MSDS of 1-Vinyl-3-Methylimidazolium Trifluoromethanesulfonate

Identification

Product Name: 1-Vinyl-3-Methylimidazolium Trifluoromethanesulfonate
Synonyms: [1-Vinyl-3-methylimidazolium][trifluoromethanesulfonate], Ionic liquid
Recommended Use: Laboratory research, chemical manufacturing, electrochemical applications
Manufacturer: Chemical solutions supplier, contact details available on original packaging
Emergency Contact: Hazmat Response USA, Telephone: 1-800-424-9300 (CHEMTREC)

Hazard Identification

Classification: Eye irritation, Category 2; Skin irritation, Category 2
Hazard Pictograms: Exclamation mark (GHS07)
Signal Word: Warning
Hazard Statements: Causes serious eye irritation. Causes skin irritation. May cause respiratory irritation.
Precautionary Statements: Wear protective gloves, protective clothing, eye/face protection. Avoid breathing dust, vapors, fumes. Wash hands thoroughly after handling. Use only outdoors or in well-ventilated areas. If in eyes: Rinse cautiously with water for several minutes.

Composition / Information on Ingredients

Chemical Name: 1-Vinyl-3-Methylimidazolium Trifluoromethanesulfonate
CAS Number: 174899-66-2
EC Number: 695-117-6
Impurities: No significant impurities classified as hazardous
Concentration: 100% Pure substance, unless otherwise specified
Molecular Formula: C7H11F3N2O3S
Molecular Weight: 276.24 g/mol

First Aid Measures

General Advice: Move affected person away from exposure area. Ensure access to fresh air, wash contaminated area with water
Inhalation: Remove to fresh air. If symptoms persist, seek medical attention
Skin Contact: Remove contaminated clothing. Flush skin with plenty of water for at least 15 minutes
Eye Contact: Rinse cautiously with water for several minutes, keeping eyelids open. Remove contact lenses if present. Continue rinsing. Seek medical attention if irritation persists
Ingestion: Rinse mouth with water. Do not induce vomiting. Seek medical advice immediately
Symptoms & Effects: Burning sensation, redness, pain at contact sites, irritation of respiratory tract
Notes to Physician: Treat symptomatically. No specific antidote known

Fire-Fighting Measures

Suitable Extinguishing Media: Water spray, dry chemical powder, carbon dioxide, foam
Unsuitable Extinguishing Media: High-velocity water jet
Special Hazards: May emit toxic fumes under fire, such as hydrogen fluoride, nitrogen oxides, sulfur oxides
Protective Equipment for Firefighters: Wear self-contained breathing apparatus and full protective gear
Special Procedures: Avoid inhalation of combustion gases, keep containers cool with water spray. Prevent runoff from entering drains

Accidental Release Measures

Personal Precautions: Evacuate non-essential personnel, ventilate area, avoid dust formation. Wear appropriate PPE: gloves, safety goggles, lab coat, suitable respirator
Environmental Precautions: Prevent further leakage or spillage if it can be done safely. Avoid discharge into drains, surface water, groundwater
Methods for Clean-Up: Absorb with inert material (sand, silica, vermiculite), sweep up and collect in suitable, labeled containers for disposal. Wash spill area with copious water

Handling and Storage

Handling: Handle in a chemical fume hood or well-ventilated area. Minimize contact with skin, eyes, and clothing. Prevent formation of aerosols or dust. Clean-up spills promptly using standardized procedures
Storage: Keep container tightly closed. Store in cool, dry, well-ventilated area away from incompatible substances. Protect from heat, sunlight, and moisture. Recommended storage temperature below 25°C. Keep away from strong oxidizers and acids

Exposure Controls and Personal Protection

Engineering Controls: Use only in fume hood or with local exhaust ventilation. Install eyewash fountain and safety shower in work area
Eye/Face Protection: Chemical safety goggles or face shield
Skin Protection: Nitrile or neoprene gloves, long-sleeved lab coat, closed-toe shoes
Respiratory Protection: Suitable respirator if aerosol or dust is generated
Hygiene Measures: Wash hands before breaks and at end of workday. Do not eat, drink or smoke while handling. Remove contaminated clothing and wash before reuse

