Material Safety Data Sheet: 1-Methoxyethyl-3-Methylimidazolium Trifluoroacetate

Identification

Product Name: 1-Methoxyethyl-3-Methylimidazolium Trifluoroacetate
Chemical Formula: C8H13F3N2O3
CAS Number: 1058160-97-6
Recommended Use: Laboratory chemicals, industrial formulation
Supplier: Contact standard chemical supplier for sourcing and support
Emergency Contact: Refer to company procedure for 24-hour assistance

Hazard Identification

Classification: Serious eye irritation, skin irritation, moderate acute toxicity
Signal Word: Warning
Hazard Statements: Causes skin and eye irritation; harmful if swallowed or inhaled
Pictograms: Exclamation mark (GHS07), corrosion (GHS05)
Precautionary Statements: Avoid breathing dust or vapor, wash exposed areas thoroughly after handling, wear protective gloves, eye protection, face protection

Composition / Information on Ingredients

Chemical Name: 1-Methoxyethyl-3-Methylimidazolium Trifluoroacetate
Concentration: 98-100% pure
Impurities: Minimal, negligible for occupational health risk
Other Identifiers: Ionic liquid, contains imidazolium and trifluoroacetate functional groups

First Aid Measures

Inhalation: Remove person to fresh air; provide oxygen if breathing is difficult; seek medical attention if symptoms continue
Skin Contact: Take off contaminated clothing; wash skin with soap and water for at least 15 minutes; contact a physician for persistent irritation
Eye Contact: Immediately rinse eyes with plenty of water for at least 15 minutes keeping eyelids open; seek urgent medical help
Ingestion: Rinse mouth thoroughly; never give anything by mouth if person is unconscious; call poison center or physician
Most Important Symptoms: Irritation, burning sensation in affected areas, possible headache or nausea following high exposure

Fire-Fighting Measures

Suitable Extinguishing Media: Water spray, foam, dry chemical, carbon dioxide
Unsuitable Extinguishing Media: High-volume water jet increases risks of spattering
Specific Hazards: May produce hazardous gases on combustion, including carbon oxides, nitrogen oxides, hydrogen fluoride, and toxic vapors
Protective Equipment: Full-face, self-contained breathing apparatus and full protective gear
Precautions: Avoid inhalation of combustion by-products; prevent contaminated firefighters’ runoff from entering drains or water sources

Accidental Release Measures

Personal Precautions: Wear gloves, goggles, and protective clothing
Environmental Precautions: Prevent material from entering drains, soil, or waterways
Methods for Containment: Absorb with inert material such as sand or earth
Methods for Cleanup: Collect spill using non-sparking tools; dispose of waste in labeled containers; ventilate area after cleanup; decontaminate surfaces as needed

Handling and Storage

Handling: Use in well-ventilated area; avoid contact with skin, eyes, and clothing; handle away from incompatible materials such as strong oxidizers or acids
Storage: Store in tightly closed container in a cool, dry, and well-ventilated place; keep away from sources of ignition and direct sunlight
Other Precautions: Keep container upright; label all storage vessels clearly; follow site-specific protocols for handling ionic liquids

Exposure Controls and Personal Protection

Exposure Limits: No established occupational exposure limits; minimize exposure via engineering controls
Engineering Controls: Provide local exhaust ventilation; use fume hood where possible
Personal Protective Equipment: Chemical-resistant gloves, lab coat, eye protection (goggles or face shield), and adequate respiratory protection in poorly ventilated areas
Hygiene Measures: Wash hands and exposed skin thoroughly after handling; remove contaminated clothing and wash before reuse; avoid eating, drinking, or smoking near work area

Physical and Chemical Properties

Appearance: Clear to pale yellow liquid
Odor: Faint, sweet or solvent-like aroma
Odor Threshold: Not established
pH: Neutral to slightly acidic (check with application-specific tools)
Melting Point/Freezing Point: Below room temperature (< 25°C)
Boiling Point/Range: Not precisely determined; decomposes before boiling
Flash Point: Above 100°C, not highly flammable
Evaporation Rate: Low
Flammability: Not easily ignited
Vapor Pressure: Very low
Relative Density: 1.2–1.3 (water = 1)
Solubility: Miscible with water and common organic solvents
Partition Coefficient (log Kow): Not available
Viscosity: Higher than water
Decomposition Temperature: Above 200°C, forms hazardous products

Stability and Reactivity

Chemical Stability: Stable under recommended storage and handling conditions
Reactivity: Reacts with strong acids, bases, and oxidizing agents
Conditions to Avoid: Elevated temperature, open flames, direct sunlight
Incompatible Materials: Strong oxidizers, mineral acids
Hazardous Decomposition Products: Carbon oxides, nitrogen oxides, fluoride compounds, possibly toxic organic vapors
Polymerization: Not expected under normal use conditions

Toxicological Information

Acute Toxicity: Ingestion, inhalation, or skin absorption may result in moderate toxicity; symptoms may include irritation, nausea, headache
Skin Corrosion/Irritation: Irritant; prolonged or repeated contact increases risk
Serious Eye Damage: Causes redness, tearing, discomfort; permanent damage possible with significant exposure
Respiratory Sensitization: Not expected, but high vapor concentration may cause respiratory tract irritation
Carcinogenicity: No evidence of carcinogenic potential based on available data
Mutagenicity: No data indicating mutagenic effects
Other Risks: Ingestion or absorption may impact central nervous system; always use recommended PPE

Ecological Information

Aquatic Toxicity: Potentially toxic to aquatic organisms; avoid direct releases to water systems
Persistence and Degradability: Slow to degrade under natural conditions; ionic liquids may persist in environment
Bioaccumulation: Not expected due to molecular structure, yet environmental monitoring advised
Mobility in Soil: Can migrate with water, attention needed to prevent groundwater contamination
Other Adverse Effects: No data on long-term ecological impacts; handle according to best practices for novel chemicals

Disposal Considerations

Waste Disposal Methods: Dispose as hazardous waste according to local, state, and federal regulations
Contaminated Packaging: Rinse containers thoroughly with suitable solvent before recycling or disposal; use appropriate labeling
Recommendation: Consult with licensed waste disposal contractor; avoid discharge to environment in any form
Special Precautions: Never dispose into municipal sewage or trash streams; keep waste in marked, sealed containers awaiting pickup

Transport Information

UN Number: Not classified under standard shipping regulations
UN Proper Shipping Name: Not regulated for transport
Transport Hazard Class: None specified; consult carrier for special rules
Packing Group: None designated
Environmental Hazards: Not considered a marine pollutant yet prevent bulk releases
Special Precautions for Transport: Use sealed, upright containers; secure loads to prevent tipping or spillage

Regulatory Information

OSHA Hazard Communication Status: Meets criteria for hazardous chemical
SARA Title III: Not subject to Section 302/313 reporting
TSCA: Not listed for commercial import; research and development restrictions may apply
REACH Status: Requires registration in some regions; users must verify compliance
Other Regulations: Observe site, state, and country-level workplace safety filings; refer to local environmental and chemical safety offices for specific responsibilities