Product Name: Methyl Anthranilate
CAS Number: 134-20-3
Synonyms: Methyl 2-aminobenzoate, MA
Molecular Formula: C8H9NO2
Molecular Weight: 151.16 g/mol
Recommended Use: Flavoring agent, fragrance component, bird repellent
Supplier: Refer to the packaging or product literature for details
Contact Information: Emergency and supplier phone numbers listed on product packaging
Classification: Irritant, not classified as hazardous under GHS for most uses
Signal Word: Warning
Hazard Statements: May cause mild skin, eye, and respiratory irritation
Pictograms: Exclamation mark
Precautionary Statements: Avoid breathing vapors, wash exposed skin after use, use with adequate ventilation
Health Hazards: May cause allergic skin reaction in sensitive individuals
Environmental Hazards: Harmful to aquatic life in concentrated spills
Physical Hazards: Combustible liquid and vapor
Chemical Name: Methyl Anthranilate
Concentration: ≥99% by weight
Impurities: Typical trace amounts of related esters, residual moisture
Hazardous Ingredients: None present above regulatory disclosure thresholds
Other Components: No additional additives reported
Inhalation: Move person to fresh air, seek medical attention if symptoms persist
Skin Contact: Remove contaminated clothing, wash skin with soap and water, consult physician if irritation develops
Eye Contact: Rinse eyes cautiously with water for at least 15 minutes, remove contact lenses if present, seek medical attention for persistent discomfort
Ingestion: Rinse mouth, do not induce vomiting, drink water if conscious, call physician or poison control center
Other Advice: For all instances, consult medical staff for continued symptoms or large exposures
Suitable Extinguishing Media: Water spray, foam, dry chemical, or carbon dioxide
Specific Hazards: Combustible; vapors may form explosive mixtures with air at elevated temperatures
Hazardous Combustion Products: Carbon oxides, nitrogen oxides, irritating organic vapors
Protective Equipment: Firefighters use self-contained breathing apparatus and protective gear
Firefighting Instructions: Stay upwind, cool exposed containers with water spray, avoid breathing smoke and gases
Personal Precautions: Evacuate area if large spill, ensure proper ventilation, use personal protective equipment
Environmental Precautions: Prevent entry to waterways, drains, and soil
Cleanup Methods: Absorb with inert material, collect for disposal in sealed container, clean area with soap and water
Disposal: Dispose in accordance with local, regional, and national regulations
Handling: Avoid inhalation of vapors and contact with skin or eyes, use with local exhaust ventilation, keep container tightly closed
Storage: Store in cool, dry, well-ventilated area away from heat, sparks, open flame, and incompatible materials such as strong oxidizers
Incompatible Materials: Strong acids, strong bases, strong oxidizers
Packaging: Keep in original container, label clearly
Engineering Controls: Use local exhaust ventilation to control exposure in confined areas
Respiratory Protection: Use approved organic vapor respirator in poorly ventilated or high-exposure situations
Skin Protection: Wear chemical-resistant gloves, protective clothing
Eye Protection: Safety goggles or face shield
Exposure Limits: No established OSHA or ACGIH exposure limits
General Hygiene: Wash hands before eating or drinking, remove contaminated clothing promptly
Appearance: Pale yellow liquid
Odor: Grape or orange blossom, sweet and floral
Odor Threshold: Noticeable at low ppm
pH: Not applicable (neutral ester)
Melting Point: Approximately -24°C
Boiling Point: 256°C
Flash Point: 104°C
Evaporation Rate: Slow
Flammability: Combustible
Explosive Limits: Not established
Vapor Pressure: 0.01 mmHg at 20°C
Vapor Density: >1 (air = 1)
Relative Density: 1.17 g/cm³
Solubility: Slightly soluble in water, miscible with alcohol, ether
Partition Coefficient (log Kow): 1.79
Auto-ignition Temperature: 495°C
Decomposition Temperature: Not specified
Viscosity: Low
Chemical Stability: Stable under recommended storage conditions
Stability Issue: May react with strong oxidizers, acids, bases; avoid extremes of temperature
Hazardous Reactions: None under normal handling
Hazardous Decomposition: Carbon monoxide, carbon dioxide, nitrogen oxides in fire
Polymerization: Will not occur
Acute Toxicity: Oral LD50 (rat) > 3000 mg/kg
Inhalation: Low toxicity via inhalation expected; vapors may irritate mucous membranes
Skin Corrosion/Irritation: May cause mild irritation
Serious Eye Damage/Irritation: May cause temporary discomfort
Respiratory Sensitization: Not classified as sensitizer
Skin Sensitization: Not classified, though sensitive users may develop rash
Germ Cell Mutagenicity: Not classified
Carcinogenicity: Not listed as a carcinogen by IARC, NTP, OSHA
Reproductive Toxicity: No evidence of reproductive toxicity
Target Organ Toxicity: No specific target organ identified
Repeated Dose Toxicity: Not expected under normal use
Ecotoxicity: Fish LC50 (96 h) ≈ 100 mg/L, considered low to moderate hazard
Persistence and Degradability: Readily biodegradable in natural environment
Bioaccumulative Potential: Low potential based on log Kow values
Mobility in Soil: Low, may adsorb to soil particles
Other Effects: Large-volume spills may impact aquatic environments temporarily; avoid direct disposal to waterways
Waste Disposal: Dispose as non-hazardous organic chemical if uncontaminated, according to regional and local requirements
Contaminated Packaging: Clean empty containers before recycling or disposal; manage residues as hazardous if contaminated with incompatible substances
Methods: Incineration most effective for destruction; small quantities treated via chemical disposal in accordance with local regulations
Regulations: Follow all applicable regulations for disposal and environmental management
UN Number: Not regulated by most ground/sea transport authorities
Proper Shipping Name: Not regulated for ground, air, sea
Transport Hazard Class: Not classified
Packing Group: Not assigned
Labeling Requirements: Not required for general cargo
Special Precautions: Avoid shipment with strong oxidizers, acids, or basic materials
OSHA Status: Not considered hazardous under US OSHA rules
TSCA Inventory: Listed
SARA 302/304/313: Not listed as reportable
EPA Status: Not regulated as a hazardous waste
California Prop 65: Not listed
FDA GRAS Status: Approved for use as a flavoring substance
REACH Registration: Registered in the EU
Chemical Inventories: Listed in AICS (Australia), DSL (Canada), EINECS (Europe), ENCS (Japan), PICCS (Philippines), IECSC (China)
