Product Name: Methyl 6-Bromohexanoate
Chemical Formula: C7H13BrO2
Synonyms: 6-Bromohexanoic acid, methyl ester; Hexanoic acid, 6-bromo-, methyl ester
CAS Number: 26256-23-1
Company Identification: Not specified
Recommended Use: Laboratory chemical, research use
Contact Information: Refer to safety officer or SDS provider
GHS Classification: Skin irritation, Eye irritation, Acute toxicity (oral and inhalation)
Hazard Statements: May cause skin and eye irritation, may be harmful if swallowed or inhaled, toxic to aquatic life
Signal Word: Warning
Pictograms: Exclamation mark, Environment
Precautionary Statements: Avoid breathing dust, wear protective gloves and eye protection, handle in well-ventilated space
Chemical Identity: Methyl 6-Bromohexanoate
CAS Number: 26256-23-1
Percent Range: >98% by weight
Impurities: Inorganic bromides, unreacted hexanoic acid esters (trace)
Inhalation: Move affected person to fresh air, seek medical attention if symptoms persist, provide oxygen if breathing becomes difficult
Skin Contact: Remove contaminated clothing, rinse skin with soap and water for at least 15 minutes, seek medical attention if irritation develops
Eye Contact: Rinse thoroughly with water for at least 15 minutes lifting upper and lower eyelids, seek immediate medical attention
Ingestion: Rinse mouth, do not induce vomiting, seek immediate medical attention
Symptoms: Redness, irritation to eyes or skin, coughing, shortness of breath, gastrointestinal discomfort
Suitable Extinguishing Media: Dry chemical, carbon dioxide, foam, water spray
Unsuitable Extinguishing Media: Direct water jet
Special Hazards: Combustion produces toxic and irritating fumes such as hydrogen bromide, carbon monoxide, carbon dioxide
Protective Equipment: Firefighters should wear self-contained breathing apparatus and full protective gear
Other Information: Avoid runoff from fire control entering waterways, cool exposed containers with water spray to prevent explosion
Personal Precautions: Use proper personal protective equipment, avoid breathing vapors or dust, ensure adequate ventilation
Environmental Precautions: Prevent further leakage or spillage, avoid release to environment, contain runoff
Methods for Cleanup: Absorb with inert material (e.g., sand or earth), collect spilled material in container for chemical waste disposal, clean area thoroughly after removal
Handling: Use in a chemical fume hood, avoid contact with skin, eyes, and clothing, wash hands thoroughly after use, keep away from incompatible substances
Storage Conditions: Store in tightly closed container, keep in a cool, dry, well-ventilated place away from heat, sources of ignition, acids, bases, and oxidizing agents
Incompatibilities: Strong oxidizers, strong acids and bases, reducing agents
Storage Temperature: Recommended storage at 2-8°C
Engineering Controls: Mechanical ventilation, fume hood, emergency eye wash stations and safety showers in vicinity
Personal Protective Equipment: Chemical-resistant gloves (nitrile), splash-resistant goggles, lab coat or disposable coveralls, respiratory protection if ventilation is inadequate
Exposure Limits: No OSHA or ACGIH limits established for this compound
Hygiene Measures: Do not eat, drink, or smoke in work area, wash hands and face after handling
Appearance: Clear to pale yellow liquid
Odor: Mild, ester-like
Melting Point: -24°C (approximate)
Boiling Point: 126-127°C at 9 mmHg
Flash Point: >110°C (estimated, not precise)
Solubility: Insoluble in water, soluble in organic solvents like alcohols and ethers
Vapor Pressure: Not readily available, low at room temperature
Density: 1.35 g/cm³ (20°C)
pH: Not applicable
Refractive Index: 1.462-1.464
Partition Coefficient (log Kow): Estimated at 2.6-3.1
Chemical Stability: Stable under normal temperatures and pressures if stored properly
Conditions to Avoid: Heat, flames, ignition sources, direct sunlight, moist or humid environments
Incompatible Materials: Strong oxidizing agents, acids, bases
Hazardous Decomposition Products: Carbon monoxide, carbon dioxide, hydrogen bromide fumes
Hazardous Polymerization: Not expected to occur
Acute Toxicity: Low to moderate oral and inhalation toxicity expected based on structure and related esters
Routes of Exposure: Inhalation, ingestion, skin and eye contact
Symptoms: May cause irritation of mucous membranes, gastrointestinal distress, skin redness, eye lacrimation
Chronic Effects: No chronic toxicity data available; prolonged or repeated exposure might cause dermatitis
Carcinogenicity: Not listed by IARC, NTP, or OSHA
Mutagenicity: No data available
Reproductive Toxicity: No data available
Aquatic Toxicity: Hazardous to aquatic ecosystems with possible long-term adverse effects
Persistence and Degradability: Not rapidly biodegradable, may persist in the environment
Bioaccumulative Potential: Potential for accumulation in aquatic organisms (estimated log Kow indicates possible risk)
Mobility in Soil: Likely moderate mobility due to partial solubility in water but high affinity for organic matter
Other Adverse Effects: Avoid release to environment, toxic to aquatic organisms even at low concentrations, possible impact on soil microfauna
Waste Disposal Method: Must be handled as hazardous chemical waste, use a licensed professional waste disposal service
Contaminated Packaging: Empty containers should be treated with the same precautions as unused material and disposed according to local regulations
Other Information: Dispose of in accordance with all national and local environmental regulations, incineration preferred with energy recovery
UN Number: Not classified
Shipping Name: Not regulated for transport under UN, IMDG, or IATA regulations (verify with current codes)
Hazard Class: Not assigned
Packing Group: Not assigned
Marine Pollutant: Possible hazard due to aquatic toxicity
Special Precautions: Transport in tightly sealed containers, protected from mechanical damage, avoid transport with foodstuffs
TSCA Status: Listed or exempt
SARA 313: Not listed as a reportable substance
REACH Status: Registration might not be required for research quantities, check supplier compliance
California Proposition 65: Not listed
WHMIS Classification (Canada): D2B (Skin/Eye Irritant) may apply
Other Local Regulations: Follow national, regional, and local chemical safety and waste guidelines for handling, consumption, and disposal
Inventory Status: Check relevant national inventories (EINECS, EC, AICS, etc.) for current listing
