Product Name: Ethyl 3-Bromopropionate
Chemical Formula: C5H9BrO2
Synonyms: Propanoic acid, 3-bromo-, ethyl ester
CAS Number: 535-11-5
Recommended Use: Intermediate in organic synthesis, chemical research
Contact Information for Manufacturer: Found on product label, SDS provided by distributor
Emergency Contact Number: Local poison control, emergency responders, or chemical supplier contact
Hazard Classification: Flammable liquid, acute oral toxicity, skin and eye irritation, environmental hazard
Signal Word: Warning or Danger (risk-based)
Hazard Statements: May cause respiratory irritation, skin and eye damage on contact, harmful if swallowed, toxic to aquatic life
Precautionary Statements: Avoid breathing vapor. Wear protective clothing and gloves. Prevent entry into drains. Wash skin thoroughly after handling. Use only outdoors or in well-ventilated area.
Label Pictograms: Exclamation mark, environment, flame
Chemical Identity: Ethyl 3-Bromopropionate
Chemical Formula: C5H9BrO2
Molecular Weight: 181.03 g/mol
Purity: >98% (contact supplier for exact levels)
Impurities: Trace amounts of byproducts from synthesis, no significant hazardous impurities disclosed by main suppliers
General Measures: Move affected person to fresh air, keep at rest, do not leave unattended
Inhalation: Remove from exposure zone. Provide oxygen or artificial respiration as needed. Seek immediate medical attention.
Skin Contact: Remove contaminated clothing immediately. Rinse skin with plenty of water for at least 15 minutes. Seek medical assistance if irritation develops.
Eye Contact: Rinse cautiously with water for several minutes. Remove contact lenses if present. Continue rinsing, get medical help right away.
Ingestion: Rinse mouth with water. Do not induce vomiting unless instructed by a health professional. Get medical attention.
Suitable Extinguishing Media: Dry chemical powder, foam, carbon dioxide, water spray
Unsuitable Media: Direct water jets
Specific Hazards: Vapors may form explosive mixtures with air. Containers may explode when heated. Hazardous combustion products such as hydrogen bromide, carbon oxides may form.
Personal Protective Equipment for Firefighters: Chemical-resistant suit, self-contained breathing apparatus
Special Instructions: Cool containers with water spray. Avoid inhalation of combustion products. Evacuate nonessential personnel from area.
Personal Precautions: Wear chemical splash goggles, gloves, lab coat or coveralls, use local exhaust or respirator if vapor is present.
Environmental Precautions: Prevent run-off into surface waters, drains, and sewers. Notify authorities if environmental release occurs.
Spill Cleanup Methods: Absorb liquid using sand, earth, or inert material. Transfer solid or absorbed materials to waste container. Ventilate area and wash spill location with water after pickup is complete.
Precautions for Safe Handling: Use in a chemical fume hood or well-ventilated space. Avoid inhalation, ingestion, and contact with skin or eyes. Wash hands after use.
Storage Conditions: Store in a tightly closed container, in a cool, dry, well-ventilated area, away from incompatible substances such as strong bases, oxidizers, or acids. Protect from light, heat, and moisture.
Incompatible Materials: Strong oxidizing agents, strong bases or acids
Engineering Controls: Laboratory fume hood or exhaust ventilation, eyewash station and safety shower
Personal Protective Equipment: Safety goggles or face shield, chemical-resistant gloves (nitrile, neoprene), long-sleeved lab coat or apron, closed-toe shoes
Respiratory Protection: Approved respirator for organic vapor exposure if ventilation is inadequate
Occupational Exposure Limits: No specific ACGIH or OSHA PELs established; minimize exposure as much as possible
Appearance: Colorless to pale yellow liquid
Odor: Fruity, sweet odor
Boiling Point: 191–193°C
Melting Point: -33°C
Flash Point: 82°C
Density: 1.41 g/cm³
Solubility: Slightly soluble in water, miscible with most organic solvents
Vapor Pressure: 0.2 mmHg at 20°C
Viscosity: Not available
pH: Not determined (does not dissociate in water)
Partition Coefficient: log Pow 1.3 (estimated)
Chemical Stability: Stable under recommended storage conditions
Conditions to Avoid: Excessive heat, open flame, strong oxidizing agents, and moisture
Hazardous Decomposition Products: Carbon monoxide, carbon dioxide, hydrogen bromide, possible corrosive vapors
Polymerization: Not known to occur
Incompatible Materials: Strong bases, strong acids, oxidizing agents
Acute Toxicity: May be harmful if swallowed or inhaled, toxic to skin and eyes
Skin and Eye Irritation: Causes moderate to severe eye and skin irritation
Respiratory Sensitization: Inhalation of vapor or mist can irritate respiratory system
Chronic Toxicity: Repeated or prolonged exposure can cause dermatitis, respiratory tract irritation
Carcinogenicity: Not classified as carcinogenic by IARC, NTP, OSHA
Genotoxicity: Data not available
LD50 (oral, rat): 1370 mg/kg (data source: supplier literature)
Ecotoxicity: Harmful to aquatic organisms, with potential long-term effects in aquatic environments
Persistence and Degradability: Only partial biodegradation in environment, not readily biodegradable
Bioaccumulation Potential: Low to moderate, log Pow of 1.3
Mobility in Soil: May leach through soil, evaporates slowly
Aquatic Toxicity: LC50 values not widely published, consider as toxic at low concentrations
Waste Disposal Methods: Dispose of in accordance with local, regional, and national regulations through a licensed waste disposal contractor
Contaminated Packaging: Triple rinse containers, puncture after use, dispose as hazardous material
Precautions: Do not release into sewers, waterways, or soil
UN Number: 2810
Proper Shipping Name: Toxic liquid, organic, n.o.s. (includes Ethyl 3-Bromopropionate)
Transport Hazard Class: 6.1 (Toxic substances)
Packing Group: III
Environmental Hazards: Marine pollutant
Transport Labels: Toxic, environmentally hazardous substance symbol
Special Precautions for Transport: Secure containers against movement or breakage, protect against moisture and physical damage during shipment
Regulatory Status: Subject to TSCA in the United States, REACH in the EU, and other chemical regulatory schemes
Hazardous Chemical Listings: Present on US TSCA, Canadian DSL, EU REACH inventory
SARA Title III: Not listed as Extremely Hazardous; may trigger reporting based on quantities stored
Workplace Labelling Requirements: OSHA-compliant labeling required with hazard identification
Other Regulatory Notes: Check regional, provincial, and local chemical management laws for additional guidance. Restrictions or special handling may apply based on local regulations.
