ventilation at points of vapor generation, use chemical fume hoods
Exposure limits: No occupational exposure standards available for this compound
Personal protective equipment: Chemical-resistant gloves (nitrile), protective eyewear, lab coats or chemical aprons, suitable respiratory protection for vapor or dust
Hygiene measures: Wash hands after handling, remove contaminated clothing, avoid eating and drinking in work area
Environmental controls: Prevent waste from entering drains, surface waters, or soil
State: Liquid at room temperature
Color: Colorless to pale yellow
Odor: Slight, characteristic
Molecular weight: 419.39 g/mol
Melting point: -4°C
Boiling point: Decomposes before boiling
Density: 1.43 g/cm³ at 20°C
Solubility: Slightly soluble in water, freely miscible with organic solvents
Vapor pressure: Negligible at room temperature
pH: Not available
Flash point: Above 120°C
Viscosity: 36-50 cP at 25°C
Auto-ignition temperature: Not determined
Chemical stability: Stable under recommended storage and handling conditions
Hazardous reactions: Reacts with strong oxidizing agents, contact with strong bases may cause decomposition
Conditions to avoid: Heat, flames, sources of ignition, moisture
Decomposition products: Fluorinated and sulfonyl-containing toxic gases (SOx, NOx, HF, CF4) may form during heating or combustion
Polymerization: Not expected under normal conditions
Acute toxicity: Data for acute oral, dermal, and inhalation exposure limited, estimated low to moderate toxicity
Irritation/corrosion: Causes eye and skin irritation in animal studies
Sensitization: No sensitization reports
Repeated dose toxicity: Long-term effects not fully documented, potential for reproductive toxicity indicated in some research
Carcinogenicity: No evidence in animal or cell culture studies
Mutagenicity: No mutagenic activity detected
Other effects: Prolonged exposure may affect reproductive capacity, data sparse, animal studies ongoing
Ecotoxicity: Toxic to aquatic organisms, may cause long-term harm in aquatic environments
Persistence and degradability: Persists in environment, slow to biodegrade
Bioaccumulation potential: May bioaccumulate in aquatic species, limited data on transfer
Mobility in soil: Mobile in some soils, poses groundwater contamination risk
Other adverse effects: Interferes with aquatic nitrogen and sulfur cycles, causes changes in microbiomes
Regulatory perspective: Disposal and emission to water bodies regulated under hazardous waste laws
Waste treatment methods: Dispose in accordance with local, national, and international regulations
Methods: Collect liquid or absorbents containing the chemical in sealed containers for hazardous waste pickup, do not flush to sewer
Incineration: Possible in licensed chemical waste incinerators, never burn in open air
Packaging: Decontaminate or incinerate empty containers, do not reuse
Other advice: Avoid landfill disposal whenever possible, use certified disposal contractors
UN number: Not assigned
Proper shipping name: Not classified for transport as a hazardous substance in most jurisdictions
Transport hazard class: No data available for specific hazard class
Packing group: No information listed
Environmental hazard: Marked hazardous to the environment in some countries, check local rules
Special precautions: Use leak-proof, closed containers, keep upright during transport, avoid extreme temperatures
Transport labels: None required under general transport, may apply under local regulations
Safety, health, and environmental regulations: Listed under REACH as a registered substance, not regulated under U.S. TSCA, not included in major international chemical control lists
Workplace safety: Covered under occupational safety and health regulations for chemical handling
Restrictions: Manufacture, use, and import subject to fabricators’ national laws
Hazard communication: Requires labelling under GHS, environmental hazard symbol for aquatic toxicity
Other regulations: Subject to discharge and disposal controls under water protection and hazardous waste rules
Supplier obligations: Provide SDS to downstream users, report significant adverse effects promptly
