Product Name: 1-Hexyl-3-Methylimidazolium Thiocyanate
Chemical Formula: C10H17N3S
CAS Number: 666826-98-4
Synonyms: [HMIM][SCN]
Recommended Use: Solvent, extraction medium, electrolyte component, phase transfer catalyst
Supplier: Provide local supplier details as required by regulatory standards
Emergency Phone Number: Seek local emergency number as per country regulations
Hazard Classification: Irritant for skin, eyes, and respiratory tract based on ionic liquid properties; not acutely toxic but can provoke immediate skin or eye discomfort
Signal Word: Warning
Hazard Statements: Causes skin and eye irritation, may cause respiratory irritation, harmful to aquatic life with long lasting effects
Precautionary Statements: Avoid breathing dust or vapors; wear eye protection, gloves, and face mask; do not release to the environment; wash hands thoroughly after handling
GHS Symbols: Exclamation mark, aquatic toxicity
Chemical Name: 1-Hexyl-3-Methylimidazolium Thiocyanate
Concentration: >95%
Other Components: Trace impurities may include water or unreacted starting materials, present in very low quantities
Chemical Family: Imidazolium-based ionic liquids
Molecular Weight: 211.33 g/mol
Inhalation: Move person to fresh air, keep comfortable for breathing, seek medical attention if symptoms persist such as coughing or tightness in chest
Skin Contact: Remove contaminated clothing, rinse skin with plenty of water, use soap if available, seek medical help for irritation or burns
Eye Contact: Rinse cautiously with water for at least 15 minutes, remove contact lenses if present and easy to do, continue rinsing, seek medical attention promptly
Ingestion: Rinse mouth, do not induce vomiting, give water or milk to dilute if conscious, seek medical advice immediately
Symptoms to Watch: Irritation, red or watery eyes, redness or blistering of the skin, headaches, dizziness, breathing difficulties
Suitable Extinguishing Media: Use water spray, dry chemical, CO2, or foam, select extinguishing agents suitable for surrounding materials as product does not support combustion on its own
Specific Hazards: Thermal decomposition may generate toxic fumes, including nitrogen oxides, sulfur compounds, and organic fragments, risk increases in enclosed spaces
Protective Equipment: Firefighters should wear self-contained breathing apparatus and chemical-resistant clothing, avoid inhalation of smoke or fumes
Special Precautions: Avoid runoff into water systems, contain firefighting water to prevent environmental contamination
Personal Precautions: Use protective gloves, safety goggles, and respirators, remove sources of ignition, ventilate area well
Environmental Precautions: Prevent entry into soil, drains, or waterways, contain spill with inert absorbent, treat as hazardous waste
Cleanup Methods: Absorb with sand, earth, or suitable inert material, shove into labeled containers for proper disposal, wash spill site with water, ventilate area after cleanup
Decontamination: Use detergent solution for area followed by water rinse to remove all residues
Handling: Use personal protective equipment, handle in a well-ventilated area, avoid inhaling dusts, vapors, or fumes, wash hands after handling, do not allow contact with skin or eyes
Storage: Keep container tightly closed in a dry, cool, well-ventilated place, store away from strong acids, bases, oxidizing agents, and moisture, segregate from food and drink
Storage Conditions: Temperature below 30°C recommended, avoid direct sunlight and sources of ignition, label containers clearly and update inventory regularly
Incompatible Materials: Strong oxidizers, reducing agents, acid chlorides, water (may cause partial hydrolysis over time)
Engineering Controls: Use local exhaust ventilation, fume hoods or equivalent systems in laboratory or industrial settings, provide eyewash stations nearby; regular air monitoring for vapor or mist concentrations is beneficial
Respiratory Protection: Wear approved respirator with organic vapor/particulate cartridge if airborne concentrations approach recommended limits
Hand Protection: Chemical-resistant gloves made of nitrile, neoprene, or similar materials to prevent skin exposure
Eye Protection: Chemical safety goggles or face shield; contact lenses not recommended during handling
Body Protection: Wear lab coat or suitably resistant clothing, ensure closed footwear, frequent laundering of contaminated clothing
Hygiene: Prohibit eating, drinking, or smoking in work areas, wash hands thoroughly after use
