Material Safety Data Sheet: 6-Bromohexanoic Acid

Identification

Product Name: 6-Bromohexanoic Acid
Chemical Formula: C6H11BrO2
CAS Number: 2539-66-0
Synonyms: 6-Bromo-hexanoic acid
Recommended Use: Laboratory reagent, chemical synthesis
Supplier Details: Contact supplier or manufacturer for further details
Emergency Contact: Refer to local poison control or emergency services for incidents involving this compound

Hazard Identification

Hazard Classification: Irritant, harmful if swallowed, causes skin and eye irritation
Signal Word: Warning
Hazard Statements: Irritates mucous membranes, respiratory system, skin, and eyes. Risk of serious damage with prolonged exposure.
Pictograms: Corrosive, Exclamation mark
Precautionary Statements: Avoid any direct contact, use only with adequate protection, avoid inhalation
Routes of Exposure: Inhalation, skin contact, eye contact, ingestion

Composition / Information on Ingredients

Chemical Name: 6-Bromohexanoic Acid
CAS Number: 2539-66-0
Concentration: 97-100%
Impurities: Trace organic and inorganic impurities possible, not considered significant in standard laboratory handling

First Aid Measures

Inhalation: Move to fresh air quickly, seek medical advice if discomfort or symptoms persist.
Skin Contact: Wash immediately with plenty of water for at least 15 minutes, remove contaminated clothes, consult a medical professional.
Eye Contact: Rinse thoroughly with plenty of water for at least 15 minutes, lift eyelids occasionally, get medical attention.
Ingestion: Rinse mouth, do not induce vomiting. Get medical assistance immediately. Do not give anything by mouth if victim is unconscious.

Fire-Fighting Measures

Suitable Extinguishing Media: Carbon dioxide, dry chemical powder, foam, water spray (do not use water jet directly on substance)
Unsuitable Extinguishing Media: High-pressure water streams
Fire Hazards: Toxic gases like hydrogen bromide and carbon oxides may release during combustion
Firefighting Procedures: Wear full protective gear and self-contained breathing apparatus
Specific Hazards: Heated containers may rupture, avoid inhaling fumes produced by burning chemical

Accidental Release Measures

Personal Precautions: Wear gloves, goggles, lab coat, and approved respirator
Environmental Precautions: Prevent material from entering water sources or drains
Cleanup Methods: Scoop up using inert absorbent material such as sand, transfer to suitable container for disposal
Ventilation: Provide adequate ventilation in spillage area
Decontamination Procedures: Wash affected area with water and detergent after removal of material

Handling and Storage

Handling: Always handle in well-ventilated areas or fume hoods, avoid inhalation, do not allow contact with skin or eyes, do not eat, drink or smoke during use
Storage: Store in tightly sealed container, protect from moisture and light, keep away from incompatible substances such as strong bases and oxidizers, store at controlled room temperature

Exposure Controls and Personal Protection

Exposure Limits: No occupational exposure limits established, use caution due to irritant properties
Engineering Controls: Use chemical fume hood, eye wash stations, safety showers readily available
Personal Protective Equipment: Chemical-resistant gloves, splash-proof goggles, long-sleeved clothing, face shield if risk of splashing
Respiratory Protection: Use NIOSH-approved respirator if vapor or dusts are likely to be generated
Hygiene Measures: Wash hands thoroughly after handling, change contaminated clothing promptly

Physical and Chemical Properties

Appearance: White to off-white crystalline powder or solid
Odor: Weak, unpleasant odor
Melting Point: 40-45°C
Boiling Point: Decomposes before boiling
Solubility: Moderately soluble in water, soluble in organic solvents like ether and chloroform
Molecular Weight: 195.06 g/mol
pH: Acidic, <7 in aqueous solution
Vapor Pressure: Not established
Density: ~1.5 g/cm³
Flashpoint: Not available

Stability and Reactivity

Chemical Stability: Stable at standard storage and handling conditions, light-sensitive
Reactivity: May react with strong oxidizers and strong bases
Hazardous Decomposition Products: Hydrogen bromide, carbon oxides
Incompatible Materials: Strong oxidizing agents, alkali metal hydroxides
Polymerization: Does not undergo hazardous polymerization under normal conditions

Toxicological Information

Acute Toxicity: Oral and dermal exposures cause irritation, symptoms may include abdominal pain, vomiting, diarrhea if ingested
Chronic Effects: Prolonged or repeated exposure may cause dermatitis or aggravated respiratory conditions
Target Organs: Eyes, skin, respiratory system
Sensitization: Not assessed for sensitization hazard
Carcinogenicity: Not listed as carcinogen by NTP, IARC, OSHA
Mutagenicity: No data available

Ecological Information

Environmental Impact: Harmful to aquatic organisms, danger of long-term adverse effects in aquatic environment
Persistence and Degradability: Expected to degrade slowly in the environment
Bioaccumulative Potential: Not expected to bioaccumulate at significant levels
Mobility in Soil: Moderate mobility, possible leaching to groundwater, monitor disposal practices
Other Adverse Effects: No specific data but prudent to minimize environmental release

Disposal Considerations

Disposal Methods: Collect and transfer material to designated chemical waste container, incinerate in chemical incinerator with afterburner and scrubber if possible
Contaminated Packaging: Dispose of as chemical waste, do not reuse packaging
Environmental Restrictions: Prevent entry into soil, drains, water sources, comply with local, national hazardous waste disposal regulations

Transport Information

UN Number: Not regulated under most transport codes
Proper Shipping Name: Chemicals, n.o.s. (not otherwise specified)
Hazard Class: Not classified as dangerous for transport, still handle with care due to irritant properties
Packing Group: Not assigned
Transportation Precautions: Transport in tightly closed containers, avoid direct sunlight and moisture, secure loads to prevent spillage

Regulatory Information

TSCA Status: Listed on the TSCA inventory
EINECS Status: Listed (219-863-7)
US Federal Regulations: Not subject to major restrictions or reporting requirements under SARA Title III or CERCLA
EU Classification: Xi (Irritant), R36/37/38 (Irritating to eyes, respiratory system, and skin)
Workplace Labeling Requirements: Clearly label containers with identity and hazard warnings as per local law
Other Local Requirements: Adhere to all applicable local, regional, and national occupational safety and health guidelines