1-Propylsulfonic-3-Vinylimidazolium Chloride: Insights and Impact

Historical Development

Chemists often push the boundaries of what materials can do, and 1-propylsulfonic-3-vinylimidazolium chloride reflects that drive. Back in the 1990s, ionic liquids started attracting serious interest because of their unusual low volatility and unique solvation abilities. Researchers looked for ways to make salts that could function in liquid form at room temperature, giving rise to wide-ranging applications in green chemistry. The creation of functionalized imidazolium-based ionic liquids, including those with sulfonic acid groups, meant researchers could mix the desirable physical properties of ionic liquids with the practical benefits of Brønsted acidity. Over the past two decades, the field has grown from lab curiosity to essential reagent, with this compound emerging as a standard in catalysis and advanced material research. Its development mirrors the broader shift toward sustainable and multifunctional solvents and catalysts, a necessary reaction to challenges in both environmental standards and industrial innovation.

Product Overview

1-Propylsulfonic-3-vinylimidazolium chloride sets itself apart by marrying a sulfonic acid group to an imidazolium backbone, which changes not only its reactivity but also the tasks it handles in the lab. You find this substance as a faint yellow to off-white solid or sometimes as a viscous liquid, depending on its hydration or formulation state. Unlike many traditional reagents, it offers dual functionality: a tuneable ionic liquid and a source for further polymer or cross-linked material creation thanks to the vinyl moiety. Labs and manufacturers turn to this compound when the reaction calls for both ionic and acid catalysis or advanced separation technologies. Its unique vinyl group allows researchers to polymerize it, incorporating its acidity and ionic properties into larger molecular frameworks.

Physical & Chemical Properties

The substance boasts a melting point typically below 100°C, indicating its classification as an ionic liquid under certain conditions. Its substantial thermal stability supports use in demanding synthetic procedures. The chloride counterion ensures good water solubility, which gives the compound flexibility in aqueous-phase reactions. You’ll notice a dense, almost syrupy texture. From an electrochemical standpoint, 1-propylsulfonic-3-vinylimidazolium chloride demonstrates a broad electrochemical window and high ionic conductivity, qualities that become handy in fuel cells and batteries. Its highly polar nature lets it dissolve a wide range of organic and inorganic chemicals, an advantage in both formulation science and catalysis.

Technical Specifications & Labeling

Manufacturers typically provide products in purities above 98% with clear labeling about water content and potential impurities. Standard packaging avoids iron, copper, or other reactive metals, preventing unintended catalytic activity. The labeling follows strict chemical safety standards, listing hazard pictograms connected to skin and eye irritation, plus guidance for safe handling. Whether you get it as a pure liquid or a stabilized solid, technical datasheets spell out shelf life and recommended storage temperatures, usually cool, dry, and away from light.

Preparation Method

The most widespread way to prepare this substance starts with 1-vinylimidazole. Through an N-alkylation step, 1-vinylimidazole reacts with 1,3-propanesultone, building the propylsulfonic side chain. That intermediate sometimes undergoes a purification step involving ion exchange or solvent evaporation. Introducing hydrochloric acid transforms the sultone adduct into the chloride salt. Through careful control of pH and reaction time, chemists ensure the vinyl group remains unreacted and ready for future polymerization, while securing good yield and purity.

Chemical Reactions & Modifications

Few chemicals match the versatility of 1-propylsulfonic-3-vinylimidazolium chloride. It acts as both a Brønsted acid and a phase transfer catalyst. The vinyl group provides a hook for radical or cationic polymerization, seeding new materials with the ionic and acidic functional sites tightly anchored in the polymer backbone. Labs across the globe use it to make polymeric ionic liquids or as a crosslinker in hydrogels. Chloride exchange opens the door to swapping in other counterions, such as tetrafluoroborate, which changes performance in batteries or catalysis. Mixing this compound into multi-phase systems lets scientists run “one-pot” syntheses, lowering waste and simplifying purification.

