Material Safety Data Sheet: 1-Carboxymethyl-Pyridinium Chloride

Identification

Product name: 1-Carboxymethyl-Pyridinium Chloride
Chemical Formula: C7H8ClNO2
CAS Number: 6223-22-3
Synonyms: Pyridinium, 1-(carboxymethyl)-, chloride
Relevant uses: Used in chemical synthesis, research, and laboratory applications in accordance with local regulations.
Manufacturer Information: Name, address, and emergency contact number of supplier or manufacturer.
Emergency telephone: 24/7 contact for information about spills, poisoning, or fire.

Hazard Identification

Classification: Irritant to eyes and skin; not classified as flammable or explosive; may cause respiratory irritation with prolonged exposure.
GHS Label elements: Warning symbol for hazardous health effects; precautionary statements regarding eye and skin contact.
Routes of exposure: Inhalation, ingestion, skin absorption, and contact.
Potential health effects: Immediate effects include burning sensation, rash or redness for skin contact, irritation and redness for eye contact, and coughing or shortness of breath for inhalation. Prolonged exposure may aggravate underlying respiratory or dermal sensitivity.
Target organs: Skin, respiratory tract, and eyes.
Environmental risk: Spills may harm aquatic life if discharged into waterways.

Composition / Information on Ingredients

Chemical identity: 1-Carboxymethyl-Pyridinium Chloride
Concentration/Content: >98% pure by standard laboratory analysis
Impurities: Trace solvents and minor byproduct residues under 1%
Hazardous components: No additional hazardous components in the supplied material.

First Aid Measures

Eye contact: Flush immediately with copious amounts of clean water for at least 15 minutes with eyelids separated. Do not allow victim to rub eyes.
Skin contact: Remove contaminated clothing, wash affected area thoroughly with soap and water, continue rinsing until medical help arrives.
Inhalation: Move person to fresh air; keep them warm and at rest; seek medical attention for difficulty breathing or persistent symptoms.
Ingestion: Do not induce vomiting; rinse mouth thoroughly with clean water; call poison control center or seek immediate medical help.
Medical attention: Provide product label or safety data to healthcare provider.

Fire-Fighting Measures

Suitable extinguishing media: Dry chemical, carbon dioxide, water spray or alcohol-resistant foam; use the method suited to surrounding fire.
Unsuitable extinguishing media: Strong water jets may spread spilled product.
Specific hazards: Decomposes under heat; may produce toxic fumes including nitrogen oxides, hydrogen chloride.
Protective gear for fire-fighters: Full protective clothing, breathing apparatus with independent air supply.
Advice: Contain contaminated runoff to prevent environmental release.

Accidental Release Measures

Personal precautions: Use appropriate protective clothing including gloves, safety goggles, and mask; avoid direct contact or inhalation.
Environmental precautions: Prevent discharge into drains, surface water, or soil. Dike spills with non-combustible absorbents.
Cleanup method: Sweep or scoop up material, place into suitable, closed containers for disposal; wash area with water and detergent.
Ventilation: Ensure adequate air flow to disperse dust or vapor.

Handling and Storage

Handling: Prevent skin and eye contact, avoid inhaling dust or vapor, do not eat or drink near this material, always wash hands after use.
Storage: Keep container tightly closed in a dry, cool, and well-ventilated space, protect from direct sunlight and incompatible materials such as strong oxidizers.
Special requirements: Use spill trays; label containers clearly.

Exposure Controls and Personal Protection

Engineering controls: Use fume hood or local exhaust to keep airborne concentrations below recommended exposure limits.
Personal protective equipment: Chemical-resistant gloves, safety glasses with side shields, lab coat; use NIOSH-approved respirator if dusty or in poorly ventilated settings.
Exposure limit values: No established OSHA or ACGIH limits, but minimize exposure.
Hygiene measures: Remove contaminated clothing, wash before reuse, maintain clean workplace, have eyewash stations and safety showers nearby.

Physical and Chemical Properties

Appearance: White to pale yellow crystalline solid.
Odor: Slightly sweet, mild characteristic odor.
pH: 4–6 in aqueous solution.
Melting point: 185–190°C.
Boiling point: Not volatile under ambient conditions.
Solubility: Readily soluble in water, slightly soluble in ethanol.
Vapor pressure: Negligible at room temperature.
Density: Approximately 1.3 g/cm³.
Flash point: Not applicable (non-flammable).
Partition coefficient (log Pow): Low, indicates preference for aqueous phases.

Stability and Reactivity

Chemical stability: Stable under recommended storage conditions for at least 24 months.
Incompatible materials: Strong oxidizing agents, acids, and bases; may react exothermically.
Hazardous decomposition: Chloride gases, nitrogen oxides and carbon oxides may form during combustion or thermal decomposition.
Polymerization: Not expected under normal conditions.
Reactivity: May react with strong oxidizers with heat or gas evolution.

Toxicological Information

Acute toxicity: Low toxicity by oral, dermal, or inhalation routes based on available animal data.
Chronic effects: No reliable data for carcinogenicity, mutagenicity, or reproductive toxicity; minimization of exposure avoids unnecessary risk.
Irritation: Contact may produce mild to moderate irritation to skin and mucous membranes.
Sensitization: No evidence of sensitization in limited testing.
Symptoms of exposure: Coughing, shortness of breath, redness and tearing of the eyes, rash on skin.

Ecological Information

Aquatic toxicity: May be harmful to aquatic organisms, avoid direct release.
Persistence and degradability: Slowly biodegradable; main concern if large quantities enter waterway.
Bioaccumulation: Low potential, based on structure and behavior in water.
Soil mobility: Moderately mobile in soil due to solubility in water.
Other adverse effects: Take care to prevent release to the broader environment.

Disposal Considerations

Waste treatment methods: Dispose of via licensed chemical waste facility; do not flush down drain or landfill untreated.
Container disposal: Triple rinse containers, puncture or crush before recycling or disposal as hazardous waste.
Regulatory note: Consult national, state, and local regulations for specifics; authorities may classify as hazardous based on concentration or mixture.

Transport Information

UN Number: Not regulated for ground, air, or sea transport.
Proper shipping name: 1-Carboxymethyl-Pyridinium Chloride
Hazard class: Not assigned.
Packing group: Not applicable.
Environmental hazards: Not a marine pollutant, but keep sealed.
Special transport precautions: Protect containers from physical damage, keep product dry.

Regulatory Information

Regulatory status: Subject to workplace safety, chemical storage, and environmental protection laws, including REACH and TSCA.
Labeling requirements: Hazard communication in compliance with OSHA Hazard Communication Standard, GHS-compliant icons and statements.
Specific national regulations: Each country may have additional requirements for handling, accidental release, or reporting.
Inventory status: Listed in relevant national or international chemical inventories where registered or evaluated.