Material Safety Data Sheet: 1-Dodecylimidazole

Identification

Product Name: 1-Dodecylimidazole
Chemical Family: Imidazole Derivative, Alkylimidazoles
Chemical Formula: C15H30N2
Molecular Weight: 238.41 g/mol
Synonyms: N-Dodecyl-1H-imidazole
Recommended Use: Surfactant, Chemical Intermediate, Research Applications
Manufacturer Information: Company address and contact number on shipping documents
Emergency Phone Number: Provided by supplier

Hazard Identification

Classification: Skin Irritant (Category 2), Eye Irritant (Category 2A), Harmful if Swallowed (Category 4)
Signal Word: Warning
Pictograms: Exclamation mark
Hazard Statements: Causes skin irritation, causes serious eye irritation, may be harmful if swallowed
Precautionary Statements: Avoid contact with skin and eyes, do not eat or drink while handling, wash exposed skin thoroughly
Potential Health Effects: Inhalation or skin exposure may cause redness, irritation, or allergic responses; ingestion could cause gastrointestinal discomfort
Target Organs: Eyes, Skin, Gastrointestinal tract
Other Hazards: No information on chronic toxicity or carcinogenicity; not listed by IARC, NTP, or OSHA

Composition / Information on Ingredients

Chemical Name: 1-Dodecylimidazole
CAS Number: 4303-67-7
Concentration: ≥ 98%
Impurities: Minor residual substances below 2%, unspecified
Mixture: Not a mixture; pure substance
Additives: None present

First Aid Measures

Inhalation: Move exposed person to fresh air, keep at rest in position comfortable for breathing, seek medical advice if symptoms develop
Skin Contact: Remove contaminated clothing, rinse skin immediately with copious water and mild soap, seek medical attention for persistent irritation
Eye Contact: Rinse eyes gently with clean water for several minutes, lift eyelids to ensure thorough irrigation, seek immediate ophthalmological consultation if discomfort persists
Ingestion: Rinse mouth with water if conscious, do not induce vomiting, call poison control or medical professional for further instructions
Most Important Symptoms: Burning, redness, stinging in exposed areas, potential gastrointestinal upset
Notes to Physician: Treat symptomatically and supportively, monitor for respiratory effects in case of large exposure

Fire-Fighting Measures

Suitable Extinguishing Media: Carbon dioxide, dry chemical, foam, water fog for larger fires
Unsuitable Extinguishing Media: Strong water jets may spread material
Special Hazards: In case of combustion, releases nitrogen oxides, carbon oxides, potentially hazardous imidazole vapors
Protective Equipment: Wear self-contained breathing apparatus, protective clothing, chemical resistant gloves, and boots
Instructions for Firefighters: Keep containers cool with water spray, avoid inhalation of combustion byproducts, isolate area and prevent runoff into water sources

Accidental Release Measures

Personal Precautions: Wear chemical-resistant gloves, safety goggles, laboratory coat, avoid direct contact with spilled material
Environmental Precautions: Contain spill, prevent runoff into drains, soil, or waterways
Methods for Cleanup: Absorb with inert material (sand, vermiculite), scoop into labeled containers, flush area with water after pickup
Disposal: Dispose of collected waste through an approved chemical disposal facility
Emergency Procedures: Evacuate area around spill if necessary, ventilate affected space to prevent vapor buildup

Handling and Storage

Handling Recommendations: Use under fume hood for laboratory scale, practice safe pipetting, minimize dust or aerosol generation, follow institutional hygienic practices
Personal Hygiene: Wash hands after handling, avoid eating, drinking, or smoking during use
Storage Conditions: Store in tightly closed containers in a dry, cool, well-ventilated place, away from acids and oxidizing agents
Storage Temperature: 15-25°C recommended
Incompatible Materials: Strong oxidizers, mineral acids
Packaging: Use chemical-resistant, properly labeled containers

Exposure Controls and Personal Protection

Engineering Controls: Local exhaust ventilation, chemical fume hood recommended during transfer or synthesis
Eye Protection: Chemical splash goggles, face shield for bulk transfer
Skin Protection: Nitrile or neoprene gloves, lab coat, long pants, closed-toe shoes
Respiratory Protection: NIOSH-certified particulate respirator for handling in powder or aerosol forms
Workplace Monitoring: Regular review of exposure levels; not assigned a workplace exposure limit by OSHA or ACGIH yet
Environmental Exposure: Prevent significant discharge into environment, handle effluent responsibly

