Material Safety Data Sheet: 1-Vinyl-3-Dodecylimidazolium Bromide

Identification

Product Name: 1-Vinyl-3-Dodecylimidazolium Bromide
Chemical Formula: C19H35BrN2
Synonyms: 1-Vinyl-3-Dodecylimidazolium Bromide, Ionic Liquid
CAS Number: 851995-56-5
Recommended Use: Lab research, manufacturing of specialty chemicals, surfactant applications
Manufacturer: Contact local supplier or chemical manufacturer for specific details
Emergency Phone: Local emergency line or Poison Control Center, specific number depending on location
Address: Refer to chemical supplier’s documentation for up-to-date location details

Hazard Identification

Classification: Skin irritant (Category 2), Eye irritant (Category 2), Potential aquatic hazard
GHS Label Elements: Exclamation mark for irritation risk, Environment symbol for aquatic hazard
Signal Word: Warning
Hazard Statements: Causes skin irritation, causes serious eye irritation, toxic to aquatic life with long lasting effects
Precautionary Statements: Avoid breathing dust or fume, wash exposed skin thoroughly after handling, wear eye and skin protection, avoid release to the environment, collect spillage to prevent contamination of waterways

Composition / Information on Ingredients

Chemical Name: 1-Vinyl-3-Dodecylimidazolium Bromide
CAS Number: 851995-56-5
Concentration: Pure compound, typically above 97% when supplied for laboratory or industrial use
Impurities: Trace organic residues from synthesis, typically below 1%

First Aid Measures

General Guidance: Move away from exposure source and bring to fresh air in all cases.
Eye Contact: Remove contact lenses if present, flush eyes with plenty of water for at least 15 minutes, seek medical attention for persistent irritation.
Skin Contact: Take off contaminated clothing, flush skin with water and mild soap, consult healthcare provider if rash or discomfort develops.
Inhalation: Remove person to fresh air, keep comfortable, seek medical attention if respiratory symptoms appear.
Ingestion: Rinse mouth with water, do not induce vomiting, seek immediate medical attention if feeling unwell.
Important Symptoms: Redness, swelling, itching, burning sensation, respiratory discomfort, nausea if ingested

Fire-Fighting Measures

Suitable Extinguishing Media: Use carbon dioxide, dry chemical powder, foam, or water spray for small fires. For larger fires, standard firefighting measures with water spray or foam.
Hazards from Fire: Emits toxic fumes under fire, including nitrogen oxides, hydrogen bromide, carbon monoxide.
Protective Equipment: Use self-contained breathing apparatus and full protective clothing. Move containers away from fire zone if safe.
Specific Fire-Fighting Procedures: Cool worn containers with water spray, avoid inhalation of vapors or particulates, keep runoff water out of drains and water sources

Accidental Release Measures

Personal Precautions: Use chemical splash goggles, gloves, long-sleeved clothing; prevent contact with skin and eyes
Environmental Precautions: Prevent further leakage or spillage if safe to do so, do not allow material to enter drains or watercourses
Cleanup Procedures: Ventilate spill area. Use inert absorbent materials such as sand or vermiculite, sweep up and place in suitable containers for disposal. Clean spill area thoroughly with water and detergent.
Advice for Emergency Responders: Wear chemical-resistant boots and protective apron. Dispose of collected material following regulatory requirements.

Handling and Storage

Safe Handling: Handle in well-ventilated areas, avoid inhaling dust or vapor, do not eat, drink, or smoke while using product, wear recommended personal protective equipment
Safe Storage: Store in tightly closed containers in a cool, dry, well-ventilated place away from heat, moisture, and incompatible materials like strong bases and oxidizing agents.
Incompatible Materials: Strong acids, oxidizing agents, reducing agents
Other Precautions: Keep away from open flames or sources of ignition, label containers clearly, do not store near food or feedstuffs

