MSDS for 1-Propylsulfonic-3-Vinylimidazolium Chloride

Identification

Product Name: 1-Propylsulfonic-3-Vinylimidazolium Chloride
Synonyms: PS-VIM-Cl
Chemical Formula: C8H15ClN2O2S
Structure: Imidazolium cation, propylsulfonic substituent, vinyl group, associated with chloride anion
Intended Use: Laboratory reagent, catalyst carrier, potential ionic liquid applications
Manufacturer Contact: Reach out to supplier for emergencies, product queries, and technical advice
Emergency Phone: Refer to supplier for direct emergency contact
Recommended Restrictions: Not for high volume commercial distribution or untrained public use

Hazard Identification

GHS Classification: Irritant to eyes, irritant to skin, possible respiratory tract irritant
Signal Word: Warning
Label Elements: Exclamation mark, hazardous to eyes and skin
Hazard Statements: Causes moderate skin irritation, causes eye irritation, may cause respiratory irritation on dust or fume exposure
Precautionary Statements: Avoid skin contact, avoid inhalation, keep container tightly closed, use only with adequate ventilation
Potential Health Effects: Eye burning sensation, skin redness, sneezing or sore throat from vapor or dust, no chronic exposure data yet
OSHA Status: Not listed as a carcinogen or mutagen, but treat as a hazardous laboratory chemical

Composition / Information on Ingredients

Chemical Name: 1-Propylsulfonic-3-Vinylimidazolium Chloride
CAS Number: 1370919-44-6 (as reported in limited academic sources)
Impurities: Laboratory synthesis might carry imidazole, sulfonic acid, chloride ions, trace solvents, water
Concentration: Greater than 98% as supplied for research or custom application
Stabilizers/Additives: No routine additives reported
Formulation Type: Solid powder or viscous liquid, depending on moisture content and purity

First Aid Measures

Eye Contact: Flush gently with water for at least 15 minutes, remove contact lenses if possible, seek medical attention if discomfort persists
Skin Contact: Wash with plenty of soap and water, remove contaminated clothing, monitor for persistent irritation, medical assessment if symptoms worsen
Inhalation: Remove person to fresh air, loosen clothing, seek medical care if breathing trouble or coughing continues
Ingestion: Rinse mouth, do not induce vomiting, seek immediate professional medical advice, give water only if victim is fully conscious
Notes for Medical Personnel: Symptom-based treatment, consider potential for chemical irritation but no systemic poison data
Emergency Facilities: Eyewash stations, deluge showers, personal protective gear available in work area

Fire-Fighting Measures

Suitable Extinguishing Media: Carbon dioxide, dry chemical powder, foam, water spray for surrounding fire
Unsuitable Extinguishing Media: Do not use water stream directly on product if it may disperse or cause splashing
Specific Hazards: Burns may release toxic gases such as nitrogen oxides, sulfur oxides, hydrogen chloride
Special Protective Equipment: Firefighters wear self-contained breathing apparatus, full turn-out gear
Thermal Decomposition Products: Incomplete burning releases toxic fumes and particulate matter
Explosion Hazard: Not classified as an explosive; colonized dust in air may form combustible mixture under rare conditions
Firefighting Instructions: Approach from upwind, keep containers cool by spraying with water, contain runoff to prevent environmental contamination

Accidental Release Measures

Personal Precautions: Wear gloves, goggles, lab coat, dust mask if handling powder form
Evacuation: Clear unnecessary personnel from area
Environmental Precautions: Prevent spill entering waterways or drains, contain with spill socks
Cleanup Procedures: Collect substance using inert absorbent like sand or vermiculite, shovel into labeled waste container, wipe surfaces with wet cloth
Ventilation: Use local exhaust or open windows to disperse vapors if product becomes airborne
Disposal: Follow waste disposal regulations, do not dump in sinks or storm sewers
Emergency Procedures: Report sizable releases to environmental or safety authority as required

Handling and Storage

Precautions for Safe Handling: Avoid skin and eye contact, prevent inhalation, cap containers tightly after use, do not eat or drink in handling area
Incompatibilities: Avoid strong oxidizers, strong bases or acids, oxidizing metals; attacks unprotected metals with moisture
Handling Equipment: Use only clean, dedicated glass or compatible plasticware
Storage Conditions: Keep in original container, store in dry, cool, well-ventilated spot, avoid extremes of temperature
Storage Life: Recommended to use within one year if stored properly, monitor for clumping, discoloration, odor
Transfer Techniques: Use spatulas or pipettes that do not react with chlorides or sulfonates

Exposure Controls and Personal Protection

Engineering Controls: Work inside ventilated fume hood or use effective local exhaust
Personal Protective Equipment: Nitrile or neoprene gloves, chemical splash goggles, closed-toed shoes, flame-resistant lab coat
Respiratory Protection: Dust mask or approved respirator if dust or fumes present
Eye/Face Protection: Chemical safety goggles, face shield for large volume or splash risk
Skin Protection: Glove material selected for breakthrough time; double-glove recommended for spills
Exposure Limits: No established OSHA or ACGIH exposure limits yet
Hygiene Measures: Wash hands after handling, do not touch face, keep food and drinks away