Physical and Chemical Properties

Appearance: Waxy solid, white to pale yellow
Odor: Light, amine-like
Odor Threshold: Not established
pH: Not determined (solubility in water is low)
Melting Point: 34-37°C
Boiling Point: >200°C (decomposes)
Flash Point: Approximately 170°C (closed cup)
Flammability: Not easily ignitable, flammable in presence of heat, flame
Explosive Properties: Not explosive under normal conditions
Vapor Pressure: Negligible at room temperature
Density: 0.89 g/cm³ at 20°C
Water Solubility: Poorly soluble, easier to dissolve in organic solvents
Solubility in other solvents: Soluble in ethanol, methanol, chloroform
Partition Coefficient (log Kow): Estimated above 3.5 (high organic affinity)
Decomposition Temperature: Above 200°C
Viscosity: Not applicable as a solid

Stability and Reactivity

Chemical Stability: Stable for at least 12 months under recommended handling and storage
Thermal Decomposition: Produces toxic fumes such as carbon and nitrogen oxides above 200°C
Reactivity: May react with strong acids producing heat and hazardous gases, less reactive with dilute common reagents
Conditions to Avoid: Avoid high temperatures, moisture, direct sunlight, open flames
Incompatible Materials: Strong oxidizing agents, strong acids
Polymerization: Hazardous polymerization unlikely under normal processing
Corrosivity: Not corrosive to common metals or glass

Toxicological Information

Likely Routes of Exposure: Skin and eye contact, accidental ingestion, inhalation of dust or aerosol
Acute Toxicity: Oral LD50 (rat) not well established; low-moderate toxicity based on related compounds
Skin Sensitization: May cause mild to moderate irritation, possibly allergic responses
Eye Irritation: Vapors or particles cause pain, redness, tearing, and severe irritation
Inhalation: Dust or vapor exposure results in respiratory irritation, coughing, sore throat
Chronic Effects: Data insufficient; structurally related compounds show no evidence of carcinogenicity
Other Health Effects: Not classified as mutagenic or teratogenic, no known reproductive toxicity
Medical Conditions Aggravated by Exposure: Pre-existing dermatological or respiratory conditions

Ecological Information

Ecotoxicity: Toxic to aquatic organisms at moderate to high concentrations, persistent due to hydrophobic chain
Persistence and Degradability: Partial biodegradability over extended periods, breakdown products may still present environmental hazard
Bioaccumulative Potential: High, likely accumulates in aquatic life based on structure
Mobility in Soil: Low mobility, binds to organic matter
Other Adverse Effects: Data on long-term ecological impacts limited, recommendation to prevent direct release to environment

Disposal Considerations

Waste Management: Classify as hazardous chemical waste
Disposal Method: Incinerate under controlled conditions at licensed facility
Handling of Waste: Avoid skin and eye contact, wear recommended PPE, do not flush to sewer or natural waters
Packaging for Disposal: Use leak-proof, chemically resistant containers clearly marked for hazardous material
Recommended Disposal Agency: Utilize specialized chemical waste disposal service, comply with local, regional, and national regulations
Empty Containers: Rinse with compatible solvent, dispose of rinseate and label containers for reprocessing or incineration

Transport Information

UN Number: Not assigned for this material
Proper Shipping Name: 1-Dodecylimidazole
Transport Hazard Class: Not regulated under ADR, IMDG, IATA for normal commercial quantities
Packing Group: Not classified
Special Precautions: Avoid inhalation of dust, wear gloves when repackaging, transport in secure packaging to prevent leaks
Environmental Hazards: Prevent major release during accidental spill in transit

Regulatory Information

US TSCA Inventory: Check compliance with supplier for commercial use
EU REACH Status: Registration status to be confirmed with manufacturer
OSHA Hazard Communication: Meets criteria for hazardous chemical
California Proposition 65: Not listed
SARA Title III – Section 313: Not listed as a toxic chemical
Canadian WHMIS Classification: Consult local authority for classification guidance
Environmental Regulations: Subject to anti-pollution and effluent regulations for industrial users
Other National/Regional Regulation: Confirm with supply chain for country-specific requirements, reportable quantity may be established for environmental discharge