Product Name: 1-Vinyl-3-Butylimidazolium Bis(Trifluoromethylsulfonyl)Imide
Chemical Family: Ionic Liquid
Synonyms: [VBmim][NTf2], 1-Vinyl-3-butylimidazolium bis(trifluoromethanesulfonyl)imide
CAS Number: 174899-72-2
Manufacturer: [Provide name of Manufacturer/Distributor]
Contact Number: [Provide emergency contact number]
Recommended Use: Solvent, electrolyte, specialty chemical research
Restrictions on Use: Not for drug, human, animal, food, or household purposes
Classification: Eye irritation (Category 2), Skin irritation (Category 2), Acute aquatic toxicity (Category 3), Chronic aquatic toxicity (Category 3)
Label Elements: Pictogram with exclamation mark, environmental hazard
Signal Word: Warning
Hazard Statements: Causes skin irritation, causes serious eye irritation, harmful to aquatic life with long-lasting effects
Precautionary Statements: Wear protective gloves and eye protection, avoid release to the environment, wash hands thoroughly after handling, seek medical attention if irritation persists
Other Hazards: Inhalation of vapor or mist can irritate respiratory tract, ingestion may cause gastrointestinal disturbances; no known significant acute systemic effects based on available data
Chemical Name: 1-Vinyl-3-Butylimidazolium Bis(Trifluoromethylsulfonyl)Imide
CAS Number: 174899-72-2
Percent: ≥98% (purity depending on supplier)
Impurities: Trace amounts of by-products from synthesis (typically below 1%)
Formula: C13H20F6N4O4S2
Molecular Weight: 462.44 g/mol
Eye Contact: Rinse with plenty of water for at least 15 minutes, hold eyelids open, remove contact lenses, seek immediate medical attention
Skin Contact: Wash with soap and water for several minutes, remove contaminated clothing, seek medical advice in case of irritation
Inhalation: Move to fresh air, keep at rest in a position comfortable for breathing, obtain medical attention if symptoms persist
Ingestion: Rinse mouth with water, do not induce vomiting, seek medical attention
Most Important Symptoms/Effects: Redness, irritation of skin, eyes, mucous membranes
Indication of Immediate Medical Attention Needed: Prolonged symptoms or significant exposure, especially with eye contact or ingestion
Suitable Extinguishing Media: Dry chemical, carbon dioxide, alcohol-resistant foam, water spray (do not use direct water stream)
Specific Hazards Arising from the Chemical: May emit toxic fumes including carbon oxides, nitrogen oxides, sulfur oxides, fluorine-containing gases, hydrogen fluoride
Protective Equipment for Fire-Fighters: Full protective clothing and self-contained breathing apparatus
Special Precautions: Approach from upwind, avoid breathing fumes
Thermal Decomposition Products: CO, CO2, NOx, SOx, HF; release intensified under fire conditions
Fire Fighting Procedures: Use water to cool containers, keep run-off out of water sources and sewers
Personal Precautions: Use appropriate personal protective equipment including gloves, goggles, lab coat
Environmental Precautions: Prevent entry into drains, surface water, soil; contain spill to avoid environmental contamination
Methods for Cleaning Up: Absorb with inert material (sand, vermiculite), scoop into compatible container for disposal, ventilate area, clean residues with detergent and water
Reference to Other Sections: See Exposure Controls and Personal Protection for suitable protective measures
Precautions for Safe Handling: Take measures to prevent exposure by skin or eyes, handle in well-ventilated areas, avoid aerosol generation
Advice on Safe Storage: Keep in tightly closed original container, store at room temperature or below, away from moisture and incompatible materials
Incompatibilities: Strong oxidizers, acids, bases, incompatible with halogenated materials
Conditions to Avoid: Heat, sunlight, high humidity
Hygiene Measures: Wash hands before breaks and after handling, do not eat, drink, or smoke near material
Engineering Controls: Use with adequate ventilation, preferably in a chemical fume hood
Personal Protective Equipment: Chemical-resistant gloves (nitrile recommended), tight-fitting goggles, laboratory coat, closed footwear
Respiratory Protection: Use NIOSH/MSHA-approved respirator if ventilation is inadequate or in case of potential dust/vapor formation