Exposure Controls and Personal Protection

Exposure Limits: No established OSHA or ACGIH exposure limits for 1-Vinyl-3-Dodecylimidazolium Bromide
Engineering Controls: Use local exhaust ventilation, fume hood, or other engineering controls to keep airborne concentrations below recommended limits
Personal Protective Equipment: Chemical splash proof goggles, chemical resistant gloves (nitrile or neoprene), lab coat or long sleeves, closed-toe shoes
Respiratory Protection: If ventilation is inadequate, use an approved respirator suitable for organic vapors or particulates
Hygiene Measures: Wash hands, face, and any exposed skin after handling, remove contaminated clothing before leaving work area

Physical and Chemical Properties

Appearance: White or off-white crystalline or powdery solid
Odor: Slight, faintly ammoniacal
Odor Threshold: Not established
pH: Slightly acidic aqueous solution
Melting Point: ~80-110°C (varies by purity)
Boiling Point: Decomposes before boiling
Flash Point: Not determined
Auto-Ignition Temperature: Not established
Explosion Properties: Product is not explosive in solid form
Vapor Pressure: Negligible at room temperature
Density: About 1.08-1.15 g/cm³
Solubility: Soluble in water, alcohols, and polar solvents
Partition Coefficient (n-octanol/water): Not determined
Viscosity: Data not available

Stability and Reactivity

Chemical Stability: Stable under standard storage conditions
Reactivity: Not reactive under normal use
Hazardous Decomposition Products: Nitrogen oxides, hydrogen bromide, carbon monoxide, carbon dioxide may form at high temperatures
Incompatible Materials: Avoid strong acids, strong oxidizers, and reducing agents
Conditions to Avoid: High temperatures, open flames, sources of ignition, moisture ingress
Polymerization: Not known to occur under normal conditions

Toxicological Information

Likely Routes of Exposure: Skin and eye contact, inhalation of dust, accidental ingestion
Acute Toxicity: Limited acute toxicity data, based on structural analogs can irritate eyes and skin
Skin Corrosion/Irritation: May cause redness, dryness, cracking with prolonged contact
Serious Eye Damage/Irritation: May cause burning, redness, watering
Respiratory Sensitization: Potential for transient irritation; chronic exposure data lacking
Chronic Effects: Not enough data for long-term effects
Mutagenicity/Carcinogenicity: No studies showing mutagenic or carcinogenic effects in current literature
Other Risks: Allergic reactions are rare but possible if user has pre-existing sensitivity

Ecological Information

Toxicity: Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment
Persistence and Degradability: Slowly biodegradable; persistent in soil and sediment
Bioaccumulative Potential: Bioaccumulation unlikely, but can’t be excluded without further study
Mobility in Soil: Soluble in water, potential for leaching into groundwater systems
Other Adverse Effects: Avoid release to environment, report spills to relevant local authorities

Disposal Considerations

Waste Treatment Methods: Incinerate or dispose of in accordance with local, regional, and national regulations
Product Disposal: Dissolve or mix with combustible solvent and burn in a chemical incinerator equipped with afterburner and scrubber
Packaging Disposal: Triple rinse containers before disposal. Puncture and dispose of at licensed landfill.
Precautions: Do not allow material to contaminate surface water or sewer systems

Transport Information

UN Number: Not classified as dangerous goods for most transport modes
Transport Hazard Class: Not regulated under ADR/RID, IMDG, IATA
Packing Group: Not assigned
Environmental Hazards: As a potential aquatic toxicant, handle spills with care
Special Precautions: Ensure containers are tightly sealed, dry, and appropriately labeled throughout transit

Regulatory Information

Safety, Health and Environmental Regulations: OSHA: Not specifically regulated as a hazardous chemical
TSCA Inventory: Not currently listed; for research and development uses only
REACH Status: Pre-registration may be required for importing into the EU
SARA Title III Sections 311/312: Not subject to reporting requirements for immediate health hazard
Canada DSL/NDSL: Check specific substance status before importation or use
Other Regulations: Handle in compliance with all applicable local, state, national, and international regulations, pay attention to environmental restrictions due to aquatic toxicity potential