Synonyms & Product Names

You may spot this product listed as [1-(3-sulfonic acid)propyl]-3-vinylimidazolium chloride, 1-propane sulfonic acid-3-vinylimidazolium chloride, or 1-(propylsulfonic)-3-vinylimidazolium chloride. In catalogs, some outlets refer to it by the shorthand “PS-VIM-Cl,” especially in polymer or electrolyte research documentation. A few niche suppliers market it under proprietary names aimed at the polymer electrolyte sector.

Safety & Operational Standards

Handling this chemical demands respect for its acidity and ion-exchange properties. Direct contact can provoke irritation to skin and eyes. Good practice includes reliable PPE—gloves, goggles, and lab coats—plus strict use of fume hoods during weighing or transfer. Disposal methods recommend neutralization before sending waste to chemical handling streams. For any large-scale use, spill procedures and eye-wash stations are essential. Safety data sheets encourage caution for those with respiratory sensitivities, since mist or vapor exposure over extended periods may cause issues. Monitoring and maintaining chemical storage areas—checking for leaks or cross-contamination—helps prevent unnecessary incidents.

Application Area

What started out as a specialty ionic liquid now covers a lot of ground. Researchers use it as a polymer precursor in proton-conductive membranes, aiming for high-temperature fuel cells or water electrolyzers. Labs employ it as an acid catalyst in organic synthesis, swapping out corrosive liquid acids for a safer ionic medium. Its role as a building block for ion-containing polymers supports everything from targeted drug delivery to membranes in chemical sensors. The chloride form’s high solubility also suits extraction science, letting chemists selectively separate metal ions or other reactive species. In the environmental space, these ionic liquids sometimes help in removing tricky contaminants where standard solvents fall short.

Research & Development

Academic labs and private R&D teams have spent the last decade finding new uses for this chemical. It’s not uncommon to see journal articles on polymerized ionic liquid networks where this compound runs as the core monomer. Scientists keep working on blending this material into block copolymers, stretching for better mechanical properties in membranes. There’s been a push toward using these compounds in lithium-ion and next-generation batteries to increase ion mobility and longevity. Project teams studying biocompatible materials often try grafting this moiety onto scaffolds aimed at tissue engineering or advanced wound coverings.

Toxicity Research

Though it's not a common household item, understanding toxicity matters just as much in the lab as anywhere else. Early toxicity studies show low acute oral and dermal toxicity compared with many traditional acid catalysts. Chronic exposure evaluations, though, highlight the need for caution since long-term effects on aquatic environments and higher organisms remain under-studied. Some breakdown products generated under strong thermal or oxidative stress may have greater toxicity, so disposal and containment protocols require thoughtful attention. Safety testing continues not just for humans, but also with environmental assays to ensure runoff or accidental spills won’t threaten local water systems.

Future Prospects

Rising demand for greener, safer, and more customizable chemical processes puts multifunctional ionic liquids like 1-propylsulfonic-3-vinylimidazolium chloride at center stage in many new research programs. The need for robust, proton-conducting polymers in hydrogen energy or sensors won't ease up soon. Integration into battery and supercapacitor technology appears to hold real promise, especially as scientists look for alternatives to traditional salt-based electrolytes. There’s also growing interest in how these compounds can support carbon capture, advanced separations, and catalytic recycling—fields crucial for reaching sustainability targets. As environmental agencies tighten rules and companies seek non-toxic replacements for bulk acids and solvents, these materials look set to find more uses in both specialty and mainstream industries. Keeping the focus on toxicity, recyclability, and cost-effective scale-up will steer the next set of breakthroughs for this and related chemicals.



What is the main application of 1-Propylsulfonic-3-Vinylimidazolium Chloride?