Physical and Chemical Properties

Appearance: Liquid or crystalline solid (depends on temperature and purity), colorless to pale yellow
Odor: Faintly sweet or amine-like
pH: Value not available (aqueous solutions may be mildly acidic)
Boiling Point: Decomposes before boiling
Melting Point: Around 30-40°C (may vary slightly with batch or impurities)
Flash Point: Not applicable, may decompose on heating
Vapor Pressure: Negligible at 20°C
Solubility: Highly soluble in water and many polar organic solvents
Density: Approximately 1.4 g/cm³
Viscosity: Higher than water (depends on temperature)
Partition Coefficient: Not determined
Auto-ignition Temperature: Not available
Decomposition Temperature: Above melting point, with emission of toxic gases

Stability and Reactivity

Chemical Stability: Stable under recommended storage conditions
Possibility of Hazardous Reactions: No dangerous reactions known under normal conditions
Conditions to Avoid: Heat, sunlight, moisture, sources of ignition
Materials to Avoid: Strong oxidizing agents, strong acids, strong bases
Hazardous Decomposition Products: Hydrogen fluoride, sulfur oxides, nitrogen oxides, carbon oxides, trifluoromethanesulfonic acid vapors

Toxicological Information

Acute Toxicity: Low acute toxicity via oral, dermal, and inhalation routes, but not well studied in humans. Animal studies point to moderate irritation
Skin Corrosion/Irritation: Causes irritation on prolonged or repeated contact
Eye Damage/Irritation: Causes severe irritation and possible damage
Respiratory Sensitization: May irritate mucous membranes and upper respiratory system
Skin Sensitization: Possible risk with chronic exposure
Chronic Toxicity: Not fully evaluated
Carcinogenicity: No data available to suggest carcinogenic potential
Reproductive Toxicity: No available significant information
Mutagenicity: No definitive mutagenic potential observed
Medical Conditions Aggravated: May aggravate existing skin, eye, or respiratory conditions

Ecological Information

Ecotoxicity: Data on aquatic toxicity are limited; possible adverse effects on aquatic life due to high solubility and persistence
Persistence and Degradability: Likely persistent, may not biodegrade readily
Bioaccumulative Potential: No significant potential expected due to low partition coefficient
Mobility in Soil: Likely to have high mobility in water and soil, due to ionic character and solubility
Other Adverse Effects: Discharge into the environment should be avoided; consult local regulations for more detailed environmental impact

Disposal Considerations

Disposal Methods: Collect and place in suitable, labeled containers. Dispose in accordance with federal, state and local environmental control regulations. Do not dispose via sinks or drains. Can be incinerated in appropriate facilities under controlled conditions
Contaminated Packaging: Dispose as hazardous waste. Clean containers before reuse or offer for recycling if allowed by local authorities
Unused Product: Send to licensed chemical disposal company or hazardous waste incinerator

Transport Information

UN Number: Not classified as a dangerous good for transport according to current international regulations
Transport Hazard Class(es): None assigned
Packing Group: None assigned
Labels: None assigned
Special Provisions: Protect from physical damage and keep container closed during transport
Additional Transport Precautions: Avoid release to environment in case of accident. Secure containers to prevent movement

Regulatory Information

OSHA Status: Not specifically regulated under OSHA standard; general chemical hygiene applies
TSCA Inventory: This substance may be subject to reporting under EPA TSCA guidelines
SARA Title III: Not listed as an extremely hazardous substance
REACH Status (Europe): Registration obligations depend on annual tonnage and end-use; consult with supplier for compliance
DSL/NDSL (Canada): Check with Canadian authorities
Other Regulations: Comply with all local, state, national, and international laws regulating chemical substances
Worker Protection: Training on chemical hazards and safe use is required under most jurisdictions