1-Propylsulfonic-3-Methylimidazolium Dihydrogen Phosphate: A Ground-Level Look

Historical Development

Chemistry has a certain way of walking forward in unpredictable shoes. About two decades ago, the scientific world started to embrace ionic liquids for their unique ability to replace traditional solvents in high-performance settings. 1-Propylsulfonic-3-methylimidazolium dihydrogen phosphate, usually spoken of in the company of green chemistry conversations, emerged from this movement. Early papers, especially those in the 2000s, carried a sense of discovery, as researchers looked for salts that would stay liquid at room temperature and do away with old, environmentally messy processes. This particular compound came out of a need for stability, ionic conductivity, and good acidity. Institutions in Europe and Asia began pushing its study further, showing its promise across synthesis and electrochemical applications. Its development marked a shift, not just away from volatile organic compounds, but toward more resilient, customized chemistry.

Product Overview

Glancing at a clear, viscous sample of 1-propylsulfonic-3-methylimidazolium dihydrogen phosphate, or [PSMIM][DHP], you find a product aimed directly at researchers juggling environmental regulations and technical demands. Chemists reach for it as both a solvent and a catalyst. Its character blends the high ionic conductivity expected from modern ionic liquids with strong Brønsted acidity. The phosphoric acid anion contributes real-world utility in catalysis and separation science, providing a choice for those sidestepping corrosive mineral acids. The material’s reputational growth rides on this dual role—supporting both reaction and separation with less fuss than many alternatives.

Physical & Chemical Properties

This compound looks somewhat unassuming at first. Under normal lab conditions, it takes the form of a clear, nearly colorless, and viscous liquid. A closer look reveals a density hovering between 1.2 and 1.3 grams per cubic centimeter, with a melting point comfortably below room temperature, making storage and pouring less lab-intensive. Hydrophilicity stands out; water pulls it in easily and it dissolves rapidly. Its ionic nature brings high conductivity, useful in fields ranging from batteries to analytical chemistry. Heat does not change it in a hurry — decomposition temperature reaches over 250°C. Acidity stands at a practical pKa near 1, which reflects its usefulness in catalyzing esterification or hydrolysis. Viscosity increases as temperatures drop, and in hands-on work, this can slow down mixing or result in thicker reaction slurries. Chemical stability persists across a wide pH range unless exposed to strong oxidizers or reducers.

Technical Specifications & Labeling

Any bottle of this chemical worth buying must give more than just a name. Suppliers regularly publish a minimum purity of 98%, with water content under 1% according to standard Karl Fischer analysis. Impurities like residual starting imidazole or incompletely sulfonated byproducts typically register below 0.5%. Certificates of Analysis should carry details on pH, specific gravity, and elemental content (carbon, nitrogen, sulfur, phosphorus), since each element’s presence pivots into both regulatory control frameworks and technical functionality. Packaging usually demands either amber glass or high-density polyethylene, with each lot given a batch number, production date, expiry, and storage recommendations between 2–8°C to prevent hydrolytic degradation and unnecessary viscosity changes. Compliance with GHS, REACH, and other safety labeling rules remains non-negotiable, showing statements on environmental and human toxicity risk without marketing spin.

Preparation Method

Crafting this compound in the lab proves straightforward, but the reactions demand certain practical sensibilities. The process begins with 1-methylimidazole, which takes on the propanesulfonic group by reacting with 1,3-propanesultone in an organic solvent, often acetonitrile or toluene, under reflux conditions. The product, 1-propylsulfonic-3-methylimidazolium, forms quickly, and after washing away unreacted materials, the product is neutralized with phosphoric acid — dihydrogen phosphate supplies the critical anion. Careful, portion-wise addition is key since exothermic reactions and foaming accompany the acid quench. The end mixture receives repeated extractions, often with ethyl acetate, and vacuum drying to scrub out solvent and lingering moisture. In practice, larger installations have automated much of this, using parallel reactors with online analytics, but in smaller labs, hands-on handling and chromatography remain in play for final refinements.

