Material Safety Data Sheet: 1-Vinyl-3-Methylimidazolium Bis(Fluorosulfonyl)Imide

1. Identification

Product Name: 1-Vinyl-3-Methylimidazolium Bis(Fluorosulfonyl)Imide
Synonyms: [Vimim][FSI], Ionic Liquid FSI Salt
Recommended Use: Electrolyte in batteries, chemical research, industrial applications
Manufacturer: Supply chain details required from sourcing entity
Emergency Contact: Refer to local poison control, manufacturer’s safety hotline
CAS Number: 174899-81-5
Address: Refer to sourcing documentation for mailing address
Telephone: Listed on supplier paperwork or packaging labels

2. Hazard Identification

Classification: Irritant to eyes, skin, respiratory system, suspected reproductive toxicant
GHS Label Elements: Signal word: Warning; Exclamation mark pictogram
Hazard Statements: Causes irritation to eyes and skin; may cause respiratory discomfort; potential for harmful effects on fertility and unborn child
Precautionary Statements: Avoid breathing dust or fumes; use ventilation; wash exposed skin thoroughly after handling; wear face, eye, and skin protection
Routes of Exposure: Inhalation, skin contact, eye contact, ingestion
Acute Effects: Burning sensation, coughing, eye watering, red skin; severe in high concentrations
Chronic Effects: Repeated contact may aggravate pre-existing respiratory or skin disorders; current data not definitive for carcinogenicity

3. Composition / Information on Ingredients

Chemical Name: 1-Vinyl-3-Methylimidazolium Bis(Fluorosulfonyl)Imide
Chemical Formula: C6H9N2FS2O4
Proportion: Typically ≥99% pure ionic liquid
Impurities: Trace imidazole derivatives, possible residual solvents or water (≤0.5%)
Molecular Weight: 310.28 g/mol
Other Information: No hazardous non-disclosed components per supplier declaration

4. First Aid Measures

Inhalation: Move to fresh air, keep person still and warm; seek medical attention if breathing becomes difficult
Skin Contact: Rinse skin thoroughly with water and mild soap; remove contaminated clothing; seek advice if irritation persists
Eye Contact: Flush eyes gently with clean running water for minimum 15 minutes, taking care to remove contact lenses; consult ophthalmological care if pain or visual disturbance occurs
Ingestion: Rinse mouth thoroughly; do not induce vomiting unless directed by medical personnel; seek immediate medical guidance; monitor for abdominal pain or nausea
Important Notes: Provide medical staff with product label if possible for reference; delayed reactions may emerge after apparent recovery

5. Fire-Fighting Measures

Suitable Extinguishing Media: Dry chemical, CO2, water spray, alcohol-resistant foam
Unsuitable Media: Strong water jet (may spread spillage)
Specific Hazards: Decomposition may release corrosive and toxic fumes: hydrogen fluoride, sulfur oxides, nitrogen oxides
Protective Equipment: Self-contained breathing apparatus, full protection suit
Advice for Firefighters: Evacuate unnecessary personnel, limit inhalation of vapors; cool containers exposed to flames with water
Fire/Explosion Data: Not considered highly flammable but may create hazardous atmospheres at high temperatures

6. Accidental Release Measures

Personal Precautions: Use full protective clothing including gloves, goggles, lab coat, and respiratory protection if ventilation inadequate
Environmental Precautions: Avoid runoff to drains or surface water; contain spill with inert absorbent material
Cleanup Methods: Ventilate area; absorb with sand or inert material; scoop up in sealed chemical container; clean area thoroughly with water
Disposal: Dispose via licensed chemical waste contractor; consult local regulations for classified waste
Prevention: Maintain containment to minimize risk of spread during routine work

7. Handling and Storage

Handling: Limit direct exposure; utilize extraction ventilation or fume hood; avoid creating dust or aerosol; minimize accumulation of product outside closed systems
Storage Conditions: Store in cool, dry place in tightly sealed original container, away from light, flames, strong bases, oxidizers, and incompatible metals
Temperature Sensitivity: Optimal stability below 25°C; keep from freezing or overheating
Storage Compatibility: Keep away from acids, alkalis, hydrochloric acid, moisture
Additional Advice: Ensure label is intact; restrict access to qualified personnel only