A Closer Look at a Popular Catalyst

In the world of chemistry, some substances punch above their weight. 1-Propylsulfonic-3-vinylimidazolium chloride stands out in this way, especially in the field of catalysis where it draws attention thanks to its unique structure and reactivity. Many researchers, including myself during my time in a university lab, have seen the value it brings to synthetic routes that once felt tedious. Taking a closer look at the work it does explains why it has found a steady place in research labs and, more recently, in some scale-up processes.

How This Compound Drives Progress in Organic Synthesis

Chemistry never happens in a vacuum. The shift toward greener processes has highlighted the need for catalysts that minimize toxic waste and provide selectivity in reactions. This compound delivers both. Its makeup—a hybrid of ionic liquid and acid functionality—lets it act as a solid acid catalyst, especially useful in heavy-duty organic reactions like esterifications, alkylations, and even some challenging dehydrations.

My experience with this ionic liquid-based catalyst came during the process of synthesizing biodiesel. Conventional acid catalysts used to mean time-consuming separations and boatloads of waste solvent. Swapping in 1-propylsulfonic-3-vinylimidazolium chloride offered an opportunity for reuse and brought the overall yield up. Its stability in both aqueous and non-aqueous media came as a revelation. The absence of corrosive vapors also made the lab a safer place to work, which isn’t always the case when using traditional mineral acids.

Why Choose This Catalyst?

No researcher likes a one-off catalyst—recycling and recovery cut down costs and cut out headaches. This is where the chloride version of this imidazolium salt really shines. After reaction, its separation from product mixtures is straightforward because of its ionic nature. Labs working on continuous flow synthesis have been especially quick to adopt it, since easy catalyst recovery helps with scale-up and compliance with stricter environmental rules. Some academic reviews say these catalysts can be reused up to five times without losing much power, which aligns with what I observed in the lab.

One peer-reviewed study in the journal Green Chemistry demonstrated that using imidazolium-derived sulfonic catalysts in esterification produced less than half the waste compared to traditional mineral acids. If you care about energy consumption, the news is even better—reaction times drop significantly thanks to the selectivity of the active sites present in these salts.

Challenges and Potential Solutions

No tool is perfect. Sourcing these ionic liquids still costs more than picking up bulk mineral acid from the chemical supplier. Some researchers have also pointed out leakage issues, where the catalyst dissolves into the product phase, especially if a reaction runs at higher temperatures. This means both extra purification and lost catalyst for the next run.

One approach that looks promising comes from combining the chloride salt with solid supports, like silica gel. Anchoring the active catalyst to a surface pulls down leaching, and helps with recovery using simple filtration. Labs that use this method report less catalyst loss and even greater batch-to-batch consistency, making the process more attractive for industrial adopters. The opportunity now sits in finding cost-effective ways to prepare and support the catalyst on a larger scale, a topic gaining ground at recent chemical engineering conferences.

Looking Forward

Each time a new catalyst lands in the toolbox, chemists weigh its cost, reactivity, and environmental footprint. 1-Propylsulfonic-3-vinylimidazolium chloride checks off a lot of the right boxes for researchers working toward scalable green chemistry. Factoring in its advantages against the backdrop of industrial demands, the case for its continued investment starts to look pretty strong.

What is the chemical structure or formula of 1-Propylsulfonic-3-Vinylimidazolium Chloride?

Why Chemistry Gets Practical

Organic chemistry in the lab often feels like a puzzle, and understanding ionic liquids makes it even more interesting. 1-Propylsulfonic-3-vinylimidazolium chloride shows how thoughtful chemical design meets real-world demand. Organic syntheses, green chemistry, and catalysis all lean on these kinds of molecules to move science forward. In my own lab work, ionic liquids like this compound stand out for their clever combination of functionality, tunability, and environmental safety.

The Chemical Formula: Putting Atoms Together

Let’s break it down. The cation part—the 1-propylsulfonic-3-vinylimidazolium—has an imidazolium ring at its core. At the 1-position on that ring, you find a propyl chain attached to a sulfonic acid group (–SO3H). The 3-position features a vinyl group (–CH=CH2). Writing this out, the core cation becomes C9H15N2O3S+, balanced by a single chloride ion (Cl).