Chemical Reactions & Modifications

This ionic liquid does not sit idle in the reaction flask. It activates carbonyl substrates, accelerates esterifications, and has helped researchers shave hours off old reaction timelines. Its sulfonic acid task force, paired with the phosphate anion, adds punch to acid-catalyzed reactions. Chemists in academia and industry often explore its use alongside recyclable solid catalysts, in two-phase systems, or even in biphasic extraction, leveraging its water solubility. Modifications center around tuning the alkyl chain on the imidazolium core or swapping the phosphate anion—sometimes for improved biocompatibility, at other times to bolster reaction selectivity. Combining it with other ionic liquids makes composite fluids with custom melting points, viscosities, or acid strengths. Cross-reaction with organometallic complexes or immobilization on solid supports continues to open doors for catalysis in high-value synthesis and biomass dissolution.

Synonyms & Product Names

Suppliers toss around quite a few handles for this chemical. Beyond its IUPAC designation, you’ll find it with catalog names like [PSMIM][H2PO4], 1-propylsulfonic-3-methylimidazolium phosphate, or simply imidazolium sulfonate dihydrogen phosphate. Trade names do not always help—listing as “Acidic Ionic Liquid G-45” or similar tags confuses more people than it helps. Inventory departments and customs regulators stick close to the established chemical name system and CAS numbers to sidestep shipping errors or compliance headaches. For researchers, maintaining clarity in labeling lab stocks prevents mix-ups with less acidic imidazolium-based liquids.

Safety & Operational Standards

Working with 1-propylsulfonic-3-methylimidazolium dihydrogen phosphate, I have found the main pain points appear not from volatility, but from skin and eye irritation. Safety data sheets warn of moderate irritant properties—this lines up with firsthand experience handling spills and splashes. Gloves meant for acids can withstand daily use, and fume hoods minimize inhalation risks, though at ambient temperature vapor pressure barely registers by comparison to volatile organics. Clean storage is essential, since moisture intrusion alters physical properties and shifts reactivity. Lab protocols call for air-tight containers, secondary containment, and prompt clean-up of any spills. Waste streams containing this material mix best with acidic liquid handling procedures and need neutralization before disposal, reflecting both regulatory expectations and a strong push toward greener solid/liquid separation or recycling options.

Application Area

I’ve seen researchers gravitate toward this compound in catalysis—transesterification of oils, ester synthesis, dehydration of sugars, and hydrolysis reactions all benefit from its strong, tuneable acidity and stability. Electrochemical folks use it as an ionic conductor in prototype fuel cells or batteries, gaining both ionic mobility and acid strength without corrosive fumes. Analytical labs load it into separation matrices for ion chromatography or as a modulator in capillary electrophoresis. Some teams use it to break down complex polymers or biomass, applying lower temperatures than traditional acids demand. Its recyclable nature takes work, but repeat-use studies show recovered material still carries catalytic activity after several reaction cycles, provided cleanup is thorough.

Research & Development

Most of my recent conversations with R&D staff circle back to customization. Groups modify the alkyl chain or alter the anion to meet targets in viscosity, acidity, or thermal stability for their projects. Patents roll out describing strategies for immobilizing this liquid on silica supports, aiming for easier recovery and reuse. Research teams also probe synergistic combinations with other ionic liquids or heterogeneous catalysts, hunting for better reaction rates or lower costs. Some focus on mechanistic understanding—using NMR, FTIR, and mass spectrometry to chart ionic association patterns and dynamics at various temperatures and concentrations. Funding agencies reward proposals that highlight environmental safety and process scalability, pushing the field toward practical use outside the lab’s four walls.

Toxicity Research

Toxicology profiles for ionic liquids often call for extra digging, and this compound joins a class where health and safety studies have not kept up with usage. Data from cell culture tests show mild cytotoxicity, with the sulfonic acid group and imidazolium ring linked to moderate cell membrane irritation at higher doses. Ecotoxicity studies in aquatic systems point to low-to-moderate risk, tempered by high water solubility—this allows easier removal from spills, but brings concerns for wastewater treatment if left unchecked. Chronic exposure data in mammals remain rare, but guidance from industry and government agencies steers users toward careful personal protection, short exposure times, and robust spill management.

