Product Name: 1-Octyl-3-Vinylimidazolium Hexafluorophosphate
Chemical Formula: C15H27F6N2P
Synonyms: [OMIM][PF6], Ionic Liquid
CAS Number: 876463-21-1
Recommended Use: Solvent, Electrolyte, Research reagent
Manufacturer: Supplier name and address
Emergency Phone Number: Provided by distributor or specific regional poison control center
Product Code: Different suppliers assign various catalogue codes
GHS Classification: Skin Irritant (Category 2), Eye Irritant (Category 2A), Acute Toxicity Oral (Category 4), Aquatic Chronic Hazard (Category 3)
Signal Word: Warning
Hazard Statements: Causes skin irritation. Causes serious eye irritation. May be harmful if swallowed. Harmful to aquatic life with long lasting effects.
Pictograms: Exclamation mark, Environment
Precautionary Statements: Avoid contact with eyes, skin, and clothing. Do not breathe vapors or dust. Wash hands thoroughly after handling. Avoid release to the environment. Wear protective gloves, eye protection, and face shield.
Potential Health Effects: Shortness of breath, coughing, nausea, irritation of the upper respiratory tract, redness of skin and eyes.
Routes of Exposure: Inhalation, ingestion, skin and eye contact
Chemical Name: 1-Octyl-3-Vinylimidazolium Hexafluorophosphate
CAS Number: 876463-21-1
Concentration: ≥98% by weight
Impurities: Minor traces of 1-Octyl-3-vinylimidazolium derivatives, possible inorganic PF6- salts
Stabilizers or Additives: None reported
General Advice: Remove contaminated clothing and show this data sheet to the attending physician.
Inhalation: Move the exposed individual to fresh air immediately. Support breathing as required with oxygen or artificial respiration. Seek medical attention if symptoms remain.
Skin Contact: Flush exposed area with plenty of water and mild soap for at least 15 minutes. Remove contaminated shoes and clothes. Get medical help for persistent irritation.
Eye Contact: Rinse eyes cautiously under running water for a minimum of 15 minutes, holding eyelids open. Remove contact lenses if present and easy to do; continue rinsing and seek medical advice.
Ingestion: Rinse mouth thoroughly with water. Do not induce vomiting unless directed by medical personnel. Contact a physician or poison center immediately.
Main Symptoms: Irritation, redness, dryness, possible allergic reaction, nausea, coughing
Extinguishing Media: Use dry chemical, foam, carbon dioxide, or water spray. Do not use direct water jet on burning liquid.
Hazards from Combustion: Hydrofluoric acid, carbon oxides, phosphorus oxides, nitrogen oxides, toxic fluoride and imidazolium fumes may be released.
Protective Equipment: Full protective clothing and self-contained breathing apparatus required. Avoid breathing smoke and combustion products.
Fire-Fighting Instructions: Move containers from fire area if safe. Dike runoff to prevent environmental contamination. Stay upwind and cool exposed containers with water spray.
Flash Point: Data not available; consider precautionary measures for unknowns.
Personal Precautions: Use appropriate personal protective equipment. Avoid inhalation of dust, vapor, or mist. Ensure adequate ventilation. Evacuate surrounding area if large spill occurs.
Environmental Precautions: Prevent further leakage or spillage. Avoid discharge into drains, water courses, or soil. Notify authorities if product enters the environment.
Cleaning Procedure: Absorb with suitable inert material (sand, diatomaceous earth). Collect and transfer to containers for proper disposal. Wash spill site after cleanup. Do not generate aerosols. Use non-sparking tools and explosion-proof equipment.
Reporting Requirements: Follow local, regional, and national guidelines.
Handling: Operate in a chemical fume hood. Minimize dust and vapor production. Do not get into eyes, on skin, or on clothing. Wash hands after handling.
Storage: Store tightly sealed in a cool, dry, well-ventilated area away from incompatible substances including acids and strong oxidizers. Avoid exposure to moisture. Store in original containers. Protect from direct sunlight and sources of ignition.
Specific Uses: Research use only unless specified otherwise. Not for food, drug, or household use.
Exposure Limits: No specific occupational exposure limits established for this chemical.
Engineering Controls: Use appropriate exhaust ventilation to keep airborne concentrations below recommended limits. Emergency eye wash fountains and safety showers recommended near work area.