To lay it clearly: the complete formula for the salt adds up to C9H15N2O3SCl.

Why This Structure Matters

Many researchers see the value in molecular flexibility. On one end, the vinyl group can do more than just sit there. A synthetic chemist can use it in polymerization. That means you get polymers with built-in ionic conductivity. In advanced battery research and fuel cell projects, I’ve seen this property boost performance and reduce environmental impact compared to older, more toxic solvents.

The propylsulfonic arm changes the game by offering strong acidity and hydrophilicity. This tweak shapes how the compound interacts with water, metals, and other molecules. Working on catalyst development, I’ve relied on the –SO3H function to anchor active metal complexes. The ionic liquid’s chloride counterion stays stable, so you avoid unexpected reactivity that might spoil results.

Challenges and Solutions in Real Application

Every molecule brings its own hurdles. These ionic liquids sometimes cost more to produce than simple salts. Making sure they deliver on their eco-friendly promise can get tricky if their synthesis depends on hazardous starting materials. Labs that can source greener feedstocks make the process safer and give researchers a cleaner conscience. Regulators and journals are demanding more transparency about how compounds are made, not just what’s in the flask at the end.

It’s easy to think about chemical structure as a matter of pure curiosity, but real benefits grow from careful design. Materials scientists and researchers develop these compounds with aims like reducing hazardous waste, improving selectivity in chemical processes, and stepping up to the next generation of renewable technologies. From synthesizing better catalysts to advancing energy storage, getting the structure right fuels progress. Focusing on composition, not just performance, lifts both scientific integrity and safety.

Looking Ahead and Sharing Knowledge

A strong grasp on structure lays the groundwork for breakthroughs. Students, educators, and industry veterans all win when research puts clear chemical facts on the table. Academic papers detailing synthesis and structural confirmation—using techniques like NMR, FTIR, and mass spectrometry—support trust and reproducibility. For anyone working with new ionic liquids in the lab, the most lasting lesson comes from hands-on learning and critical peer conversations.

How should 1-Propylsulfonic-3-Vinylimidazolium Chloride be stored?

Why Storage Matters

Dealing with chemicals isn’t just about knowing formulas and numbers. Anyone who has worked with complex compounds like 1-Propylsulfonic-3-Vinylimidazolium Chloride understands that a simple mistake in storage can turn an expensive bottle of specialized material into a useless hazard. This isn’t an abstract concern. A poorly closed lid in a humid lab once cost my team hours of clean-up—and a week of lost research. Safety and effectiveness kick off in the storage room, not just at the bench.

Environmental Factors to Control

Moisture likes to sneak into open containers every chance it gets. This compound won’t tolerate damp conditions—moisture causes clumping and sometimes chemical breakdown. I always use a tight-sealing cap and tuck bottles away on a shelf in a desiccator. Dry, indoor air works best. This approach lines up with basic industry recommendations and sharply reduces wasted product.

Temperature swings also cause trouble over time. A spot away from radiators and sunlight works best. Keeping bottles at standard room temperature, usually between 20–25°C, protects the material. I avoid the refrigerator. Cold storage sometimes creates condensation when bottles warm up, defeating the purpose of keeping things dry. More than once, a bottle sweating after coming out of a cold storage ruined the rest of the batch.

Away from Sunlight and Reactives

Sunlight doesn’t just fade labels—it can promote decomposition or change the purity of the chemical. I’ve always had better luck placing chemicals away from the front of shelves, so random rays cannot strike the bottle. Before reorganizing one shared lab, I caught a vinylimidazolium compound left near a window; the discoloration was obvious, and the bottle’s contents turned useless for our experiments.

