Material Safety Data Sheet: 1-Tetradecyl-2,3-Dimethylimidazolium Chloride

Identification

Product Name: 1-Tetradecyl-2,3-Dimethylimidazolium Chloride
Synonyms: C14-Dimethylimidazolium Chloride
Chemical Formula: C19H38ClN2
CAS Number: 1047658-72-5
Recommended Uses: Phase transfer catalyst, ionic liquid, surfactant in research laboratories
Manufacturer Information: Identify with name, address, and emergency phone number for supplier or distributor
Emergency Contact: Refer to company emergency response team or national poison center for urgent incidents

Hazard Identification

Classification: Eye irritation (Category 2A), Skin irritation (Category 2), Acute aquatic toxicity (Category 2)
Signal Word: Warning
Hazard Statements: Causes serious eye irritation, causes skin irritation, toxic to aquatic life
Pictograms: Exclamation mark, environment
Precautionary Statements: Wear protective gloves and eye protection, avoid release to environment, wash thoroughly after handling, immediately call a poison center or doctor in case of contact

Composition / Information on Ingredients

Chemical Name: 1-Tetradecyl-2,3-Dimethylimidazolium Chloride
CAS Number: 1047658-72-5
Concentration: 98–100%
Impurities/Additives: Trace residual solvents or byproducts may occur from synthesis, specifics determined by supplier batch analysis

First Aid Measures

Inhalation: Remove individual from exposure area, allow to breathe fresh air, seek medical advice if symptoms (cough, shortness of breath) persist
Skin Contact: Wash affected area with soap and water for several minutes, remove contaminated clothing, seek medical attention if irritation or rash develops
Eye Contact: Rinse cautiously with water for at least 15 minutes, holding eyelids open; remove contact lenses if present, continue rinsing, seek immediate medical attention
Ingestion: Rinse mouth, do not induce vomiting, seek immediate medical help, provide product label or information to healthcare personnel
Most Important Symptoms/Effects: Redness, pain, possible chemical burns to skin or eyes, gastrointestinal discomfort if ingested

Fire-Fighting Measures

Suitable Extinguishing Media: Water spray, carbon dioxide, dry chemical powder, foam
Specific Hazards: May release toxic fumes of nitrogen oxides, chlorine, hydrogen chloride gas on burning or decomposition
Special Protective Equipment: Wear self-contained breathing apparatus, full protective gear
Firefighting Instructions: Move containers from fire area if possible, cool with water spray to prevent rupture from heat, control contaminated water run-off

Accidental Release Measures

Personal Precautions: Evacuate unnecessary personnel, ventilate the area, avoid contact with spilled material, wear suitable protective equipment (gloves, goggles, respirators as needed)
Environmental Precautions: Prevent entry into drains, sewers, and natural waterways; notify authorities if product enters environment in significant amounts
Clean-Up Procedures: Absorb with inert material (e.g., sand, earth), sweep up and place in labelled container for disposal, wash area with water and detergent, avoid dry sweeping to limit dust

Handling and Storage

Handling: Use proper laboratory or industrial hygiene practices, avoid breathing dust, fumes, or vapors, avoid contact with eyes, skin, and clothing, wash hands thoroughly after use, no eating, drinking, or smoking while handling
Storage: Store in tightly closed containers, keep in a cool (2-8°C), dry, well-ventilated space, protect from moisture and incompatible substances, label container with contents and hazard warnings
Incompatibilities: Avoid contact with oxidizing agents, acids, strong bases

Exposure Controls and Personal Protection

Engineering Controls: Use in a fume hood or well-ventilated area, employ local exhaust ventilation if dust or vapor generated
Respiratory Protection: Use NIOSH-approved respirator if exposure limits risk to respiratory tract
Skin Protection: Appropriate chemical-resistant gloves (e.g., nitrile), laboratory coat or apron
Eye Protection: Safety goggles with side shields or face shield
Hygiene Measures: Wash hands, forearms, and face after handling, remove contaminated clothing before entering eating areas
Exposure Limits: No established occupational exposure limits; minimize exposure as a precaution

