Material Safety Data Sheet: 1-Ethoxyethyl-3-Methylimidazolium Bromide

Identification

Product Name: 1-Ethoxyethyl-3-Methylimidazolium Bromide
Chemical Family: Imidazolium salt
Synonyms: [No common synonyms]
CAS Number: 941294-07-9
Recommended Use: Laboratory chemicals, research and development
Supplier Information: Please consult with distributor or manufacturer for up-to-date contact information.
Emergency Contact Number: Accessible through national poison center or local emergency services.

Hazard Identification

Classification: Acute oral toxicity (Category 4), Skin irritation (Category 2), Eye irritation (Category 2A), Specific target organ toxicity – single exposure (Category 3)
Symbol/Pictogram: GHS07 (Exclamation mark)
Signal Word: Warning
Hazard Statements: Harmful if swallowed, causes skin irritation, causes serious eye irritation, may cause respiratory irritation
Precautionary Statements: Wash hands thoroughly, use personal protective equipment, avoid breathing dust or vapors, use only outdoors or in well-ventilated areas

Composition / Information on Ingredients

Chemical Name: 1-Ethoxyethyl-3-Methylimidazolium Bromide
CAS Number: 941294-07-9
Concentration: >98%
Impurities: Trace solvent residues, moisture (<1%)
Additives: None known

First Aid Measures

Inhalation: Remove person to fresh air, keep at rest, consult medical attention if symptoms develop or persist. Symptoms might include cough, shortness of breath, sore throat.
Skin Contact: Remove contaminated clothing, immediately rinse skin with plenty of water for at least 15 minutes, seek medical advice for persistent redness, irritation, or blistering.
Eye Contact: Rinse cautiously with water for several minutes, remove contact lenses if present and easy to do, continue rinsing, seek ophthalmological consultation for reddening, watering, or pain.
Ingestion: Rinse mouth, do not induce vomiting, get medical help if feeling unwell or after large ingestion, provide the product label or SDS to healthcare professional.
Notes for Physician: Treat symptomatically, no known specific antidote

Fire-Fighting Measures

Suitable Extinguishing Media: Use dry chemical, CO₂, foam, or water spray – use water jet only for cooling closed containers.
Hazards from Combustion: Can produce carbon oxides, nitrogen oxides, hydrogen bromide, imidazole derivatives.
Protective Actions: Wear self-contained breathing apparatus and full protective gear, avoid inhaling combustion products.
Specific Hazards: Thermal decomposition releases toxic and irritant fumes
Special Procedures: Keep containers cool with water spray if exposed to heat or fire, prevent runoff from entering drains

Accidental Release Measures

Personal Precautions: Use suitable personal protective equipment (PPE) such as gloves, goggles, lab coat, avoid breathing dust or vapor.
Environmental Precautions: Prevent spills from entering soil, waterways, or sewage system, notify authorities if contamination occurs.
Spill Cleanup Methods: Collect spills using inert absorbent material (sand, earth, vermiculite), transfer to labeled waste container, clean area with water and detergent.
Disposal: Dispose of material following national regulations and hazardous waste guidelines

Handling and Storage

Handling: Avoid skin and eye contact, minimize dust and vapor generation, handle in fume hood or well-ventilated area, use PPE including gloves and splash-proof goggles.
Hygiene Measures: Wash hands and face before eating or drinking, do not eat, drink, or smoke near work area, change contaminated clothing.
Storage Conditions: Store in tightly closed original container, keep in cool, dry, and well-ventilated area, protect from moisture and direct sunlight.
Incompatibilities: Strong oxidizing agents, acids, sources of ignition

Exposure Controls and Personal Protection

Control Parameters: No established occupational exposure limits, minimize exposure through engineered controls.
Engineering Controls: Ensure adequate ventilation, use fume hood in laboratory, install eyewash stations and safety showers.
Personal Protection: Wear protective gloves (nitrile or equivalent), chemical splash goggles, laboratory coat or other suitable protective clothing, approved dust mask or respirator for powder handling.
Environmental Protection: Prevent release into environment, implement spill containment practices

Physical and Chemical Properties

Appearance: Solid, crystalline powder
Color: White to off-white
Odor: Odorless or mild chemical scent
pH: No data available (aqueous solutions may be mildly acidic)
Melting Point: 80–110°C
Boiling Point: Decomposes before boiling
Flash Point: Not determined
Solubility: Highly soluble in water and polar organic solvents
Vapor Pressure: Negligible at ambient conditions
Relative Density: Approximately 1.3–1.5 g/cm³
Viscosity: No data available for solid form
Partition Coefficient (n-octanol/water): Not determined

Stability and Reactivity

Chemical Stability: Stable under normal conditions and if stored as advised.
Reactivity: No dangerous reactions known under recommended conditions of use.
Conditions to Avoid: Moisture, light, high temperatures, incompatible substances.
Materials to Avoid: Strong oxidizers, acids, reducing agents.
Hazardous Decomposition Products: Produces toxic bromide fumes, imidazole derivatives, carbon oxides, nitrogen oxides upon heating.
Polymerization: Not expected to occur

Toxicological Information

Routes of Exposure: Inhalation, ingestion, skin and eye contact.
Acute Effects: Harmful if swallowed or inhaled, causes skin and eye irritation.
Symptoms: Inhalation can trigger respiratory irritation, coughing, and throat discomfort; skin contact may produce redness or burning; eye exposure can result in redness, watering, or pain.
Chronic Exposure: No definitive chronic toxicity data available; repeated exposure may increase risk of sensitization or dermatitis.
LD50: Not specifically determined for this compound – related imidazolium salts show oral rat LD50 between 300–2000 mg/kg.
Carcinogenicity: No data available; not classified as carcinogenic.
Mutagenicity/Teratogenicity: Not available

Ecological Information

Eco-toxicity: Data on aquatic toxicity is limited, avoid uncontrolled environmental release.
Persistence/Degradability: Imidazolium salts can show limited biodegradability.
Bioaccumulative Potential: Expected to be low based on structure but not specifically measured.
Mobility in Soil: High water solubility suggests mobility through soil and potential leaching.
Other Adverse Effects: Prevent product, washings, or packaging from entering surface waters, sewer, or soil to avoid harm to aquatic organisms from acute exposure

Disposal Considerations

Waste Treatment: Dispose of contents in accordance with local, regional, national, and international regulations governing hazardous chemical waste.
Contaminated Packaging: Rinse and render containers inert, deliver to approved chemical waste recycler.
Additional Information: Avoid discharge to environmental compartments, coordinate disposal through licensed hazardous waste contractor.
Sewage Disposal: Do not discharge to sewer

Transport Information

UN Number: Not assigned specifically for 1-Ethoxyethyl-3-Methylimidazolium Bromide; check for related imidazolium salts.
Transport Hazard Class: Not classified as hazardous for transport under current regulatory guidelines, but handle with care.
Packing Group: Not applicable.
Environmental Hazards: Not a marine pollutant under IMDG.
Special Precautions: Provide secondary containment during transport, carry documentation, highlight chemical irritant risk

Regulatory Information

Classification: Follows GHS and relevant national chemical safety regulations.
Inventory Listings: Not listed under major international chemical inventories, review with local compliance requirements.
Labelling: Requires GHS toxic and irritant pictogram and risk phrases.
Restrictions: For research and development use only, not for food, drug, cosmetic, or household use.
Other Regulations: Satisfies regulations under OSHA Hazard Communication Standard, REACH, and other national or international frameworks as provided by supplier