Physical and Chemical Properties

Appearance: Off-white to light tan powder or viscous oil, faint chemical odor
Odor: Mild, slightly sulfurous/amine scent
pH (aqueous solution): Slightly acidic, typically 4–6
Melting Point: 60 °C to 90 °C (varies by purity)
Boiling Point: Decomposes before boiling
Flash Point: Not established, presumed above 150 °C due to ionic nature
Evaporation Rate: Negligible at room temperature
Solubility: Miscible with water, ethanol, DMSO, some glycols
Vapor Pressure: Near zero at room temperature
Relative Density: About 1.3–1.5 g/cm³
Partition Coefficient: Not measured
Autoignition Temperature: Not available
Decomposition Temperature: Above 180 °C, decomposes with smoke and fumes
Viscosity: May be high as neat liquid, low as aqueous solution

Stability and Reactivity

Chemical Stability: Stable at standard ambient conditions, sensitive to strong heat, moisture can cause slow hydrolysis
Reactivity: Reacts with strong oxidants, acid chlorides, alkali metals
Conditions to Avoid: High temperatures, open flames, direct sunlight, damp storage
Incompatible Materials: Oxidizers (peroxides, permanganates), strong alkalis, strong acids, reducing metals
Hazardous Decomposition: Toxic gases like HCl, SOx, and possible nitrogen compounds
Polymerization: May polymerize if contamination occurs, avoid mixing with radical initiators

Toxicological Information

Acute Toxicity: Data limited due to rare commercial use; animal studies for structurally similar compounds indicate low to moderate toxicity
Eye Irritation: May cause tearing, redness, stinging; prolonged contact can injure corneal tissue
Skin Irritation: Repeated or prolonged exposure may cause redness, dryness, mild dermatitis
Inhalation Hazard: Powder, aerosol, or vapor inhalation may cause coughing, sore throat, mild headache
Ingestion Risk: Nausea, possible gastric upset, data lacking for more severe effects
Chronic Exposure: No long-term studies in humans; potential risk for allergic reactions on repeated exposure
Carcinogenicity: Not classified by IARC, OSHA, NTP
Mutagenicity: No evidence in available assays
Reproductive Toxicity: No reported effects
Target Organ Effects: No evidence for specific organ effects from acute or chronic data

Ecological Information

Ecotoxicity: No specific studies; ionic liquids show adverse effect in aquatic environments at high concentration
Persistence and Degradability: Structure implies slow breakdown in soil and water; recyclability possible under certain controlled processes
Bioaccumulation Potential: Low likelihood, though no definitive studies
Mobility in Soil: Highly water soluble, can leach if not managed; avoid unrecovered release
Aquatic Toxicity: Analogues have shown acute toxicity to algae and daphnia above certain doses
Special Notes: Avoid releasing into surface waters, take care with lab drains or floorwashings

Disposal Considerations

Waste Handling: Treat as hazardous chemical waste, collect in designated containers for halogenated organics
Method of Disposal: Send for incineration or chemical waste treatment at licensed facility
Container Disposal: Rinse containers three times with compatible solvent before recycling/plastic waste stream
Sewage Disposal: Avoid discharge to municipal systems, report accidental spills as required
Regulatory Requirements: Comply with local, state, and federal regulations for hazardous waste; consult environmental officer for unknowns
Environmental Precautions: Prevent migration to drains, soil, or landfill

Transport Information

UN Number: Not assigned for small-scale laboratory or specialty use
Proper Shipping Name: Not regulated under US DOT, IATA, IMDG for quantities under threshold, but confirm current status for scaled shipping
Transport Hazard Class: Treat as irritant solid or liquid for PPE and signage
Packing Group: III (if regulated), limited hazard in transport
Labeling: Irritant symbol for workplace transport
Special Precautions: Seal tightly, protect from direct sunlight, stack containers securely
Spill Response in Transit: Isolate area, ventilate, use absorbent pads for cleanup, personal protective gear for handlers

Regulatory Information

TSCA Inventory: Likely not listed, consult manufacturer for pre-manufacture notice or specific commerce rules
DSL/NDSL (Canada): Check status for custom-synthesized chemicals
SARA Title III: Not listed as hazardous by US EPA, but workplace safety data may place under inventory reporting
California Proposition 65: No expected listing; chemical family not documented as carcinogenic or reproductive hazard
REACH Status (EU): Exempt for R&D or intermediate use, registration needed for full commercial market
Workplace Labelling: Clearly mark as irritant, store with hazard signage in chemical storage
Other Regulations: Handle and dispose in compliance with local, regional, national, and international guidelines