Product Name: 1-Hexyl-3-Methylimidazolium Dicyanamide
Chemical Formula: C12H20N6
CAS Number: 448127-98-4
Synonyms: [HMIM][DCA], 1-Hexyl-3-methylimidazolium dicyanamide ionic liquid
Use: Used in electrochemistry, solvent extractions, catalysis, battery electrolytes
Supplier Information: Refer to packaging or sales representative for current contact information
Emergency Contact: Poison Control Center or local emergency services as indicated on package
GHS Classification: Acute Toxicity (Oral, Category 4); Eye Irritation (Category 2A); Skin Irritation (Category 2)
GHS Label Elements/Symbols: Exclamation mark, toxic symbol
Signal Word: Warning
Hazard Statements: Harmful if swallowed; causes skin and eye irritation; may damage organs through prolonged or repeated exposure.
Precautionary Statements: Avoid breathing dust or vapors; wear protective gloves, clothing, and eye protection; wash hands thoroughly after handling.
Other Hazards: Not listed as carcinogen; avoid direct contact with incompatible materials, high temperatures, or open flames.
Chemical Name: 1-Hexyl-3-Methylimidazolium Dicyanamide
Concentration: > 98% by weight
Molecular Formula: C12H20N6
Impurities: Trace amounts of related imidazolium compounds and residual solvents possible
Hazardous Components: No significant hazardous impurities expected based on current manufacturing processes
Inhalation: Remove person to fresh air; seek medical advice if symptoms persist; avoid self-exposure during rescue.
Skin Contact: Wash affected area thoroughly with soap and water for 15 minutes; remove contaminated clothing and wash before reuse.
Eye Contact: Immediately flush eyes with plenty of water for at least 10 minutes; consult physician.
Ingestion: Rinse mouth, avoid inducing vomiting, seek medical attention promptly.
General Notes: Provide this sheet to medical personnel; monitor for symptoms such as breathing difficulty, coughing, rash, or eye pain.
Suitable Extinguishing Media: Dry chemical, carbon dioxide, water spray, or foam
Specific Hazards from Combustion: Can emit hazardous fumes including nitrogen oxides, carbon monoxide, cyanide gases
Protective Equipment for Firefighters: Wear self-contained breathing apparatus and full protective suit
Firefighting Instructions: Move containers from area if it can be done safely; cool containers with water spray from a safe distance
Unusual Fire Hazards: Decomposition can generate toxic or flammable vapors; minimize exposure and prevent runoff from entering sewers
Personal Precautions: Evacuate area; ventilate space; avoid dust or vapor formation; prevent contact with skin or eyes
Protective Equipment: Suitable gloves, goggles or full-face shield, lab coat or chemical apron
Emergency Procedures: Stop leak if safe; prevent further leakage or spillage; keep away from drains and water bodies
Clean-Up Methods: Absorb with inert material (sand, diatomite); sweep up and place in proper waste container; wash spill area thoroughly
Environmental Precautions: Prevent product from entering soil, waterways, or storm drains to minimize environmental exposure
Safe Handling: Handle in well-ventilated area; minimize dust and aerosol generation; avoid contact with eyes, skin, and clothing
Safe Storage: Keep container tightly closed; store in cool, dry, and well-ventilated space away from incompatible substances (oxidizing agents, strong acids, bases)
Storage Precautions: Protect from direct sunlight and sources of ignition; maintain temperature between 2-25°C; avoid moisture exposure
Incompatible Materials: Avoid strong oxidizers, acids, acid chlorides, acid anhydrides, reducing agents
Special Requirements: Store in properly labeled containers; do not reuse empty containers for other chemicals
Control Parameters: No regulatory occupational exposure limits currently established for this compound; general workplace dust limits may apply
Engineering Controls: Use with local exhaust ventilation or chemical fume hood; implement eyewash and emergency shower in work area
Individual Protection: Chemical-resistant gloves (nitrile, neoprene recommended), protective eyewear (safety goggles), laboratory coat or chemical apron, respiratory protection in absence of adequate ventilation
Hygiene Measures: Wash hands before breaks and after handling; do not eat, drink, or smoke in work areas; regularly inspect PPE for integrity
Appearance: Colorless to light yellow liquid
Odor: Mild, faint organic odor
Melting Point: -10°C to 8°C (range may shift with impurities)
Boiling Point: Decomposes before boiling at 256°C
Flash Point: > 120°C (closed cup)
Flammability: Not highly flammable, but may burn under conditions with enough energy source
Vapor Pressure: Negligible at room temperature
Solubility: Miscible with water and organic solvents (ethanol, acetone)
Density: 1.07 - 1.11 g/cm3 at 25°C
pH: Approx. 7 (neutral in solution)
Partition Coefficient: log Kow not available; ionic liquids generally have low bioaccumulation potential
Chemical Stability: Stable under recommended storage and handling conditions
Conditions to Avoid: Prolonged heat exposure, open flames, high-energy sources, contact with moisture
Incompatible Materials: Strong oxidizers, acid chlorides, reducing agents, strong acids and bases
Hazardous Decomposition Products: Nitrogen oxides, carbon monoxide, hydrogen cyanide, other toxic gases upon combustion or thermal breakdown
Polymerization: Not known to polymerize
Acute Toxicity: LD50 (oral, rat): estimated 500-2000 mg/kg; harmful if swallowed
Skin Corrosion/Irritation: Causes moderate skin irritation on direct contact
Eye Damage/Irritation: Causes eye irritation, redness, and discomfort
Respiratory Sensitization: Data not sufficient, low volatility lowers risk but avoid inhalation
Other Effects: Prolonged or repeated skin contact may cause dermatitis; no known reproductive or mutagenic toxicity from current studies
Target Organs: May affect liver, kidneys with long-term, large exposures; no carcinogenic risks identified in published research to date
Aquatic Toxicity: LC50 (fish): estimated 10-100 mg/L; moderately toxic to aquatic organisms
Persistence and Degradability: Not readily biodegradable; stable in environmental conditions
Bioaccumulative Potential: Low bioaccumulation expected for dicyanamide salts
Mobility in Soil: High mobility; soluble in water and may move through soil to groundwater
Other Adverse Effects: Spills may cause short-term damage to aquatic life; minimize discharge to sewer or water systems
Waste Treatment Methods: Dispose of in accordance with local, regional, and national regulations at licensed hazardous waste disposal facility
Product Waste: Collect and deliver to approved chemical disposal service; avoid release into environment
Contaminated Packaging: Triple-rinse then dispose as hazardous chemical waste; do not reuse for other purposes
Special Precautions: Do not pour down drains, on land, or in watercourses; consult regulatory authorities for country or region-specific guidance
UN Number: Not assigned specific UN number for transport
UN Proper Shipping Name: Not regulated as dangerous good under IATA, IMDG, ADR shipping codes
Transport Hazard Class: Not classified as hazardous for transport
Packing Group: Not assigned
Special Precautions for Transport: Keep containers tightly sealed; protect from physical damage and temperature extremes; use proper labeling and documentation as required by customs or carriers
Safety, Health, and Environmental Regulations: Not listed on US TSCA inventory; check national inventory listings for other regions
OSHA Status: Not considered hazardous under US OSHA Hazard Communication Standard
EU Regulation: Not on Annex XVII or SVHC lists, but use REACH guidance for import or manufacture > 1 ton per year
Other Regulations: Not subject to SARA Title III, CERCLA, or state-specific chemical notification lists
Chemical Safety Assessment: Assessment carried out for manufacturing, laboratory, and professional use; end-users should implement SDS-based risk mitigation
