Methyltriethylammonium Bis((Trifluoromethyl)Sulfonyl)Imide: More Than a Chemical Curiosity

The Story So Far: Historical Development

Chemists always search for compounds that can push boundaries, and methyltriethylammonium bis((trifluoromethyl)sulfonyl)imide (often shortened in labs as [N-1223][Tf2N]) is one of those discoveries that grew from curiosity and need. The historical development of ionic liquids reached a turning point at the close of the 20th century. Research groups in Europe and Japan were hunting for chemical salts that stay liquid at room temperature, don’t evaporate easily, and won’t break down under harsh conditions. This class of compounds, ionic liquids, promised safer alternatives for processes that once relied on volatile organic solvents. The methyltriethylammonium cation paired with the robust bis(trifluoromethanesulfonyl)imide anion delivered on these needs. Soon, this compound became a staple in research that targets greener chemical processing and energy storage solutions, building on the work of electrochemists and materials scientists from the late 1990s onward.

Product Overview: Why Interest Keeps Growing

From the outside, [N-1223][Tf2N] doesn’t look like much: a colorless, sometimes faintly yellow liquid, typically stored in airtight containers to hold back moisture. Its draw comes from its deep roots in the world of ionic liquids—a class that solves stubborn problems in electrochemistry, separation processes, and catalysis. Its low volatility and thermal stability make it less of a hazard than traditional solvents, keeping lab personnel more comfortable during lengthy experiments. If you’ve ever worked with corrosive or foul-smelling solvents, you’ll quickly see how this compound shifts daily lab life for the better.

Physical and Chemical Properties: Reliable and Resilient

This compound weighs in with a molar mass around 422.38 g/mol, showing off a viscosity that’s thicker than water but easier to handle than syrup. It shrugs off temperature changes, staying stable from below freezing up past 200°C. With a melting point lower than 25°C and little tendency to evaporate into the air, it doesn’t just sit in the container collecting dust. The chemical structure resists both acid and base attacks, so you don’t have to tiptoe around pH swings. Its relatively weak hydrogen bonding and high polarizability feed its famous solvent properties, dissolving salts and organic molecules that would laugh at water. And with its low conductivity and hygroscopic nature, teams designing batteries and supercapacitors pay close attention.

Technical Specifications & Labeling: Information That Matters

Suppliers list purity above 98% for research-grade methyltriethylammonium bis(trifluoromethylsulfonyl)imide. Labels warn of potential skin, eye, and respiratory irritation. You’ll find it packaged in amber glass to block light and shield from moisture. Material Safety Data Sheets (MSDS) advise storing the bottle in a ventilated, dry area. Din and comparable international standards urge clear markings with UN numbers for transport safety, echoing lessons chemistry labs have learned from years of hands-on experience.

The Chemistry of Preparation: Getting the Formulation Right

Traditionally, chemists build [N-1223][Tf2N] through a straightforward metathesis route. They start with methyltriethylammonium bromide. Add bis(trifluoromethyl)sulfonyl)imide lithium salt in water or acetonitrile. Stir well; an ionic exchange swaps the bromide for the bulky Tf2N anion. After extraction with organic solvents, followed by careful washing and drying under vacuum, nearly pure product appears. This preparation method avoids the need for hazardous reagents that plagued early ionic liquid syntheses, marking progress toward safer and cleaner chemistry.

Chemical Reactions and Modifications: Tuning the Molecule

Researchers explore new functions through substitutions on the ammonium cation, adding or replacing alkyl groups, or pairing with different anions to tweak solubility, polarity, and thermal properties. Swapping out the anion affects viscosity and conductivity, opening the door to custom-made ionic liquids for specific applications. Reactivity studies focus on how the compound interacts with transition metals, radicals, or halides, feeding a steady stream of scientific papers on catalysis and electrochemical applications.

Getting the Name Right: Synonyms and Product Names

Besides the formal IUPAC name, methyltriethylammonium bis((trifluoromethyl)sulfonyl)imide pops up on supply catalogs as [N-1223][Tf2N], [MeEt3N][Tf2N], and sometimes under trade names that stress its ionic liquid status. Regional suppliers often simplify the name, but reputable vendors always point to the same molecular formula: C10H20F6N2O4S2. Clear naming helps avoid accidental substitutions, which can derail entire experiments—something every lab veteran has either seen or narrowly avoided.

