Product Name: 1-Butyl-3-Vinylimidazolium Hexafluorophosphate
Synonyms: Ionic liquid, 1-butyl-3-vinylimidazolium PF6
Chemical Formula: C11H17F6N2P
Molecular Weight: 338.23 g/mol
Recommended Use: Laboratory chemicals, research and development, catalyst for organic synthesis
Supplier Details: Manufacturer address, emergency contact number, support email, local distributor contact
Classification (GHS): Acute toxicity (oral, dermal, inhalation), Skin corrosion/irritation, Serious eye damage/irritation
Label Elements: Hazard pictogram (exclamation mark, corrosive), Signal Word: Warning
Hazard Statements: Harmful if swallowed, causes skin irritation, may cause serious eye irritation, toxic to aquatic life
Precautionary Statements: Avoid inhalation, wash hands thoroughly after use, use protective clothing, do not eat, drink, or smoke during handling, dispose contents/container in accordance with local regulations
Other hazards: Prolonged exposure may cause organ damage, possible environmental impact on aquatic ecosystems
Chemical Name: 1-Butyl-3-vinylimidazolium hexafluorophosphate
CAS Number: 50864-54-5
Concentration: ≥98%
Other Ingredients: May contain trace amounts of water, related imidazolium impurities, and stabilizers
General Advice: Move affected person to fresh air, remove contaminated clothing, keep at rest
If Inhaled: Move to fresh air, monitor breathing, seek medical attention if symptoms such as coughing or dizziness persist
Skin Contact: Remove contaminated clothing, rinse skin with plenty of soap and water for 15 minutes, seek medical attention if irritation develops
Eye Contact: Rinse thoroughly with water for at least 15 minutes, lift eyelids occasionally, seek immediate medical advice
If Swallowed: Rinse mouth, do not induce vomiting, give water (if conscious), seek prompt medical advice
Notes for Physician: Symptomatic treatment, keep under observation for potential systemic effects
Most Important Symptoms: Redness, burning, pain at contact site, nausea or headache if ingested or inhaled
Suitable Extinguishing Media: Water spray, alcohol-resistant foam, carbon dioxide, dry powder
Unsuitable Extinguishing Media: High-pressure water jets can spread chemical
Specific Hazards: Thermal decomposition releases toxic/hazardous fumes including HF, phosphorus oxides, nitrogen oxides
Special Precautions: Wear self-contained breathing apparatus and full protective gear, evacuate area and fight fire from safe distance
Additional Information: Cool containers with water spray, prevent firewater from entering drains
Personal Precautions: Use personal protective equipment, avoid skin and eye contact, ensure adequate ventilation, evacuate unnecessary personnel
Environmental Precautions: Prevent entry into waterways, drains, or soil, contain spill with inert absorbent material
Methods for Cleanup: Collect spillage with absorbent material (sand, earth), place in suitable closed containers, wash spill area with plenty of water, ventilate area
Disposal: Dispose of material in accordance with federal, state, and local regulations
Safe Handling: Handle in a chemical fume hood, avoid inhalation of vapors or contact with skin and eyes, do not eat or drink in work area, wash hands before breaks and after handling
Storage Conditions: Store in tightly sealed container in a dry, cool, well-ventilated area, protect from direct sunlight, keep away from incompatible materials such as strong acids, bases, or oxidizing agents
Incompatibilities: Strong oxidizers, water/moisture (may hydrolyze PF6), strong acids
Specific End Use: Restricted to industrial and laboratory use only
Engineering Controls: Work under local exhaust ventilation, laboratory fume hood, safety shower and eyewash nearby
Personal Protective Equipment: Protective gloves (nitrile or rubber), chemical safety goggles, lab coat or apron, suitable respiratory protection if ventilation is inadequate
Hygiene Measures: Remove contaminated clothing immediately, avoid contact with skin, eyes, and clothing, store personal protective equipment separately, do not eat or drink in laboratory
Control of Environmental Exposure: Prevent further leakage/spillage if safe, do not allow to enter drains
Appearance: Colorless to pale-yellow liquid
Odor: Mild, possibly slightly sweet/amine odor
Odor Threshold: Not established