Future Prospects

Ionic liquids like this one appear set for wider adoption in precision chemistry and green process design. Industrial players looking to streamline catalytic steps, lower solvent emissions, and boost recyclability have found serious value in this sector. Advancements in computational chemistry, in-situ monitoring, and big data analytics mean property prediction and process optimization keep improving year by year. Breakthroughs in scalability and economic recovery could open up new roles in biorefining, pharmaceuticals, and battery technology. Market signals, regulatory shifts toward sustainable chemistry, and consumer demand for cleaner products all nudge research and development in the right direction, holding out steady promise for a future filled with ever-more versatile, safer, and recyclable ionic liquids.



What is 1-Propylsulfonic-3-Methylimidazolium Dihydrogen Phosphate used for?

Behind the Chemical Name

Stepping into a laboratory, you spot rows of glass jars marked with labels that look like tongue twisters. One name sticks out: 1-Propylsulfonic-3-Methylimidazolium Dihydrogen Phosphate. The title rolls off the tongue only after a few tries, but in the world of green chemistry, this compound keeps popping up for a reason. Folks in the field call it an ionic liquid. Unlike table salt and sugar that stay solid unless dumped in water, this one stays liquid at room temperature. Now, why should anyone outside chemistry care?

Changing the Game in Green Chemistry

Traditional solvents often create headaches, both for people’s health and the environment. Think of the strong smell of paint thinner and the warnings about what happens if it spills down the drain. Scientists started looking for alternatives that work just as well, but don’t leave such a mess behind. That’s where these new “ionic liquids” step in. 1-Propylsulfonic-3-Methylimidazolium Dihydrogen Phosphate stands out for helping chemists clean up their act. Unlike toxic, flammable solvents, it barely evaporates and doesn’t catch fire easily, keeping work areas safer.

Getting Reactions Moving

In the world of manufacturing, speed and yield count for everything. This ionic liquid shows up again and again in research on making biodiesel, breaking down plant matter, or speeding up chemical reactions that normally take a lot of energy or time. For example, researchers have used it to help turn biomass—like leftover corncobs—into valuable chemicals or fuels. The liquid dissolves plant fibers where water or oil can’t. It’s proven much more efficient than old-school acids, and you can often use much less of it. Factories churning out cleaner products, in less time, with fewer leftovers to scrub out. That’s a practical win.

Recyclable—and Not Just Once

One of my own frustrations in the lab came from constantly restocking expensive chemicals that could only be used once before turning into hazardous waste. This isn’t a problem unique to my field. 1-Propylsulfonic-3-Methylimidazolium Dihydrogen Phosphate can be fished out and used over again in multiple cycles. That doesn’t only save money, it cuts down on what goes to hazardous waste sites. The fewer barrels of contaminated liquid headed out to processing plants, the better for neighbors and workers all around.

Barriers Left to Cross

Cost stops many new materials from moving beyond the laboratory. Some ionic liquids used to run at premium prices, shutting out wide adoption. Over the past decade, prices for specialty chemicals like this have dropped as demand grew. Widespread use calls for further investment in production methods, and clear data showing what happens to the material at the end of its life in real-world settings. I’d like to see more open studies on the long-term environmental effects, since the greenest solution on paper still needs a real-world stress test.

Looking Toward the Future

This isn’t just another exotic lab concoction. With companies chasing more sustainable ways to make fuel, plastics, and medicines, solutions that reduce waste offer hope. Skills learned through hands-on chemistry and the lessons of trial and error still matter. It’s encouraging to see tools like 1-Propylsulfonic-3-Methylimidazolium Dihydrogen Phosphate fitting into a wider toolbox for change, not just in universities, but in industry-scale settings. Smart choices in chemistry ripple far beyond the lab bench.

What is the chemical formula of 1-Propylsulfonic-3-Methylimidazolium Dihydrogen Phosphate?

Looking at the Formula

The chemical formula for 1-propylsulfonic-3-methylimidazolium dihydrogen phosphate comes out as C7H15N2O4PS2. You see this formula on research papers, chemical bottles, maybe even safety sheets. But a formula isn’t just letters and numbers—it shapes how scientists view the world, how industries use ion liquids, and how regulators keep labs and workplaces safe.