Personal Protection:
- Eye/Face: Chemical safety goggles with side shields, face shield as necessary
- Skin/Body: Nitrile or neoprene gloves, lab coats, chemical resistant footwear
- Respiratory: NIOSH-approved respirator for organic vapor and particulates if exposure limits may be exceeded
- Hygiene: Avoid contact with skin and eyes. No eating, drinking, or smoking in areas of use. Wash hands thoroughly
Appearance: Colorless to pale yellow liquid or oil
Odor: Mild, characteristic organic
Odor Threshold: Not determined
pH: Not applicable (neutral liquid)
Melting Point/Freezing Point: Information varies, approximately -20 °C
Boiling Range: Decomposes before boiling
Flash Point: Not established; presumed >100 °C
Evaporation Rate: Not available
Flammability: Not highly flammable, but combustible
Explosion Limits: Not available
Vapor Pressure: Expected to be low
Vapor Density: Not determined
Density: Approximately 1.20 g/cm3
Solubility: Slightly soluble in water; miscible with polar organic solvents
Partition Coefficient (log Kow): Not known
Decomposition Temperature: Above 200 °C
Viscosity: Moderate to high
Other Data: Ionic liquid; tends to absorb moisture from air
Chemical Stability: Stable under recommended storage conditions. Sensitive to extreme heat and moisture.
Possibility of Hazardous Reactions: Hydrolysis with release of toxic HF under moisture or strong acids.
Incompatible Materials: Strong oxidizers, water, acids, alkalis, moisture.
Hazardous Decomposition Products: Hydrofluoric acid, phosphorus oxides, carbon oxides, nitrogen oxides, imidazolium fragments.
Conditions to Avoid: Elevated temperature, contact with acids, direct sunlight, presence of water.
Acute Toxicity: No precise data for oral, dermal, or inhalation toxicity; avoid exposure.
Skin Corrosion/Irritation: Causes moderate irritation and possible dermatitis on prolonged contact.
Serious Eye Damage/Irritation: Risk of eye irritation with redness, tearing, or possible burns.
Respiratory Sensitization: May induce short-term irritation; no data for sensitization.
Ingestion Effects: May lead to nausea, vomiting, stomach upset.
Chronic Effects: No long-term data; regular inhalation or skin exposure could raise risk of organ effects.
Carcinogenicity: No evidence from animal or human studies.
Mutagenicity: Not tested
Reproductive Toxicity: No information
Other Effects: Allergic reactions possible in sensitive individuals
Ecotoxicity: Harmful to aquatic organisms with potential for long-lasting effects.
Persistence: Unlikely to degrade rapidly
Bioaccumulation: Limited data, but ionic nature can limit bioconcentration in fat tissue
Mobility in Soil: Moderately mobile; will follow waterways if released
Other Hazards: Does not break down easily; may persist in environment; not readily biodegradable.
Supplements: Avoid discharge to sewers, ground, or surface waters due to environmental risks.
Product Waste: Use registered waste collectors. Dispose of in accordance with local, regional, and national regulations. Incinerate in chemical incinerator equipped with afterburner and scrubber if permitted.
Contaminated Packaging: Triple rinse containers, then offer for reconditioning or incinerate with waste product residue.
Special Precautions: Avoid waste contact with soil or water systems. Label waste containers appropriately. Do not reuse empty packaging.
Additional Guidance: Seek input from hazardous waste management specialists regarding disposal options.
UN Number: Not assigned or not regulated for small amounts
UN Proper Shipping Name: Chemical, non-hazardous for air, sea, or road as per typical sample size
Transport Hazard Class: Not classified under UN recommendations for hazardous materials
Packing Group: Not applicable
Special Precautions: Use leak-proof, sealed containers. Keep away from incompatible goods.
Environmental Hazards: Contact designated authority for bulk shipments due to aquatic hazards.
EU Regulations: Not listed under Annex I of Directive 67/548/EEC. REACH status: consult supplier.
US Federal Regulations: Not listed as a hazardous substance under SARA Title III Sections 302, 313; not on TSCA Inventory, research use only.
Canadian Regulations: Not listed on DSL/NDSL or WHMIS controlled product list
Other Regulations: Consult regional regulations prior to use or transport. Safety data, exposure limits, and registration status may vary.