Appearance: Pale yellow to colorless liquid or solid depending on storage moisture
Odor: Mild, characteristic, no strong pungency
Melting Point: Approximately 25-40°C (varies with purity and moisture content)
Boiling Point: Decomposes before boiling, typically above 250°C
Solubility: Miscible with water, soluble in many organic solvents
Vapor Pressure: Negligible at room temperature
Density: 1.05 – 1.12 g/cm³ at 20°C
pH (diluted): Neutral to weakly alkaline
Viscosity: Moderate to high, depending on temperature
Flash Point: >120°C, not easily flammable
Autoignition Temperature: Not determined, likely above 350°C
Explosion Limits: Not applicable due to ionic nature
Partition Coefficient (log P): Information limited, likely moderately hydrophilic
Chemical Stability: Stable under ambient storage conditions if kept dry and closed
Reactivity: Reactive with oxidizing agents, decomposition releases toxic gases at elevated temperatures
Conditions to Avoid: Extreme heat, moisture, direct sunlight, strong acids and oxidizers
Hazardous Decomposition: May emit poisonous gases such as hydrogen cyanide, sulfur oxides, nitrogen oxides when heated above decomposition point
Polymerization: Has not been shown to polymerize under normal operating conditions
Acute Toxicity: Oral LD50 (rat) estimated >2000 mg/kg; not acutely toxic but ingestion may cause gastrointestinal discomfort
Skin Corrosion/Irritation: May cause moderate irritation, prolonged exposure may provoke dermatitis
Eye Damage/Irritation: Causes irritation, risk of corneal injury on direct contact
Respiratory Effects: Inhalation of mist or vapor may irritate mucous membranes and respiratory tract, may aggravate asthmatic symptoms
Chronic Toxicity: No evidence for chronic toxicity; repeated exposures to high concentrations can cause sensitization
Sensitization: Skin or respiratory sensitization possible after repeated exposure based on structural analogues
Carcinogenicity/Mutagenicity/Reproductive Toxicity: No listings with OSHA, NTP, or IARC; no conclusive animal or epidemiological data as of the latest review
Target Organs: Skin, eyes, respiratory system
Aquatic Toxicity: Harmful to aquatic organisms, causes long-term adverse effects in the aquatic environment, LC50 (fish) estimated 1-10 mg/L
Persistence and Degradability: Not readily biodegradable, persists under standard environmental conditions
Bioaccumulation Potential: Not expected to bioaccumulate significantly due to ionic nature; chronic exposure could still be harmful
Mobility in Soil: Moderately mobile, soluble in water, potential to leach to groundwater
Other Adverse Effects: Limited information available, avoid release to surface water and municipal sewer systems, uncontrolled disposal is strongly discouraged
Disposal Methods: Incinerate in compliance with local, regional, and national regulations, do not dump untreated into sewers, groundwater, or surface water
Container Disposal: Decontaminate containers with detergent and water before recycling or disposal, treat rinse water as hazardous waste
Local/Regional Regulations: Follow chemical waste disposal protocols in your jurisdiction, consult environmental authorities for proper disposal channels
Unused Product: Encourage recycling or return to supplier if unused; avoid unnecessary accumulation and long-term storage
UN Number: Not regulated or assigned under standard transport regulations
Proper Shipping Name: Not classified as hazardous for international transport by air, sea, or land
Transport Hazard Class: Does not meet criteria for hazardous materials
Packing Group: Not applicable
Special Transport Precautions: Prevent container damage and leaks, use robust packaging, include accurate labeling, keep away from food and feedstuffs, ensure compliance with all relevant local and international shipping regulations
US Federal Regulations: Not specifically listed; subject to TSCA inventory, comply with SARA reporting if thresholds met
EU Regulations: Not currently classified under REACH as a registered substance; observe requirements for safe handling and notification of new chemicals
Labeling Requirements: Chemical name, pictograms, hazard and precautionary statements, supplier contact, emergency number
Occupational Exposure Limits: No established occupational exposure limits, recommend following good industrial hygiene practices and local rules
International Inventories: Notified or in process of notification in major global chemical registries, end users should review specific country requirements