pH: Not determined (as supplied)
Melting Point/Range: Approx. -40°C
Boiling Point/Range: Decomposes before boiling, above 250°C
Flash Point: >100°C (closed cup)
Evaporation Rate: Not available
Flammability: Not classified as highly flammable
Explosion Limits: Not determined
Vapor Pressure: Very low at room temperature
Vapor Density: No data
Relative Density: 1.25 - 1.35 g/cm3 at 25°C
Solubility: Slightly soluble in water, miscible with organic solvents
Partition Coefficient (n-octanol/water): Not available
Autoignition Temperature: Not available
Decomposition Temperature: >250°C
Viscosity: Moderate viscosity at room temperature
Chemical Stability: Stable under standard handling and storage conditions
Possibility of Hazardous Reactions: Reacts with strong oxidizing agents and strong acids, hydrolyzes slowly in moist environments
Hazardous Decomposition Products: Hydrogen fluoride, phosphorus oxides, nitrogen oxides, imidazole derivatives
Conditions to Avoid: Heat, exposure to flame, direct sunlight, moisture/humidity
Incompatible Materials: Strong oxidizers, strong acids, water (leads to hydrolysis), bases
Acute Toxicity: Harmful by ingestion, inhalation, skin absorption, may cause minor irritation, headache, nausea, and dizziness
Skin Corrosion/Irritation: Causes skin irritation after prolonged contact
Serious Eye Damage/Irritation: May cause severe irritation, redness, blurred vision
Respiratory Sensitization: Data not conclusive, may cause coughing and irritation to mucous membranes
Germ Cell Mutagenicity: No adverse effect observed at tested concentrations in standard in vitro studies
Carcinogenicity: No data specific to this compound, but related compounds have not shown evidence of carcinogenicity
Reproductive Toxicity: No significant data, prudent to avoid exposure
Target Organ Effects: No target organ toxicity observed in short-term animal studies
Medical Conditions Aggravated: Existing skin or respiratory disorders may worsen with exposure
Ecotoxicity: Toxic to aquatic life and may cause long-term adverse effects in the aquatic environment
Persistence and Degradability: Not readily biodegradable, can persist in soil and water for extended periods
Bioaccumulative Potential: May have potential for bioaccumulation according to related ionic liquids
Mobility in Soil: Moderate mobility, leaching may occur in wet conditions
Other Adverse Effects: Disrupts aquatic organisms’ normal metabolic processes, even in low concentrations, and could impact broader ecosystems if released in significant quantities
Product Waste: Dispose via licensed chemical disposal contractor in accordance with local, state, and federal waste regulations
Contaminated Packaging: Dispose of unused product and contaminated packaging as hazardous waste, rinse containers thoroughly prior to recycling or reuse
Special Precautions for Disposal: Prevent material from reaching waterways or soil, do not mix with municipal waste stream, keep residues in labeled containers for hazardous waste pickup
Recycling: Not supported due to toxicological profile and persistence, incinerate at approved facilities where possible
UN Number: Not assigned for this compound
UN Proper Shipping Name: Chemical, n.o.s. (contains 1-butyl-3-vinylimidazolium hexafluorophosphate)
Transport Hazard Class: Not classified as hazardous for transport by ADR/RID, IMDG, or IATA, although local regulations for toxic liquids may apply
Packing Group: III (if assigned)
Environmental Hazards: Marine pollutant—take care to prevent accidental leakage during transport
Special Precautions for User: Secure containers tightly, transport only in original, properly labeled containers, notify carrier of any spill risk
US Federal Regulations: Not listed on TSCA inventory, subject to Emergency Planning and Community Right-to-Know Act (EPCRA) if released in significant quantity
EU Regulations: Not listed on REACH Annex XVII, but restricted to professional use, safety data sheet required for provision
Other International Regulations: Not listed on schedules for Canada (DSL/NDSL) or Australia (AICS), observe national occupational exposure controls
Labeling Requirements: GHS hazard pictograms, warning phrases, supplier identification, instructions for use and prevention, appropriate disposal instructions
