5-Bromopentyl Acetate: Material Safety Data Sheet List

Identification

Product Name: 5-Bromopentyl Acetate
Chemical Formula: C7H13BrO2
Synonyms: 1-Acetoxy-5-bromopentane
CAS Number: 5369-09-7
Recommended Use: Organic synthesis, laboratory chemical
Manufacturer: Name and contact details required at workplace
Emergency Phone Number: Local emergency numbers should be clearly posted

Hazard Identification

GHS Classification: Harmful if swallowed or inhaled, causes skin and eye irritation
Signal Word: Warning
Hazard Statements: H302 (Harmful if swallowed), H315 (Causes skin irritation), H319 (Causes serious eye irritation), H332 (Harmful if inhaled)
Precautionary Statements: Avoid breathing vapors/mist, wear protective gloves/eye protection, wash thoroughly after handling, do not eat, drink, or smoke during use
Pictograms: Exclamation Mark

Composition / Information on Ingredients

Chemical Name: 5-Bromopentyl Acetate
Concentration: ≥99%
Impurities: Trace organic byproducts from synthesis
Other Components: No hazardous major impurities noted in standard batches

First Aid Measures

Inhalation: Move person to fresh air, keep at rest, seek medical attention if symptoms appear
Skin Contact: Remove contaminated clothing, rinse skin with plenty of water, consult physician if irritation develops
Eye Contact: Rinse cautiously with water for several minutes, remove contact lenses if present and easy to do, continue rinsing, seek medical help
Ingestion: Rinse mouth, do not induce vomiting, seek immediate medical advice
Important Symptoms: Skin redness, eye burning sensation, sore throat, coughing

Fire-Fighting Measures

Suitable Extinguishing Media: Water spray, carbon dioxide, dry chemical powder, foam
Specific Hazards: May release toxic and corrosive vapors including hydrogen bromide and acetic acid on decomposition
Protective Equipment for Firefighters: Full protective gear including self-contained breathing apparatus
Additional Information: Containers exposed to fire may rupture, use water spray to cool unopened containers

Accidental Release Measures

Personal Precautions: Evacuate unnecessary personnel, use proper personal protection
Environmental Precautions: Prevent entry into drains, soil, or waterways
Spill Containment: Absorb with inert material (sand, earth), shovel into chemical waste container
Cleaning Methods: Ventilate area, wash spill site after material pickup complete

Handling and Storage

Handling: Avoid direct contact, use in well-ventilated areas, minimize dust and vapor production
Storage: Store in tightly closed containers in a cool, dry, well-ventilated facility, away from sources of ignition and incompatible materials such as strong oxidizers
Storage Temperature: Ambient, avoid excessive heat or freezing
Special Precautions: Label containers properly, keep away from children and unauthorized personnel

Exposure Controls and Personal Protection

Engineering Controls: Fume hood or local exhaust ventilation
Personal Protective Equipment: Nitrile or neoprene gloves, safety goggles, lab coat, if airborne exposure possible: appropriate respiratory protection
Hygiene Measures: Wash hands before breaks and after handling, do not eat, drink, or smoke when working with this compound
Occupational Exposure Limits: No established limits for 5-Bromopentyl Acetate, keep exposure as low as possible

Physical and Chemical Properties

Appearance: Clear, colorless to pale yellow liquid
Odor: Mild, ester-like
Odor Threshold: Not determined
Molecular Weight: 209.09 g/mol
Boiling Point: Approximately 110-112°C at 15 mmHg
Melting Point: Not applicable (liquid at room temperature)
Vapor Pressure: Not available
Density: 1.324 g/cm³ (approximate)
Solubility: Insoluble in water, soluble in organic solvents (e.g. acetone, ether)
Flash Point: Approximately 80°C (closed cup)
Explosive Properties: Not classified as explosive
Autoignition Temperature: Not available
Partition Coefficient (log Kow): Not determined

Stability and Reactivity

Chemical Stability: Stable under ordinary use and storage conditions
Reactivity: May react with strong oxidizing agents, strong bases
Hazardous Decomposition Products: Hydrogen bromide, acetic acid, carbon oxides under fire conditions
Polymerization: No data indicating hazardous polymerization
Conditions to Avoid: Excessive heat, sparks, open flames, exposure to strong oxidizers

Toxicological Information

Likely Routes of Exposure: Inhalation, skin and eye contact, ingestion
Symptoms: Respiratory tract irritation, skin redness, eye discomfort, possible headache or nausea on inhalation
Acute Toxicity Data: Not fully characterized; structurally related esters showed moderate toxicity, LD50 oral (rat) estimate 1,000–2,000 mg/kg
Chronic Effects: Prolonged or repeated exposure may cause dermatitis, potential risk to liver or kidneys not excluded
Carcinogenicity: Not listed by IARC, NTP, OSHA
Other Data: No detailed reproductive or mutagenic data available

Ecological Information

Aquatic Toxicity: Data not available for this compound, similar esters show low to moderate toxicity to aquatic life
Persistence and Degradability: Expected to undergo slow hydrolysis and biodegradation over time
Bioaccumulative Potential: Not known, potential exists based on log Kow of similar alkyl acetates
Mobility in Soil: Low volatility, poorly water-soluble, may bind to soil organic matter
Other Adverse Effects: No data, avoid uncontrolled environmental release

Disposal Considerations

Disposal Methods: Incinerate in suitable facility, chemical waste should comply with local, regional, and national regulations
Contaminated Packaging: Rinse empty containers with suitable solvent, dispose following hazardous waste regulations
Disposal Recommendation: Avoid discharge into sewers or surface waters, consult waste disposal professionals for safe destruction

Transport Information

UN Number: Not assigned
Proper Shipping Name: Not regulated for transport under most major international regulations
Transport Hazard Class: Not classified
Packing Group: Not classified
Special Transport Precautions: Protect containers from physical damage, keep sealed and upright during transport

Regulatory Information

TSCA Status: Listed or in compliance
EINECS/ELINCS: 226-733-5
SARA/OSHA: Not subject to specific reporting requirements
California Prop 65: Not listed
Other Regulations: Product safety and use should comply with current federal, state, and local regulations pertaining to chemical hazards