Product Name: 1-Decyl-3-Methylimidazolium Acetate
Chemical Formula: C16H30N2O2
Synonyms: [C10mim][OAc], Ionic Liquid, Decylmethylimidazolium Acetate
Recommended Use: Laboratory solvent, catalyst, cellulose dissolution, chemical processing
Manufacturer: Supplier contact information available on purchase order
CAS Number: 188973-44-4
Emergency Phone: Local emergency number or poison control
Classification: Not classified as hazardous under GHS criteria but can cause skin and eye irritation
Hazard Symbols: No pictogram under GHS, but caution required
Potential Health Effects: Irritation of skin, eyes, respiratory tract on prolonged contact; possible harmful effects if swallowed
Precautionary Statements: Avoid direct contact, use with adequate ventilation, wash hands after handling
Route of Exposure: Skin, eye, inhalation, ingestion
Environmental Effects: Potential aquatic toxicity; avoid release to waterways or drains
Chemical Identity: 1-Decyl-3-Methylimidazolium Acetate
Common Name: [C10mim][OAc]
Concentration: >98% pure
Impurities: Trace water, non-volatile residues (<2%)
CAS Number: 188973-44-4
Molecular Weight: 282.42 g/mol
Inhalation: Move to fresh air, seek medical advice if symptoms persist, provide oxygen if breathing is difficult
Skin Contact: Remove contaminated clothing, wash skin thoroughly with soap and water, get medical attention if irritation develops
Eye Contact: Rinse cautiously with water for 15 minutes, remove contact lenses, seek medical help if irritation or pain remains
Ingestion: Rinse mouth with water, do not induce vomiting, contact poison control or physician immediately
General Advice: Show this safety data to attending physician, keep person warm and rested
Suitable Extinguishing Media: Water spray, foam, dry chemical, carbon dioxide
Unsuitable Extinguishing Media: Not identified in literature due to low volatility and high flash point
Specific Hazards: May produce irritating or toxic fumes such as nitrogen oxides, carbon monoxide when burned
Protective Equipment: Full protective gear and self-contained breathing apparatus recommended for large fires
Advice for Firefighters: Use standard firefighting procedures, keep unaffected containers cool with water spray, avoid inhalation of combustion byproducts
Personal Precautions: Evacuate unnecessary personnel, provide adequate ventilation, wear suitable protective clothing and gloves
Environmental Precautions: Prevent release to soil, surface water, drains; contain spill using inert absorbent such as vermiculite
Clean-Up Methods: Collect spilled material in suitable closed containers for disposal, wash area with water after removal
Disposal of Clean-Up Materials: Dispose of contaminated absorbents in accordance with local regulations
Additional Advice: Ensure area is well ventilated before reoccupation
Protective Measures: Use in well-ventilated area, avoid contact with skin and eyes, wash thoroughly after handling
Safe Handling Advice: Use only as intended, keep away from incompatible materials (strong oxidizers, acids)
Storage Conditions: Store in tightly sealed original container, cool and dry, protect from light and moisture, temperature ideally between 2-8°C
Incompatible Materials: Strong acids, strong oxidizing agents
Special Requirements: Ensure proper labeling and secondary containment for bulk containers, keep away from foodstuffs
Engineering Controls: Work in fume hood or with local exhaust ventilation to limit vapor accumulation
Personal Protection: Chemical-resistant gloves (nitrile or similar), safety goggles, lab coat
Hygiene Measures: Hand washing after handling, removal of contaminated clothing, no eating or drinking near work area
Respiratory Protection: Use approved respirator if vapors or mists develop
Exposure Limits: No specific occupational exposure limits established; control exposure as for nuisance dust or vapor
Appearance: Colorless to pale yellow liquid
Odor: Slight, characteristic
Odor Threshold: Not established
pH: 6-8 (in aqueous solution)
Melting Point: <0°C (liquid at room temperature)
Boiling Point: Near 330°C (decomposes before boiling)
Flash Point: >150°C (closed cup)
Evaporation Rate: Very low, non-volatile
Flammability: Not easy to ignite
Vapor Pressure: Negligible at 20°C
Density: 0.98 g/cm³ at 20°C
Solubility: Soluble in water, polar organic solvents
Partition Coefficient (log Kow): Not determined
Auto-Ignition Temperature: >200°C
Decomposition Temperature: >200°C
Viscosity: Moderate, depends on temperature
Chemical Stability: Stable under normal conditions, avoid excess moisture and high temperatures
Reactivity: Low, but reacts with strong acids and oxidizers
Conditions to Avoid: Exposure to heat, direct sunlight, strong oxidizing or acidic conditions
Incompatible Materials: Strong oxidizers, strong acids
Hazardous Decomposition Products: Oxides of carbon, nitrogen, possible imidazole derivatives under combustion or strong thermal decomposition
Acute Toxicity: Not extensively studied; estimated oral LD50 in rats >2,000 mg/kg (low toxicity classification)
Irritation: Mild to moderate irritation possible for skin and eyes based on chemical group
Sensitization: Data not available; low likelihood
Long-Term Effects: No data for carcinogenicity, mutagenicity, or reproductive toxicity in humans
Possible Symptoms: Redness, itching, watering for eyes/skin; nausea, headache for high exposure
Toxicity to Aquatic Life: Limited studies; ionic liquids like [C10mim][OAc] may produce moderate toxicity to aquatic organisms at elevated concentrations
Persistence and Degradability: Not rapidly biodegradable, may persist in the environment
Bioaccumulative Potential: Low to moderate; more data needed
Mobility in Soil: High solubility in water increases mobility, risk of leaching to groundwater
Other Adverse Effects: Do not allow large amounts to reach surface water or sewage systems to limit impact on microbial activity
Waste Disposal Methods: Collect and place in appropriate designated waste container, do not pour into drains or sewers
Contaminated Packaging: Triple rinse containers, offer for chemical recycling where possible
Special Instructions: Handle waste per local, regional, and national regulations
Additional Info: Consult licensed hazardous waste disposal contractor for safe destruction
UN Number: Not regulated as dangerous goods for transport by road, rail, air, or sea
Proper Shipping Name: Not classified as hazardous according to major transport codes (ADR, IMDG, IATA)
Packaging Requirements: Leakproof, properly labeled, protect from breakage during transit
Transport Hazard Class: No classification or labeling required
Special Transport Precautions: Prevent spillage and ensure lid secure to limit direct contact
US TSCA: Components appear on the inventory or are exempt
EU REACH: Subject to registration; SDS may be provided on request under Article 31
Hazard Communication: Not subject to mandatory labeling under CLP or OSHA GHS
WHMIS (Canada): Non-controlled product
Other Regulations: Not on California Prop 65, not listed as a carcinogen by IARC, NTP, or ACGIH
Labelling: Standard chemical laboratory labeling recommended, keep out of reach of children
