Product Name: 1-Propyl-3-Methylimidazolium Iodide
Chemical Formula: C7H13IN2
CAS Number: 7790-28-5
Synonyms: PMII, 1-Propyl-3-Methylimidazolium iodide ionic liquid
Recommended Use: Laboratory chemicals, chemical synthesis, materials research
Manufacturer/Supplier: Refer to supplier’s label
Contact Information: Emergency phone number listed on packaging, safety officer on-site or in lab directory
GHS Classification: Harmful if swallowed, causes skin and eye irritation, may be harmful if inhaled
Signal Word: Warning
Hazard Statements: H302 (Harmful if swallowed), H315 (Causes skin irritation), H319 (Causes serious eye irritation), H335 (May cause respiratory irritation)
Pictograms: Exclamation mark
Precautionary Statements: Wash hands thoroughly after handling, avoid breathing dust or vapors, wear eye protection, use gloves, do not eat, drink, or smoke when using the product
Hazards Not Otherwise Classified: Harmful to aquatic life
Chemical Name: 1-Propyl-3-Methylimidazolium Iodide
Molecular Formula: C7H13IN2
Purity: greater than 98%
Impurities: Trace amounts of imidazole derivatives or solvent residues, generally less than 1%
Component: 1-Propyl-3-Methylimidazolium iodide (Single ingredient substance)
Inhalation: Move person to fresh air, keep at rest, seek medical attention if symptoms continue such as coughing, dizziness or breathing difficulty
Skin Contact: Wash with lots of soap and water for at least 15 minutes, remove contaminated clothing, inform medical personnel if irritation or redness persists
Eye Contact: Rinse with water for several minutes, hold eyelids apart, consult a doctor if pain, redness, or vision changes occur
Ingestion: Rinse mouth, never give anything by mouth to an unconscious person, call poison center, seek immediate medical attention
Suitable Extinguishing Media: Water spray, foam, carbon dioxide, dry chemical powder
Unsuitable Media: Do not use water jet directly. Can spread fire in certain situations
Specific Hazards: Formation of toxic iodine or nitrogen oxides upon combustion, releases hazardous fumes
Protective Equipment: Self-contained breathing apparatus, full protective gear
Advice for Firefighters: Avoid inhaling combustion gases, keep drums cool with water spray, prevent runoff into drains
Personal Precautions: Use chemical-resistant gloves and goggles, avoid dust formation, ensure adequate ventilation, evacuate area if necessary
Environmental Precautions: Keep out of waterways, prevent product from entering ground or drains
Cleanup Methods: Scoop up spill with non-combustible absorbent (sand, earth), collect in sealed, labeled container, ventilate area, wash spill site with soap and water after cleanup, dispose in accordance with local regulations
Handling: Work in fume hood or well-ventilated space, minimize dust and vapor exposure, wash hands and face before eating or drinking, keep container tightly closed when not in use
Storage: Store in original, clearly labeled, tightly sealed container, keep in cool, dry spot away from incompatible substances (oxidizers, strong acids), protect from moisture and light, restrict access to trained personnel
Exposure Limits: No established OSHA/ACGIH limits
Engineering Controls: Use local exhaust ventilation, safety eyewash stations, keep lab air exchange sufficient
Personal Protective Equipment: Chemical splash goggles, resistant gloves (nitrile, neoprene), lab coat, long sleeves, avoid open sandals
Hygiene Measures: Remove contaminated clothing and wash before reuse, avoid ingestion, never pipet by mouth, keep away from food
Appearance: White to off-white crystalline powder
Odor: Nearly odorless
Melting Point: 120–140 °C
Boiling Point: Decomposes before boiling
Solubility: Soluble in water, alcohols, acetone
Vapor Pressure: Negligible at ambient temperature
Density: About 1.6–1.7 g/cm³
pH (1% aqueous): 4–6
Flash Point: Not flammable (no measurable flash point)
Partition Coefficient: Not available
Auto-ignition Temperature: Not determined
Chemical Stability: Stable under normal laboratory conditions, decomposes at high temperature
Reactivity: No strong reactivity under ambient laboratory uses
Conditions to Avoid: Excessive heat, exposure to strong oxidizers or acids, prolonged exposure to light
Hazardous Decomposition Products: Iodine, nitrogen oxides, carbon oxides during heat or fire
Polymerization: No known hazardous polymerization
Acute Toxicity: Not thoroughly studied; estimated LD50 for oral exposure in rats: 500–2000 mg/kg
Skin Corrosion/Irritation: Causes irritation on contact, may trigger allergic reactions in sensitive individuals
Serious Eye Damage/Irritation: May cause pain, redness, or blurred vision
Respiratory Sensitization: Dust or vapors can lead to respiratory tract irritation
Chronic Effects: Long-term data limited; repeated, unprotected use could trigger dermatitis or respiratory effects
Carcinogenicity/Mutagenicity: No data indicating carcinogenic or mutagenic effects
Target Organs: Potentially skin, respiratory system, eyes
Ecotoxicity: Harmful to aquatic organisms, limited information available on long-term impact, biodegradable to some degree
Mobility in Soil: Spills may leach through soil profile into water table
Bioaccumulation: No reliable data, considered low risk
Persistence/Degradability: May partially degrade in environment; avoid disposing in natural habitats
Other Adverse Effects: Do not allow material to reach sewage systems or water courses unnecessarily
Waste Treatment Methods: Collect and seal waste in labeled chemical waste containers, do not pour down drain,
Disposal: Follow local, state, and federal hazardous waste regulations for disposal
Contaminated Packaging: Triple rinse, remove or deface labels before discarding or recycling
UN Number: Not classified as hazardous for transport under most current regulations
UN Proper Shipping Name: Not regulated
Transport Hazard Class: None assigned
Packing Group: None
Environmental Hazards: Avoid releases to environment, not a marine pollutant
Special Precautions for User: Carry in tightly sealed, compatible containers, keep away from food, do not stack excess weight on package
TSCA: Compound listed for research and industrial use
EINECS/ELINCS: Registration numbers available for EU uses
OSHA: No specific standard
SARA Title III: Not listed as an extremely hazardous material
California Proposition 65: Not listed
Other Information: User responsible for regulatory compliance specific to intended use and location
Labelling Requirements: Proper hazard labeling, safety training for handlers, emergency response plan recommended