Why Chemistry Cares About This Stuff

I remember grinding through organic chemistry, staring at molecular models late at night, chasing a connection between chemical structure and real-world function. That connection becomes especially clear with a compound like this. Each part of the formula carries purpose. The imidazolium ring brings overall stability and unique reactivity, while the sulfonic group attached to a propyl chain improves the material's ability to dissolve in water or polar solvents. Methylation of the ring tailors how the molecule interacts with other ions. Dihydrogen phosphate gives charge, polarity, and the ability to shuttle protons around.

There’s a reason researchers keep revisiting ionic liquids: they come with promise for green chemistry—solvents that don’t pump harmful fumes into labs, recyclable catalysts, reusable ion conductors. Across Europe and Asia, studies point to more sustainable extraction of rare earth metals, safer cellulose processing, and even better battery electrolytes using these compounds. None of this works unless people trust the basics—the formula matches the bottle, the bottle matches the protocol, and everyone from technician to regulator knows what’s inside.

Formulas and Safety Walk Hand in Hand

Mixing up a chemical recipe isn’t like following a cooking show. A missing atom spells trouble. I’ve seen the confusion on faces when reports list the wrong salt or an ambiguous imidazolium compound. Fire marshal inspections often hinge on getting that formula right. Water reactivity, toxicity, and storage labels all tie back to C7H15N2O4PS2 being understood exactly. A safety data sheet built on vague terms leaves gaps in emergency response.

What Better Labeling Would Mean

Getting the chemical formula right enables labs to waste less, store smarter, and comply with evolving environmental rules. Barcode systems in university labs work best when paired with clear formulas, not just trade names. Students spot hazardous swaps before they happen. New research moves quicker when suppliers and buyers speak the same chemical language.

Clear labeling could cut costs by trimming avoidable delays. Ordering the wrong ionic liquid, only to discover it halfway through a synthesis, frustrates everyone. The right formula on paperwork lets purchasing agents source the right material without second guessing. I’ve watched seasoned chemists call back to double-check specs, because too often ambiguity creeps in.

Building Trust through Chemistry

A transparent approach grounded in clear chemical information means fewer lab accidents and improved reproducibility. Routine compliance inspections rely on those formulas to spot outdated or mislabeled stock. In competitive grant reviews, unambiguous documentation shows funding agencies the team handles chemicals responsibly.

Precision matters. Industry leaders and regulators never accept “sort of the right stuff.” The future of safer, greener, and more trustworthy laboratories depends on it.

What are the storage conditions for 1-Propylsulfonic-3-Methylimidazolium Dihydrogen Phosphate?

Why Storage Matters for This Chemical

Anybody who’s handled specialty chemicals in a lab or industrial setting knows that proper storage isn’t just a box-ticking exercise. One misstep can mean lost product, unexpected reactions, or even a safety incident. 1-Propylsulfonic-3-methylimidazolium dihydrogen phosphate—let’s call it “the ionic liquid” for now—can seem stable enough on a shelf, but it deserves real attention to detail when you plan long-term storage or frequent use. This stuff gets talked about for its uses in catalysis, green chemistry, and separation science, which ramps up the stakes for safety and quality.

Biggest Threat: Moisture and Contamination

This chemical is hygroscopic, meaning it pulls moisture from the air like a sponge in a hot kitchen. Humidity sneaks in and can mess with its concentration, create clumps, or shift its properties. If you keep it unsealed or cap it sloppily, you’ll return to a product that’s not fit for precise applications. Industries and universities lose more usable material to moisture than most people expect; you don’t want to join that group.

Solid Steps to Store Safely

Keep it tightly sealed: Always screw caps all the way home or use air-tight stoppers. Some labs use double containment—placing the main bottle inside a second sealed container—especially in humid climates. If you use a lot of it, buy in smaller aliquots so each bottle sees less air and opens less often.

Dry, cool environment: Find room temperature storage away from direct sunlight, steam pipes, and radiators. Heat breaks down chemicals over time. A cool, dry cabinet far from acid or base fumes beats a fancy glass display case every time. Moisture-absorbing packets—silica gel or molecular sieves—work wonders if you store the chemical for months at a stretch.