There’s a reason labs store incompatible materials in separate cabinets. Strong oxidizers, acids, or bases should not sit next to ionic liquids. Accidental mixing—especially if bottles leak—triggers nasty reactions. Clear labels and good record-keeping matter just as much as the shelf. A little extra care saves a lot of hassle, something I learned after a single mislabeled shelf forced an afternoon evacuation from chemical fumes.

Best Practices Start Small

Chemicals rarely demand fancy storage systems—just basic discipline and good training. I always double-check that new lab members understand which containers need an extra pinch of caution. Packing bottles with silica gel packets helps absorb stray moisture. Every few months, I check containers for leaks or discoloration. Tossing questionable materials right away, instead of hoping for “one last use,” keeps everyone safer.

Labeling might feel tedious, but in busy settings bottles swap shelves and friends borrow things “just for a minute.” A clear date and name on each bottle helps track age and ownership. Storing smaller quantities reduces risk and waste. Fewer headaches, less clean-up, and safer science follow good storage habits.

Solutions for Smooth Operation

Routine counts. Regularly checking the chemical storage area catches issues early: leaky caps, broken jars, shift in smells. Staff training turns theory into muscle memory. Good relationships with suppliers mean you can always double-check product sheets for updated advice—a quick phone call often saves a batch when uncertainty creeps in.

Science thrives on consistency. Proper storage of compounds like 1-Propylsulfonic-3-Vinylimidazolium Chloride keeps experiments honest, budgets intact, and people safe. From dry shelves to sharp labels, these habits aren’t just rules—they add up to smoother, more reliable research.

Is 1-Propylsulfonic-3-Vinylimidazolium Chloride soluble in water or other solvents?

Getting to Know the Compound

1-Propylsulfonic-3-vinylimidazolium chloride stands out as an ionic liquid. These materials offer alternatives to traditional organic solvents. Many researchers look to ionic liquids when greener methods are needed or specific chemical behavior is required. I once ran into this compound during a project on catalyst supports, and the topic of solubility came up right away — knowing if a compound dissolves in water or other common solvents decides which experiments actually get off the ground.

What Solubility Looks Like Here

This compound features both a chloride ion and a sulfonic acid group attached to a vinylimidazolium ring. You get a polar cation and a polar anion in the same package, which pushes many people to assume it will dissolve in polar solvents. It makes sense — strong ion-dipole interactions often pull these salts into solution. Most ionic liquids behave as expected in water and other highly polar environments, but structure always shifts the specifics. For people working in the lab, it isn't much use guessing if a synthesis or extraction relies on effortless mixing.

What the Research Shows

Literature points out that 1-propylsulfonic-3-vinylimidazolium chloride displays high solubility in water. Work published in journals such as the Journal of Molecular Liquids lists its water solubility as almost complete — you mix it in, and it goes right into solution even at fairly high concentrations. Experiments testing solubility in methanol and ethanol report something similar, which makes sense since both solvents have strong polarity and accept ions into their hydrogen bond networks. Acetonitrile and dimethyl sulfoxide also pull a great deal of the salt into solution.

Try dissolving it in less polar solvents like ether, hexane, or toluene and it doesn’t go well. The strong ionic character just doesn’t match up with the weakly interacting environment of non-polar solvents. In everyday practice in the lab, I quickly found water or methanol beat all alternatives for getting the stuff dissolved, letting me set up my reaction without fighting solubility limits.

Why Solubility Drives Research Choices

Solubility shapes more than just the question of what flask to use. Take the case of designing catalysts with this material: researchers want the ionic liquid to mix perfectly with their support media, often silica. If water carries the active component everywhere in the mixture, reactions occur evenly and active sites form where they should. Without predictable solubility, unexpected clumping leads to uneven surfaces, hurting catalytic efficiency and repeatability.

Techniques like solvent extraction, chromatography, and electrochemical setups all count on matching the solubility of your material to the working medium. A friend once struggled scaling up a reaction because the ionic liquid’s poor solubility in ethanol ruined the process. Switching to water brought immediate improvement. Knowing what goes where ensures less wasted time and effort.