8. Exposure Controls and Personal Protection

Engineering Controls: Use local fume extraction; general laboratory ventilation required
Personal Protection: Lab coat, impermeable gloves (nitrile suggested), chemical splash goggles; use P2 or N95 respirator if airborne concentration possible
Workplace Exposure Limits: No assigned TLV or PEL; control occupational exposure below discomfort threshold
Hygiene Measures: Wash hands before eating or leaving lab; remove work clothes prior to breaks or shift end
Environmental Exposure Controls: Prevent entry to drains or environmental waterways

9. Physical and Chemical Properties

Appearance: Colorless to pale yellow liquid
Odor: Mildly pungent, chemical odor
pH: Slightly acidic water solution
Melting Point: Typically below 10°C
Boiling Point: Decomposes before boiling over 300°C
Vapor Pressure: Negligible at room temperature
Solubility: Readily soluble in water, acetonitrile, some alcohols
Density: 1.25 – 1.31 g/cm3 at 25°C
Viscosity: Moderate, varies with temperature
Flash Point: Not determined, but high compared with common solvents
Evaporation Rate: Low
Partition Coefficient: Not established
Decomposition: Releases HF, SO2 above 300°C

10. Stability and Reactivity

Chemical Stability: Stable under recommended storage; degrades with strong acids, bases, light, heat
Reactivity: May generate toxic fumes on contact with acids, bases, or at high temperature
Hazardous Reactions: Vigorous reaction with strong oxidizers, alkali metals
Conditions to Avoid: Sunlight, moisture, sources of ignition, contact with strong acids/bases
Hazardous Decomposition: Hydrogen fluoride, sulfur oxides, nitrogen oxides, carbon monoxide/dioxide

11. Toxicological Information

Acute Toxicity Data: No specific LD50 data for this compound; ionic liquid analogs typically considered low acute oral toxicity to rodents
Skin Irritation: May cause redness, dryness, or blistering on prolonged contact
Eye Irritation: Causes severe irritation, watering, and potential for reversible injury
Inhalation: Expected to be low risk in controlled use, but high concentrations may lead to cough and mucous membrane discomfort
Chronic Effects: Long-term exposure not fully tested; structural similarities to toxic substances mean reproductive and developmental risks cannot be dismissed
Carcinogenicity: Data are currently inconclusive; not listed in IARC or NTP lists
Additional Toxicological Remarks: Handle as potentially harmful; limited epidemiological data, so extra precaution is justified

12. Ecological Information

Aquatic Toxicity: Data limited; ionic liquids, depending on structure, may cause harm to aquatic organisms
Persistence and Degradability: Likely slow to degrade in environment; may resist biological breakdown due to strong chemical bonds
Bioaccumulation Potential: Unknown; professional judgement indicates low likelihood of major accumulation due to high solubility, but absence of confirmed information
Mobility in Soil: Tends to leach through soil due to water solubility
Other Adverse Effects: Prevent uncontrolled release to natural environments until more robust ecological data exists

13. Disposal Considerations

Waste Disposal: Collect in clearly labeled hazardous waste drums; transfer to approved disposal facility
Contaminated Packaging: Rinse with water, then dispose as hazardous chemical waste
Special Precautions: Incineration by licensed waste handler preferred for destruction; follow regional and national guidelines
Regulatory Compliance: Align disposal practices with local, national, and international laws on hazardous chemical management

14. Transport Information

UN Number: Not assigned
Proper Shipping Name: Not specifically listed; classify as a corrosive liquid if shipment in bulk quantities—consult shipping provider for MSDS inclusion
Transport Hazard Class: 8 (Corrosive), subject to transport mode and packaging
Packing Group: III (based on tested corrosivity)
Label Required: Corrosive, if applicable
Special Precautions: Protect packaging from leakage, spillage, and strong impact; secure against shifting loads
Environmental Risks: Transport to minimize risk of leaks into aquatic or soil environments

15. Regulatory Information

OSHA: Not listed under OSHA hazardous chemicals, but prudent care recommended
TSCA: Consult supplier certification for specific registration status
REACH: Usage in European Economic Area may require registration; check EC No. with supplier
WHMIS Classification: Not officially classified; recommend labeling as toxic, corrosive
Other Regulations: Handle according to local, national, and international requirements for laboratory and industrial chemicals
Labeling Recommendations: Ensure clear hazard communication using chemical name and hazard warnings as outlined above