Skip the fridge unless the supplier says so: Cold isn’t always better. Some ionic liquids turn too viscous or even crystallize at low temperatures, making accurate dispensing a nightmare and recovery slow. Most manufacturers test stability at regular lab conditions (around 20–25°C), and unless your technical data sheet says otherwise, stick to these bounds.

Stay organized: Label clearly with all relevant info. Date of purchase, date first opened, and a lot number matter more than many realize. A badly relabeled bottle leaves everyone guessing about age and purity. With drift in properties, precise record-keeping keeps experiments reproducible and avoids using degraded material by mistake.

What Else Goes Wrong—and How to Fix It

Accidental mixing with solvents, chemicals, or even dust can sneak in if the bottle isn’t closed quickly after use. Once, while running a student lab, I lost half a batch to cross-contamination because two students mixed up lids. Ever since, I count lids at the start and end of every session—a small habit, but it saved hours and money.

Be careful about long-term plans. If you only need a little, split a bulk order with colleagues or write down a plan for consumption. Hoarding a big drum “just in case” leads to aging and waste—expired chemicals cost far more in disposal and lost research time than the savings from buying bulk.

Stay Informed for Safe Handling

Suppliers publish safety data sheets for a reason, and they update them every few years as testing improves. Sometimes, a formula tweak means new storage advice. I always pull the manufacturer’s recommendation off the official website before planning a new storage system. By double-checking those instructions each year, you guard against surprises—like shelf-life changes or updated hazards—while showing due diligence.

Proper storage for this type of ionic liquid isn’t rocket science, but it does call for routine, discipline, and a watchful eye. If you treat it with respect, it will pay you back in reliable, safe, and high-performance applications.

Is 1-Propylsulfonic-3-Methylimidazolium Dihydrogen Phosphate hazardous?

Understanding the Risks

Work in labs long enough and you start to recognize that every bottle—no matter how fancy the chemical name—carries risks. Take 1-Propylsulfonic-3-Methylimidazolium Dihydrogen Phosphate, which researchers call an ionic liquid. These substances have drawn a lot of attention in green chemistry circles because they tend not to evaporate, so they produce fewer fumes. That makes them sound safer than regular solvents, but people shouldn’t let their guard down around them.

You look at some material safety data sheets, and the information tends to be limited. Not every new compound gets full toxicology screening before hitting the shelves. This phosphate salt hasn’t been around as long as classic chemicals like acetone or benzene, so scientists still piece together its biological impacts. Early findings point out that it can irritate the skin and eyes on contact. Some studies show cell lines exposed to certain ionic liquids lose viability faster than control cells. For people working at the bench, that red flag means gloves and goggles aren’t optional.

The Environmental Piece

Talking about hazards, it makes sense to consider the world beyond the lab. Traditional organic solvents often become air pollutants, but ionic liquids, including this one, behave a little differently. They dissolve in water and don’t easily vaporize, but that trait sends them down the drain, not into the air. Now, research from environmental chemists in Europe reports evidence of toxicity to aquatic organisms, including freshwater crustaceans and worms, once these compounds seep into rivers. That turns a “green” solvent into a question mark if disposal isn’t handled properly.

The trouble is, modern wastewater treatment systems haven’t caught up with these newer molecules. Breakdowns can stall if the chemical structure clogs up the process. Fish and other creatures get hit with compounds their biology can’t break down, and that stress rolls up the food chain. Large-scale factories using 1-Propylsulfonic-3-Methylimidazolium Dihydrogen Phosphate ought to have robust waste management to keep these substances out of the ecosystem.

Worker Safety and Solutions

There’s also a real-world angle worth mentioning. Building good habits handling any type of chemical, new or old, makes a big difference. That means not assuming something is safe just because it doesn’t have a skull-and-crossbones on the label. I’ve watched new chemists get a rash from ionic liquids because they didn’t take skin contact seriously. Standard gloves hold up for routine use, but if you spill a lot, switching gloves more often makes sense.

