Product Name: 1-Propyl-2,3-Dimethylimidazolium Tetrafluoroborate
Synonyms: [C3mim][BF4], Ionic liquid
CAS Number: 655723-69-0
Recommended Use: Laboratory reagent, solvent for chemical synthesis, electrochemical studies
Supplier Information: Chemical manufacturer or distributor contact details as provided on purchase
Emergency Contact: Refer to local poison center or supplier's emergency hotline for prompt advice
Classification: Serious eye irritation (Category 2A), Skin irritation (Category 2), Specific target organ toxicity—single exposure (Category 3), Not classified as a carcinogen or mutagen by current IARC or OSHA standards
Signal Word: Warning
Hazard Statements: Causes serious eye irritation, may cause skin irritation, may cause respiratory tract irritation, may be harmful if swallowed
Pictograms: Exclamation mark
Precautionary Statements: Avoid breathing vapors or mist, wash hands thoroughly after handling, use only outdoors or in well-ventilated area, wear protective gloves, clothing, eye protection
Chemical Name: 1-Propyl-2,3-Dimethylimidazolium Tetrafluoroborate
Concentration: 98–100% pure by analysis
CAS Number: 655723-69-0
Impurities: Trace moisture < 1%, hydrolyzed byproducts (< 0.1%)
Inhalation: Remove exposed person to fresh air, provide supportive care, seek medical attention if symptoms persist or worsen
Skin Contact: Remove contaminated clothing, wash affected area with plenty of soap and water, do not use solvents to clean skin, consult healthcare professional for irritation or rash
Eye Contact: Rinse cautiously with water for several minutes, remove contact lenses if present and easy to do, continue rinsing, seek immediate medical advice
Ingestion: Rinse mouth thoroughly, do not induce vomiting, call poison center or doctor if you feel unwell
Extinguishing Media: Water spray, alcohol-resistant foam, CO2, dry chemical
Hazardous Combustion Products: Decomposition releases toxic fumes of boron trifluoride, nitrogen oxides, hydrogen fluoride, carbon oxides
Fire Fighting Instructions: Evacuate area, keep upwind, fire fighters should wear full protective clothing and self-contained breathing apparatus
Special Hazards: Electrolyte spills in fire may accelerate combustion if absorbed in organic materials, risk of hydrogen fluoride release in closed spaces
Personal Precautions: Use chemical splash goggles and nitrile gloves, avoid breathing vapors, ventilate area
Environmental Precautions: Prevent release into soil, sewer, waterways
Clean-Up: Absorb spillage with inert dry material (sand, diatomite), collect into containers for disposal, wash spill area with water after cleanup, do not touch spilled material without proper protection
Handling: Handle in a chemical fume hood using appropriate protective equipment, avoid skin and eye contact, avoid inhaling vapors, keep containers tightly closed
Storage: Store in original container, tightly sealed, in a cool and dry area (<30°C), protected from moisture, segregated from acids, bases, and oxidizing agents, keep away from direct sunlight
Engineering Controls: Use in fume hood or with local exhaust ventilation, install emergency eyewash and shower stations nearby
Personal Protection: Wear chemical-resistant gloves (nitrile), safety goggles, laboratory coat, respiratory protection (NIOSH-approved respirator) if risk of inhaling vapor exists
Occupational Exposure Limits: No established limits for this compound, based on best practice with similar ionic liquids
Hygiene: Wash hands before breaks and after handling, do not eat, drink, or smoke during use
Appearance: Colorless to light yellow liquid
Odor: Mild, neutral, typical of ionic liquids
pH: Not applicable (liquid salt, not water-based solution)
Melting Point: 10–25°C
Boiling Point: Decomposes before boiling
Flash Point: >120°C (closed cup, estimated)
Solubility: Miscible with water, dissolves many polar and non-polar organics
Vapor Pressure: Negligible at room temperature
Density: 1.16–1.19 g/cm³ at 20°C
Viscosity: 40–60 cP at 25°C
Partition Coefficient: Not determined
Auto-Ignition Temperature: Not self-igniting under normal conditions
Chemical Stability: Stable under recommended storage conditions, sensitive to strong oxidizers and moisture
Reactivity: Avoid contact with acids, alkali, oxidizing materials, or water
Hazardous Reactions: Hydrolysis forms hydrogen fluoride and boron trifluoride
Decomposition: Elevated temperature, contact with water or acids triggers release of corrosive and toxic gases
Incompatible Materials: Inorganic acids, strong bases, oxidizers, water
Acute Toxicity: Oral LD50 (rat) > 2000 mg/kg, limited data on inhalation toxicity
Skin Corrosion / Irritation: May cause irritation and allergic reactions
Eye Damage/Irritation: Eye exposure can result in redness, pain, potential long-term damage
Respiratory Sensitization: Shortness of breath or throat irritation may be observed with high exposures
Chronic Effects: Long-term data limited; effects similar to related imidazolium salts include dermatitis on repeated exposure
Carcinogenicity: Not classified as carcinogenic by NTP, OSHA, or IARC
Mutagenicity and Reproductive Toxicity: Not expected based on current studies, data gaps remain for thorough assessment
Aquatic Toxicity: Classified as moderately hazardous to aquatic life with acute and chronic effects (EC50 10–100 mg/L for Daphnia magna)
Persistence and Degradability: Resists rapid biodegradation, persistent in aquatic and soil environments
Bioaccumulation: Low bioaccumulation potential in aquatic organisms
Mobility in Soil: Highly mobile in moist soil and sediments due to solubility
Other Ecological Effects: No specific evidence of biomagnification, monitoring recommended in sensitive environments
Disposal Methods: Collect and dispose of waste according to federal, state, and local regulations, incinerate under controlled conditions by a licensed facility
Contaminated Packaging: Rinse containers, offer for recycling where available or dispose with proper authority
Considerations: Do not discharge unneutralized material into sewers, waterways, or the environment
UN Number: Not classified as hazardous for transport under UN transport regulations in current form
Proper Shipping Name: Chemical, liquid, NOS (not otherwise specified)
Transport Hazard Class: Not regulated under IMDG, IATA, DOT for ground, air, sea, or rail where packed in limited quantities
Packing Group: Not assigned
Special Precautions: Protect containers from physical damage, store upright, avoid extreme temperatures and moisture during transit
TSCA Status: Listed or exempt from listing as per supplier declaration
REACH Status (Europe): Registered or pre-registered, may require notification dependent on use volume
Right To Know Components: Not listed specifically on state hazardous substance inventories (such as California Proposition 65)
Other Regulatory Information: This product subject to chemical hygiene standards in laboratories, applicable waste disposal rules, workplace safety notification requirements according to OSHA