Environmental Controls: Avoid discharge into the environment, use containment measures for bulk handling
Exposure Limits: No occupational exposure limit values set for this compound; follow good laboratory practices and safety limits
Appearance: Colorless to pale yellow liquid
Odor: Mild, characteristic
Odor Threshold: Not established
pH: Neutral (6.5-7.5 in water)
Melting Point: -15 °C to -28 °C (varies by purity)
Boiling Point: Decomposes before boiling
Flash Point: >180 °C (closed cup)
Evaporation Rate: Not available
Flammability: Non-flammable liquid, may burn at high temperature
Vapor Pressure: Negligible at ambient conditions
Vapor Density: Not available
Relative Density: 1.3-1.4 g/cm³ at 25 °C
Solubility: Miscible with many organic solvents, slightly soluble in water
Partition Coefficient: Not available
Autoignition Temperature: Not determined
Decomposition Temperature: >250 °C
Viscosity: 45-70 mPa·s at 25 °C
Reactivity: Stable under normal laboratory conditions
Chemical Stability: Maintains integrity in dry, inert atmosphere
Possibility of Hazardous Reactions: Unlikely under recommended storage and handling
Conditions to Avoid: Moisture, elevated temperatures, contact with strong oxidizers or acids, storage near heat sources
Incompatible Materials: Strong oxidizing agents, strong acids and bases, halogenated reagents
Hazardous Decomposition Products: CO, CO2, SOx, NOx, hydrogen fluoride, other toxic fumes in the event of fire or overheating
Routes of Exposure: Skin contact, eye contact, inhalation, ingestion
Acute Toxicity: Data limited in humans and animals, estimated oral LD50 (rat) >2000 mg/kg
Skin Corrosion/Irritation: Causes skin irritation upon prolonged or repeated contact
Serious Eye Damage/Irritation: Causes eye irritation upon exposure, may result in redness, watering
Respiratory Sensitization: No sensitization data; potential to irritate respiratory tract
Chronic Toxicity: No chronic systemic health effects established; avoid prolonged or repeated exposure
Carcinogenicity/Mutagenicity/Reproductive Toxicity: Not classified as carcinogenic or mutagenic by IARC, ACGIH, NTP, OSHA; no reproductive studies found
Additional Information: Adherence to workplace safety protocols reduces risk
Toxicity to Aquatic Life: Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment; EC50 (Daphnia, 48h): 10-100 mg/L
Persistence and Degradability: Not readily biodegradable in the environment, potential for persistence
Bioaccumulation: Expected to have low to moderate potential based on structure
Mobility in Soil: Moderate to low mobility; binds to organic matter
Other Adverse Effects: Release to waterways can be hazardous; limit discharge as best practice
Waste Disposal Methods: Dispose of in accordance with local, regional, and national regulations; incinerate under controlled conditions if possible
Container Disposal: Triple rinse, puncture, and send to licensed chemical waste facility
Special Precautions: Do not dispose of through municipal waste streams; avoid contamination of soil, groundwater, and waterways
Recommendations: Contract with chemical waste disposal company familiar with ionic liquids
UN Number: Not regulated for transport under most jurisdictions
Proper Shipping Name: Not classified as hazardous for transport
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
Environmental Hazards: Marine pollutant if in large amounts
Special Precautions for User: Protect container from physical damage and direct sunlight; ensure secure closure
Transport in Bulk According to Annex II of MARPOL and IBC Code: Not listed under bulk transport regulations
TSCA Status: Listed or notification submitted if used in the USA
REACH Status: Registration or notification required for use/import in Europe
DSL/NDSL (Canada): Check listing status
WHMIS Classification: D2B (Toxic material causing other toxic effects, skin/eye irritant)
SARA Title III: Not listed in Section 302/304/313
OSHA Hazard Communication: Meets criteria for hazardous chemical
Other Regulations: Local, state, and federal environmental and employee protection regulations may apply; always consult with regulatory compliance team before large-scale or commercial activities