Training staff to recognize hidden hazards helps. Periodic reviews of new research matter, too. As more is learned about how these chemicals interact with biological systems and the environment, labs can update protocols. For now, anyone using it should keep handling to closed systems whenever possible, wear proper PPE, and collect all waste for specialist disposal. At the industrial scale, investment in specialized filtration and destruction technologies can trap ionic liquids before they leave the plant.

Looking Forward

The drive for safer, greener chemistry isn’t going away. Substituting one hazardous solvent for another isn’t progress if the new one’s risks appear down the road. Research into alternative solvents demands more toxicology and environmental studies before widespread use. Chemists and companies have a responsibility—both legal and ethical—to put safety and sustainability ahead of simple convenience.

How is 1-Propylsulfonic-3-Methylimidazolium Dihydrogen Phosphate typically supplied or packaged?

Why Packaging Matters for This Ionic Liquid

In the world of chemistry, how a product lands on your lab bench says a lot about safety and the road it traveled. I’ve spent years running research projects, and the supply chain’s choices often leave their mark on the efficiency and safety we experience every day.

Let’s talk straight: 1-Propylsulfonic-3-Methylimidazolium Dihydrogen Phosphate is not a doorstep Amazon package. This ionic liquid pops up in catalysis, separation processes, and green chemistry. Each use demands a steady quality and purity—nobody wants a catalyst gummed up by mystery film or unforeseen water. That’s where packaging steps in, either keeping your project moving or tripping up results with unexpected headaches.

Liquid, Not Dust—or Why Containers Matter

Unlike powders you might scoop with a spatula, this ionic liquid needs a leak-proof vessel. In the labs where I’ve ordered and used it, amber glass bottles show up most often, sealed with PTFE-lined caps. The darker glass keeps UV light from slowly changing or degrading the material—a smart move, especially if bottles get shuffled onto open shelving. Some manufacturers ship it in HDPE bottles, but glass latches in that confidence labs need during storage.

Corrosive materials like this ionic liquid can chew through less robust packaging. Seeing a leaky or cracked container wastes money and time, but more importantly, once these liquids seep out, cleanup gets ugly. Injuries happen, equipment suffers, everyone’s day goes sideways. So, companies shipping high-purity chemicals stake their reputation on tight, tamper-evident seals and double-layered packing for transit. This isn't just bureaucracy—it's practical wisdom earned from accidents in the past.

The Problem with Bulk Orders

I’ve been in labs where a bulk drum of chemical sits in a corner, and it’s clear nobody’s thrilled about opening it. For high-purity, sensitive ionic liquids, drumming them out like road salt leads to headaches. Nobody wants to dip a clean pipette into a giant vat and wonder about cross-contamination. Most suppliers stick with manageable bottle quantities: 100 mL, 500 mL, sometimes a liter if you ask nicely and can show you’ll use it fast. For industrial-scale requests—think several kilos—steel or plastic drums line up, each with thick liners and sometimes controlled-atmosphere blanks to keep out air and moisture.

Keeping It Dry, Pure, and Labeled

Moisture kills the effectiveness of a sensitive ionic liquid. High-purity packaging includes desiccants in the shipping box, and bottles themselves tend to run with air-tight seals and even shrink-wrap around the neck for extra insurance. Accurate, readable labels hold the CAS number, batch ID, storage advice, and hazard pictograms. I’ve seen smart labeling save a lab tech from grabbing the wrong bottle more than once, especially after a long day. Keeping materials sorted and traceable matters to labs facing regulatory audits or internal safety checks.

How Labs Can Push for Safer, Smarter Packaging

If you’re on the receiving end, communication lines with suppliers can change the situation. Asking for smaller, multiple bottles helps reduce waste and contamination risk. Requesting certificates of analysis straight from the packaging run lets your quality control team dodge unneeded testing. I’ve seen teams negotiate tamper-proof seals or extra secondary containers, especially for international transit where rough handling is common. After all, a simple leak in transit can wipe out dollars and even harm reputations.

Good packaging comes down to thinking ahead—keeping chemical integrity, protecting lab workers, and ensuring nobody faces an ugly cleanup. Investing a little more upfront in packaging saves a mountain of trouble on the other end.

1-Propylsulfonic-3-Methylimidazolium Dihydrogen Phosphate