Material Safety Data Sheet: 1-Vinyl-3-Ethylimidazolium Bromide

Identification

Product Name: 1-Vinyl-3-Ethylimidazolium Bromide
Chemical Formula: C7H11BrN2
Synonyms: 1-Ethyl-3-vinylimidazolium bromide
Manufacturer: Manufacturer details available on product label
Recommended Use: Ionic liquid, organic synthesis intermediate
CAS Number: 210888-78-7
Emergency Contact: Local emergency number or national poison control center

Hazard Identification

Classification: Skin irritation, Eye irritation, Harmful if inhaled or swallowed
Hazard Statements: Causes skin and eye irritation, may cause respiratory irritation, harmful if ingested
Signal Word: Warning
Pictograms: Exclamation mark
Precautionary Statements: Avoid breathing dust or vapors, wear protective equipment, wash hands thoroughly after handling, avoid release to the environment

Composition / Information on Ingredients

Chemical Name: 1-Vinyl-3-Ethylimidazolium Bromide
Concentration: >95%
Impurities: Trace amounts of precursors and byproducts, none above 1%
Molecular Weight: 219.09 g/mol

First Aid Measures

Inhalation: Move to fresh air, provide oxygen if breathing is difficult, seek medical attention for persistent symptoms
Skin Contact: Wash thoroughly with soap and water, remove contaminated clothing, seek medical help for irritation
Eye Contact: Flush with plenty of water for at least 15 minutes, lift eyelids occasionally, get medical attention
Ingestion: Rinse mouth, do not induce vomiting, drink water if conscious, get immediate medical attention
Acute Symptoms: Coughing, redness, burning sensation on skin or eyes, nausea

Fire-Fighting Measures

Suitable Extinguishing Media: Water spray, alcohol-resistant foam, dry chemical, carbon dioxide
Special Hazards: Emits toxic fumes of nitrogen oxides, carbon monoxide, bromine compounds during combustion
Protective Equipment: Firefighters require self-contained breathing apparatus and full protective gear
Advice for Firefighters: Avoid inhaling combustion gases, use water spray to cool surfaces and prevent vapor buildup

Accidental Release Measures

Personal Precautions: Use protective gloves, goggles, and suitable clothing, ventilate area, avoid dust formation
Leak Response: Do not allow material to get into drains or watercourses, keep away from ignition sources
Cleanup Methods: Collect spilled material with non-combustible absorbent (e.g., sand), transfer to suitable waste container for disposal, wash area with water after collection

Handling and Storage

Precautions for Handling: Wear appropriate PPE, prevent contact with skin and eyes, avoid inhalation of dust or vapor, operate in well-ventilated area
Safe Storage Conditions: Store in tightly closed container, away from moisture, heat sources, strong oxidizers or acids, keep in a cool, dry, and well-ventilated place
Incompatibilities: Avoid contact with strong oxidizing agents, strong acids, reducing agents

Exposure Controls and Personal Protection

Exposure Limits: No established occupational exposure limits
Engineering Controls: Use local exhaust ventilation or work in a chemical fume hood to minimize exposure
Personal Protection: Wear chemical-resistant gloves (nitrile or neoprene), splash-proof goggles, lab coat, and if dust or vapor present, use NIOSH-approved respirator
Hygiene Measures: Wash hands and face thoroughly after handling, remove and wash contaminated clothing before reuse, do not eat, drink or smoke in work area

Physical and Chemical Properties

Appearance: White to off-white crystalline powder
Odor: Faint, characteristic
Odor Threshold: Not determined
pH: Not available
Melting Point/Range: Approximately 120-125°C
Boiling Point/Range: Decomposes before boiling
Flash Point: Not applicable
Evaporation Rate: Not determined
Flammability: Not readily flammable
Vapor Pressure: Negligible at room temperature
Relative Density: ~1.4 (water = 1)
Solubility: Soluble in water, methanol, DMSO
Partition Coefficient (n-octanol/water): Not determined
Autoignition Temperature: Not determined
Decomposition Temperature: Above 200°C

Stability and Reactivity

Chemical Stability: Stable under normal storage conditions and recommended use
Reactivity: Not highly reactive under ambient conditions
Hazardous Reactions: May react with strong oxidizers, acids or reducing agents
Conditions to Avoid: High humidity, elevated temperatures, exposure to light
Hazardous Decomposition Products: Carbon oxides, nitrogen oxides, hydrogen bromide

Toxicological Information

Likely Routes of Exposure: Skin and eye contact, inhalation, ingestion
Acute Effects: Skin and eye irritation, possible respiratory discomfort, gastrointestinal symptoms if ingested
Chronic Effects: Prolonged or repeated exposure can cause skin dermatitis or sensitization
Toxicity Data: No specific LD50 data available, structurally similar ionic liquids have shown moderate acute toxicity
Carcinogenicity: No component listed as carcinogen by IARC, NTP, OSHA
Mutagenicity: No data to suggest mutagenic effects
Other Information: No known information on reproductive or developmental toxicity

Ecological Information

Ecotoxicity: Limited data available, similar compounds are toxic to aquatic organisms in high concentrations
Persistence and Degradability: May persist in environment, not readily biodegradable
Bioaccumulation Potential: Low potential for bioaccumulation
Mobility in Soil: High solubility in water indicates potential mobility in soil and water systems
Other Adverse Effects: Do not let material reach natural water sources, inform appropriate authorities of large releases

Disposal Considerations

Waste Disposal Methods: Dispose as hazardous chemical waste in accordance with local, regional, and national regulations
Container Disposal: Rinse thoroughly before disposal or recycle if practical, do not dispose in general waste or sewer
Special Precautions: Consult a licensed waste disposal contractor for proper disposal procedures

Transport Information

UN Number: Not classified as a dangerous good by current transport regulations
Proper Shipping Name: Chemical, not otherwise specified
Transport Hazard Class: Not regulated
Packing Group: Not regulated
Environmental Hazards: Avoid release into environment during transport
Special Precautions: Keep container upright and secure during movement

Regulatory Information

TSCA Status: Listed or exempt
EINECS/ELINCS Number: 606-375-2
REACH Registration: Check with supplier for registration status
SARA 313: Not listed
California Prop 65: Not listed as a chemical known to cause cancer or reproductive toxicity
Other Local or International Regulations: Follow national and international regulations for chemical handling, labeling, and safety