Material Safety Data Sheet: 1-Butylsulfonic-3-Ethylimidazolium Trifluoromethanesulfonate

Identification

Product Name: 1-Butylsulfonic-3-Ethylimidazolium Trifluoromethanesulfonate
Chemical Family: Ionic Liquid
Synonyms: [BSEIm][OTf], 1-Butylsulfonic-3-Ethylimidazolium Triflate
Recommended Use: Laboratory chemicals, electrochemistry, catalysis
Supplier Details: Manufacturer’s address, telephone number, and email
Emergency Contact: Emergency number available 24 hours

Hazard Identification

Classification: Irritant, possible skin and eye irritant; may provoke mild to moderate health concern if swallowed, inhaled, or comes into contact with skin
Label Elements: Signal word: Warning; hazard pictograms for skin and eye irritation
Hazard Statements: Causes skin and eye irritation; may cause respiratory irritation if mist inhaled
Precautionary Statements: Avoid breathing vapors, wear gloves and eye protection, wash exposed skin thoroughly after handling, seek medical advice if discomfort persists

Composition / Information on Ingredients

Chemical Identity: 1-Butylsulfonic-3-Ethylimidazolium Trifluoromethanesulfonate
CAS Number: 1260041-16-0
Formula: C10H17F3N2O5S2
EC Number: Not readily available
Purity: >98% (as supplied in laboratory and industry use)

First Aid Measures

Inhalation: Remove individual to fresh air, keep at rest, seek medical attention if symptoms such as coughing or shortness of breath develop
Skin Contact: Wash with soap and plenty of water for at least 15 minutes, remove contaminated clothing, consult physician if irritation persists
Eye Contact: Rinse thoroughly with running water for several minutes, lift eyelids to ensure removal, obtain medical advice if discomfort remains
Ingestion: Rinse mouth with water if conscious, do not induce vomiting, seek prompt medical attention
Most Important Symptoms: Irritation, redness, discomfort, rarely, respiratory symptoms or gastrointestinal distress
Notes to Physician: Treat symptomatically; no specific antidote identified

Fire-Fighting Measures

Suitable Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or foam
Special Hazards: May emit hazardous fumes of carbon oxides, nitrogen oxides, sulfur oxides, and hydrogen fluoride upon combustion
Protective Equipment: Firefighters should wear full protective clothing and self-contained breathing apparatus
Advice for Firefighters: Approach fire from upwind side, prevent runoff to drains or open waterways, cool containers with water spray

Accidental Release Measures

Personal Precautions: Use adequate ventilation, avoid breathing dust or vapor, prevent skin and eye contact, wear appropriate personal protective equipment
Environmental Precautions: Prevent further leakage or spillage, do not let product enter drains, surface water, or soil
Methods for Cleanup: Absorb with inert material (sand, earth), place in suitable disposal container, ventilate area, wash spill site with appropriate cleaning agents and water

Handling and Storage

Handling: Avoid contact with skin, eyes and clothing, handle in well-ventilated area, do not breathe fumes or vapors, use protective equipment
Storage Conditions: Store in tightly closed container, keep in a cool, dry, well-ventilated place, protect from moisture and incompatible substances such as strong oxidizers and strong bases
Incompatibilities: Strong oxidizing agents, strong bases, acids may cause rapid decomposition or hazardous reactions

Exposure Controls and Personal Protection

Control Parameters: No established exposure limits, use general district workplace exposure guidelines for chemicals
Engineering Controls: Use fume hood or local exhaust ventilation at point of vapor or mist formation
Personal Protective Equipment: Chemical-resistant gloves (nitrile or neoprene), safety goggles, protective lab coat, if risk of inhalation, use NIOSH-approved respirator
Hygiene Measures: Do not eat, drink or smoke near area, wash hands and face after handling

Physical and Chemical Properties

Appearance: Pale yellow to colorless liquid (may vary on quality)
Odor: Slight, aromatic or sulfur odor
pH: Not available
Melting Point: Approx. 10-20°C
Boiling Point: Decomposes before boiling
Flash Point: >150°C (estimate, not flammable but may combust at high temperature)
Solubility: Miscible in water and polar organic solvents
Vapor Pressure: Negligible at room temperature
Density: Around 1.4-1.5 g/cm³ at 25°C

Stability and Reactivity

Chemical Stability: Stable under recommended storage and handling conditions
Conditions to Avoid: High temperatures, strong oxidizing or reducing agents, direct sunlight
Incompatible Materials: Strong bases, oxidizers, acids can trigger hazardous decomposition
Hazardous Decomposition Products: May release carbon oxides, sulfur oxides, nitrogen oxides, hydrogen fluoride
Polymerization: Not expected under standard conditions

Toxicological Information

Acute Toxicity: Data limited, expect low acute toxicity based on structure; ingestion or skin absorption may cause irritation
Skin Irritation: May cause redness, swelling or discomfort
Eye Irritation: Exposure may lead to pain, watering or redness
Inhalation: Misting can irritate respiratory tract
Chronic Effects: No comprehensive studies reported, use caution and limit exposure
Carcinogenicity/Mutagenicity: No data available; chemical not listed as carcinogen by NTP, IARC, or OSHA based on available literature

Ecological Information

Ecotoxicity: Information not widely available, ionic liquids have potential toxicity for aquatic organisms; release to environment should be minimized
Persistence and Degradability: Likely degradable by hydrolysis and photolysis over time, exact data unavailable
Bioaccumulation Potential: No significant risk expected, low log Kow anticipated, but data lacking
Mobility in Soil: High solubility suggests mobility, risk of groundwater contamination must be monitored
Other Hazardous Effects: No known significant effects or critical hazards, but best practice advises caution

Disposal Considerations

Disposal Methods: Dispose of in accordance with local, regional, and national regulations; incineration in licensed facility usually preferred
Contaminated Packaging: Treat as chemical waste; triple rinse and remove labels before disposal
Environmental Release: Minimize any spillage into drains, soil, or aquatic environments; report large or significant releases to proper authorities

Transport Information

UN Number: Not classified as dangerous goods under current transport regulations
UN Proper Shipping Name: Not regulated
Transport Hazard Class: Not assigned
Packing Group: Not applicable
Special Precautions: Ensure containers are tightly sealed and properly labeled, handle with appropriate care to prevent leaks

Regulatory Information

TSCA Status: Not explicitly listed
REACH Status: Not registered for large-scale EU commerce
SARA/OSHA Status: Not cited in SARA Title III or OSHA hazardous chemical lists
Labeling Requirements: Follow chemical labeling guidance for laboratory and technical grade stocks
Other Standards: Observe all national and international chemical safety and environmental regulations relevant to user location and handling purpose