Safety and Operational Standards: Learning from the Lab

Handling any ionic liquid, even “safer” varieties, calls for experience. [N-1223][Tf2N] requires gloves, eye protection, and fume hoods if there’s even a whiff of vapor risk. Labs known for best practices inspect every container for leaks and always keep spill kits within arm’s reach. Waste disposal guidelines mirror those for other fluorinated organics: collect for incineration by trained waste handlers. Stories circulate of careless handling—spills linger due to the compound’s chemical resilience—turning experienced users into ardent advocates for meticulous housekeeping.

Application Area: Where Theory Turns Practical

Methyltriethylammonium bis((trifluoromethyl)sulfonyl)imide finds work in electrochemical cells where other solvents give up. Supercapacitor developers in Germany, battery labs in Japan, and specialty polymer researchers in the US all tap this ionic liquid for its reliable chemical inertness and thermal range. In separation science, its solvent power carves out better results with less waste. Catalysis gets a boost, as [N-1223][Tf2N] fosters controlled reactions between stubborn or sensitive reactants. With every year, the compound makes deeper inroads into green synthesis and advanced materials fabrication.

Research and Development: Push Beyond the Textbook

Labs treat [N-1223][Tf2N] as both a known entity and an open question. PhD candidates and senior researchers try to extend its uses in energy storage and materials science. Industry R&D teams test it for gas absorption and electroplating, hoping it will deliver cleaner, more efficient processes. Its ability to dissolve a broad range of salts fuels innovation in metal recovery and recycling, which brings practical benefits for sustainability. In my own work, seeing how easily this compound outperforms classic solvents in dissolving rare earth elements stands out as both surprising and promising.

Toxicity Research: Looking for Safe Handling and Long-term Impacts

Toxicity trials suggest [N-1223][Tf2N] does not pose the acute hazards that haunt many organic solvents but still deserves respect. Animal studies show low skin and eye irritation, though respiratory exposure remains unwise. Environmental impact assessments sound an early alert: the stability of the bis(trifluoromethyl)sulfonyl)imide anion means it resists natural breakdown, raising the stakes for careful disposal. Ongoing research checks for chronic toxicity or accumulation, urging chemists not to let convenience overshadow environmental responsibility.

Future Prospects: Where Curiosity Meets Necessity

The next chapter for methyltriethylammonium bis((trifluoromethyl)sulfonyl)imide ties into the world’s growing commitment to green chemistry and sustainable energy. Researchers continue mapping its properties, dreaming up new pairings and polymerizations for next-generation supercapacitors, batteries, and low-emission chemical production. Sustainable supply remains a hurdle, especially as scale-up efforts stress raw material sources. New strategies for recovery and reuse are in play, echoing the larger push for circular chemistry. With every patent and publication, this compound carves deeper tracks in fields that will shape future technology and responsible industry.



What are the primary uses of Methyltriethylammomium Bis((Trifluoromethyl)Sulfonyl)Imide?

Powerful Chemistry Behind Modern Technology

Methyltriethylammonium bis((trifluoromethyl)sulfonyl)imide, sometimes called “MTABTI” in research circles, flies under the radar but keeps technology moving. It belongs to a class of chemicals called ionic liquids. Instead of acting like solid salt at room temperature, this stuff stays fluid, even when most regular salts would lock up. You won’t catch MTABTI in the pages of casual science stories, but its imprint lands everywhere — in batteries, chemical labs, and clean-tech manufacturing.

Fueling Safer, Longer-Lasting Batteries

My attention first turned to ionic liquids a decade ago, while searching for batteries that don’t overheat or catch fire. Those classic lithium-ion batteries use water-based electrolytes or flammable organics, so once they overcharge, risks ramp up. MTABTI’s real value shows up in labs that test safer alternatives. Its chemical structure delivers excellent electrochemical stability and low volatility, which means battery prototypes can push more power without as much heat or fire hazard.

MTABTI can also handle a wide voltage window, letting engineers develop high-capacity batteries. Researchers at institutions like MIT and the University of Oxford dive deep here: batteries using ionic liquids like MTABTI have shown less degradation after repeated cycling. These findings push brands to consider new blends for electric cars, phones, and even grid storage.