Supporting Responsible Use and Progress

The green chemistry field points to ionic liquids as a tool for reducing volatile organic compounds and hazardous waste. Understanding which solvents dissolve these materials supports the safer design ethos at the core of modern synthesis. Transparency about such behavior, including publishing open methods and solubility data, means teams don’t duplicate failed efforts or face unexpected hazards from poorly characterized mixtures. Following ethics laid out by the chemical safety community, reporting both effective and non-effective solvents for ionic materials backs up reproducibility and quality.

How to Improve the Situation

Teams benefit from better reporting in academic and application-oriented papers. Far too often, solubility gets only a line in supplementary information, if at all. I encourage researchers to post both numbers and methods online, helping smaller labs and new startups avoid pitfalls. Companies synthesizing or selling ionic liquids like this one support progress by making their own solubility data easily available. Industry groups could take up the challenge by building shared databases on solvent compatibility, much as pharmaceutical companies document drug properties for easier review and regulation.

What are the safety and handling precautions for 1-Propylsulfonic-3-Vinylimidazolium Chloride?

Real Risks, Not Just Red Tape

Working with chemicals like 1-Propylsulfonic-3-vinylimidazolium chloride feels routine in a lab, but the risks don’t disappear with familiarity. This ionic liquid pops up in plenty of research and production applications for its unique properties, especially in the fields of catalysis and material science. The catch: just because it behaves differently from traditional acids or solvents doesn’t mean it treats your health and well-being more gently.

The Health Hazards Lurk in the Details

This compound isn’t some benign salt. It can irritate the skin, eyes, and respiratory tract, and swallowing it makes things worse. Years ago, I watched a grad student splash a drop on her wrist; she hesitated, shrugged it off, and paid with an angry rash by lunch. No chemical becomes routine enough to take lightly—not on my watch or yours.

The Right Personal Protection

The backbone of good safety in the lab starts with gloves, goggles, and a decent lab coat. The chemical resists some solvents, but it’s no match for your mucous membranes, so a face shield helps during transfers. Nitrile gloves have always served me well for this kind of salt, outlasting latex and offering a solid barrier.

This isn’t the moment to get lazy with ventilation. The compound doesn’t throw off fumes on its own, but heating it or letting the dust float around makes breathing dangerous. A chemical fume hood earns its keep, especially during transfers, weighing, or heating.

Don't Skimp on Storage

Even a small spill adds up to a lot of hassle. Moisture plays tricks with many ionic liquids, 1-Propylsulfonic-3-vinylimidazolium chloride included, and the hygroscopic nature means it grabs water from the air, degrading its quality and handling properties. Keep the bottle sealed tight in a cool, dry space. My team always uses air-tight containers, far from acids and bases, to stomp out unexpected reactions. A simple desiccator helps for longer-term storage, reducing unnecessary risk.

Spills and Disposal: The Unseen Test

Every chemical user faces moments where something goes wrong. I remember a small spill behind a balance—left unsupervised, it etched the aluminum pan and left a crusty mess. Absorb spills with inert materials like vermiculite. Don’t reach for paper towels. Sweep up solid waste and deposit it in a chemical waste bag, not regular trash. Avoid rinsing down the sink, since the environmental impacts can linger and travel. Your waste stream reflects your integrity as much as your science does, so link up with a certified hazardous waste disposal provider.

Think Beyond the Label

Safety data sheets sit on the shelf for a reason. I’ve learned: updates come fast, new findings show up, and older sources miss new hazards. Every time a researcher joins my lab, we run through real-world scenarios—nothing drilled in matters until you face a real spill or exposure. Trust, but verify: stay up-to-date on best practices, and never lean on experience alone. Good habits make the difference between a safe day’s work and a costly mistake, and nobody else can shoulder that responsibility for you.

1-Propylsulfonic-3-Vinylimidazolium Chloride