Physical and Chemical Properties

Appearance: White to off-white crystalline powder
Odor: Faint, characteristic, possibly similar to surfactants
Melting Point: 80–90°C (variation depends on purity)
Boiling Point: Not readily determined, decomposes before boiling
Solubility: Soluble in water and polar organic solvents (methanol, ethanol, DMSO)
pH Value: Approx. 6–8 (1% aqueous solution)
Vapor Pressure: Low at room temperature
Partition Coefficient (log Kow): Data not provided, expected to be low based on ionic structure
Density: 0.95–1.05 g/cm³ (20°C)
Flash Point: Not readily flammable, no data for exact value
Decomposition Temperature: >150°C

Stability and Reactivity

Chemical Stability: Stable under recommended conditions of storage and use
Conditions to Avoid: Excess heat, open flames, exposure to moisture
Materials to Avoid: Strong oxidizing agents, strong acids, strong bases; can react violently in such cases
Hazardous Decomposition Products: Nitrogen oxides, chlorine, hydrogen chloride, imidazole derivatives
Polymerization: Not known to occur

Toxicological Information

Routes of Exposure: Skin, eye contact, inhalation, ingestion
Acute Toxicity: Limited animal data; estimated oral LD50 in rats >1000 mg/kg
Skin Irritation: Causes irritation and possible chemical burns
Eye Irritation: Causes severe irritation, risk of corneal injury
Respiratory Effects: Dust or fumes may cause mild respiratory irritation
Sensitization: No data available
Chronic Effects: Not fully studied; avoid repeated prolonged contact
Carcinogenicity, Mutagenicity, Reproductive Toxicity: No data indicating carcinogenic or mutagenic effects; not classified as reproductive toxin
Symptoms: Eye pain, redness, burning sensation, gastrointestinal upset, rash, itching, dry or cracking skin

Ecological Information

Aquatic Toxicity: Toxic to fish, daphnia, and other aquatic organisms; use caution to avoid widespread environmental discharge
Persistence and Degradability: Substance not readily biodegradable in the environment; may accumulate
Bioaccumulative Potential: May pose some risk due to persistence, potential for bioaccumulation is considered low to moderate
Mobility in Soil: Limited mobility; binds with negatively charged soils due to cationic nature
Other Adverse Effects: High concentrations may cause long-term adverse effects in aquatic environments, chemical should not enter water systems

Disposal Considerations

Waste Treatment Methods: Treat as hazardous chemical waste, do not pour into drains or environment
Disposal Containers: Keep in a sealed, properly labelled, compatible container
Disposal Procedures: Dispose of by incineration at approved facility or in accordance with local, regional, and national regulations
Contaminated Packaging: Decontaminate or dispose as hazardous waste, avoid re-use
Special Precautions: Ensure compliance with community guidelines, never mix with incompatible substances for disposal

Transport Information

UN Number: Not regulated under most conventions, check current transport guidance
Proper Shipping Name: Not assigned, consult local regulations
Transport Hazard Class: Not classified as hazardous for most shipments under UN TDG, IMDG, IATA
Packing Group: Not assigned
Marine Pollutant: Yes, avoid discharge into the environment during transport
Special Precautions for User: Securely seal and label, carry documentation showing chemical name and emergency contacts

Regulatory Information

Labeling Requirements: Comply with OSHA, GHS, or CLP requirements for workplace labeling
SARA 302/304/311/312: Not specifically listed
TSCA Inventory: Check supplier registration
REACH Registration: Not registered, pre-registration or evaluation may apply to larger quantities
Other Local/National Regulations: Substance may be subject to registration, notification, or reporting under jurisdictional laws
Worker Protection: Provide training and access to this information sheet, ensure control standards and monitoring