Product Name: 1-Decyl-3-Ethylimidazolium Bromide
Synonyms: [C10EIm]Br, Ionic Liquid, Decyl-ethylimidazolium bromide
CAS Number: 850932-12-4
Recommended Use: Laboratory chemical, ionic liquid applications in research and synthesis, solvent and electrochemical studies
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GHS Classification: Acute toxicity (oral, dermal), eye irritation, aquatic toxicity
Signal Word: Warning
Hazard Statements: Harmful if swallowed; causes moderate eye irritation; toxic to aquatic life with long lasting effects
Pictograms: Exclamation mark, environmental hazard symbol
Precautionary Statements: Avoid breathing dust or vapor; wash hands thoroughly after handling; keep away from the environment; wear protective gloves, eye protection, and clothing
Chemical Name: 1-Decyl-3-Ethylimidazolium Bromide
Common Name: [C10EIm]Br
CAS Number: 850932-12-4
Concentration: >97% (as supplied)
Impurities: Less than 3%, mostly related to unreacted precursors or side-products from synthesis
Inhalation: Move person to fresh air; if symptoms develop, seek medical attention
Eye Contact: Rinse carefully for several minutes; remove contact lenses if present and easy; continue rinsing; consult a physician
Skin Contact: Remove contaminated clothing; wash skin with soap and water; seek medical advice if irritation persists
Ingestion: Rinse mouth thoroughly; do not induce vomiting; seek immediate medical advice
Suitable Extinguishing Media: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide
Hazards from Combustion: Fumes may contain hydrogen bromide, carbon oxides, and imidazole derivatives
Protective Equipment: Firefighters should wear self-contained breathing apparatus and full protective gear
Special Precautions: Approach from upwind to avoid possible exposure to hazardous fumes during fire events
Personal Precautions: Evacuate area, ventilate space, avoid breathing vapors or dust
Protective Equipment: Wear appropriate chemical-resistant gloves, protective goggles, and lab coat
Environmental Precautions: Do not let the product enter drains, soil, or surface water sources
Clean-Up Method: Absorb spills with inert material (sand, vermiculite); collect into containers for disposal; clean area with detergent and water
Safe Handling: Handle in a well-ventilated area, avoid contact with skin, eyes, and clothing; do not ingest or inhale
Storage Conditions: Keep tightly sealed in original container; store in cool, dry, well-ventilated place
Incompatible Materials: Strong oxidizers, strong acids, moisture, sources of ignition
Additional Precautions: Prevent formation of dust or aerosols, use only with adequate ventilation
Engineering Controls: Use local exhaust ventilation, handle in fume hood when possible
Personal Protective Equipment: Wear NIOSH-approved respirators if exposure limits are exceeded; ANSI-approved eye protection (goggles); long sleeves and chemical-resistant gloves
Hygiene Measures: Wash hands, face, and exposed areas after handling; avoid eating, drinking, or smoking during use
Environmental Exposure Controls: Use containment to avoid environmental release; have spill control materials available
Appearance: White to off-white solid (may appear as crystalline powder or flakes)
Odor: Mild, slightly ammoniacal
Odor Threshold: Not determined
pH: Not determined (as supplied, usually neutral to slightly basic in solution)
Melting Point: 50-60°C (approximate)
Boiling Point: Decomposes before boiling
Flash Point: >150°C (closed cup)
Evaporation Rate: Not applicable
Flammability: Not highly flammable under normal conditions
Vapor Pressure: Negligible at room temperature
Vapor Density: Not applicable
Relative Density: 1.05–1.12 g/cm³
Solubility: Soluble in water and polar organic solvents
Partition Coefficient (n-octanol/water): Not determined
Autoignition Temperature: Not known
Decomposition Temperature: >200°C
Viscosity: Not determined (higher than water in general)
Chemical Stability: Stable under recommended storage and handling conditions
Hazardous Polymerization: Does not occur in normal use
Incompatible Materials: Strong oxidizing agents, strong acids
Conditions to Avoid: Excessive heat, light, and moisture
Hazardous Decomposition Products: Burning produces toxic bromine and nitrogen oxides, carbon monoxide, and carbon dioxide
Routes of Exposure: Inhalation, ingestion, skin or eye contact
Acute Toxicity: Harmful if swallowed, may cause gastrointestinal discomfort; skin contact may produce mild irritation
Chronic Effects: No long-term studies in humans; long-term exposure may cause target organ toxicity
Irritant Effects: Causes moderate to severe eye irritation; mild skin irritation possible
LD50 / LC50: Data not widely available, estimated oral LD50 (rat) > 300 mg/kg
Carcinogenicity: No data to suggest carcinogenic effects in humans
Other Information: No data on mutagenic or reproductive effects; use in research settings should be guided by caution
Ecotoxicity: Harmful to aquatic organisms, may cause long-term adverse effects in aquatic environments
Persistence and Degradability: Not readily biodegradable; tends to persist in the environment
Bioaccumulation Potential: Limited data suggest some potential; ionic liquids may be taken up by aquatic species
Mobility in Soil: Moderately mobile in water, attenuated by soil-binding
Other Adverse Effects: Avoid release to surface waters or sewage; ionic character increases risk to aquatic species
Disposal Techniques: Dispose of in accordance with local, regional, and national regulations; incineration may be appropriate under controlled conditions
Contaminated Packaging: Empty containers may retain product residues; treat as hazardous waste
Other Disposal Recommendations: Do not discharge to environment; use licensed waste disposal contractors where possible
UN Number: Not assigned
UN Proper Shipping Name: Not regulated as a hazardous material under most international transport codes
Transport Hazard Classes: Not classified (use local guidelines)
Packing Group: Not applicable
Environmental Hazards: Not designated as marine pollutant under IMDG, but avoid aquatic release
Special Precautions for Transport: Avoid mechanical shock, keep dry, package in accordance with chemical shipping requirements
Labelling Requirements: GHS labels required for laboratory and industrial settings
Safety, Health, and Environmental Regulations: Not specifically listed in major international chemical inventories; subject to occupational exposure standards
Other Regulatory Status: Subject to the requirements of workplace health and safety laws and chemical inventory reporting; local and national restrictions may apply based on use and destination