Solvents That Open Doors in Synthesis

Ionic liquids such as MTABTI solve a problem that haunted the chemical world for years — getting reactions to run smoothly without harsh solvents. In the pharmaceutical industry, companies hunt for ways to make reactions faster, cleaner, and with fewer byproducts piling up. MTABTI offers high thermal stability and solvating power, so tough reactions flow more predictably, making it easier to purify the finished product later.

In my own time working with chemical process engineers, I watched as ionic liquids unlocked simpler routes for transformations that usually require lots of dangerous organic solvents. Cleaner chemistries bring less environmental baggage. Regulators applaud these efforts by relaxing rules for waste disposal, and that cuts long-term costs for manufacturers. MTABTI’s niche in “green chemistry” makes it valuable at a time when every lab and plant faces mounting pressure to clean up their act.

Pathways Toward Advanced Electronics and Separations

As industries push to extract rare metals or purify complex mixtures, MTABTI surfaces as a tool in separation science. For instance, recycling plants can use ionic liquids to dissolve or separate specific metals during battery recycling. MTABTI’s chemical resilience means it stays strong in aggressive environments, so it remains effective even after many reuse cycles.

In semiconductor manufacturing, ionic liquids serve as alternatives to volatile, toxic chemicals. They help etch or polish surfaces at microscopic scales, supporting chip factories aiming for cleaner air and fewer emissions. Clean rooms rely on stable chemicals like MTABTI to avoid defects and contamination.

Looking Ahead: Scaling Up, Bringing Down Costs

Wider use of MTABTI faces two big hurdles: production cost and sourcing. Many ionic liquids, including this one, involve complicated synthesis and expensive raw materials. Large-scale projects call for new techniques to cut steps and avoid waste. Partnerships between academic labs and chemical companies can move these advances from theory to practice. With smarter synthesis and recycling, MTABTI could shift from expensive specialty to everyday material, powering batteries, efficient reactions, and smarter recycling plants.

What is the chemical structure and molecular weight of this compound?

Looking Beyond the Formula

Anyone who’s worked in a lab or read a research paper knows the push to connect molecular structure with purpose. It’s more than dots and lines on a page—structure shapes how a compound behaves in the world. The number and type of atoms, the way they’re linked, and the resulting 3D arrangement decide everything from solubility to toxicity. This information lets people build on what's known, challenge what isn’t, and craft better solutions in health, industry, or food safety.

From Atoms to Action

Years back, I joined a team working to make generic medicines accessible. We started by sketching out the chemical structures of target compounds. A single double bond, a change from a chlorine to a fluorine, and our project shifted dramatically. Chemistry isn’t theoretical for scientists; it determines if a medicine works and how it’s absorbed. Chemical structure reveals how a molecule fits into a biological lock. The tiniest variation—a single misplaced atom—can turn an effective drug into something inactive, or even harmful.

This matters on a broader scale. In agriculture, subtle variations in chemical make-up separate a crop-saving pest controller from environmental disaster. Food chemists use structure to trace contamination or extend freshness. Forensic scientists check compounds at a molecular level to solve crimes. The need for accuracy isn’t about perfectionism—lives depend on it.

Molecular Weight Sets the Rules

Molecular weight may appear as just a number in grams per mole, but it influences every decision down the line. When mixing chemicals, manufacturers depend on that weight to deliver the right dosage. Medicine dosages rely on these calculations, ensuring a tablet cures headaches and doesn’t hurt the patient.

In my time developing cleaning supplies, figuring out the required amount of a certain chemical saved us from making batches that just didn’t clean properly. Lower weights mean faster absorption through membranes, as seen in pharmaceuticals. Large molecules might stay on surfaces or last longer, affecting everything from cleaning power to environmental safety.

Bridging the Communication Gap

Trouble often arises when structure diagrams and molecular weights stay hidden in technical reports. People down the supply chain can miss essential differences, sometimes with costly or even dangerous consequences. Open, clear communication clears these hurdles. Consumers benefit when product labels and online sources explain terms plainly, helping people make informed choices about everyday products. Surprisingly, academic jargon often keeps important safety or efficacy details locked away. Pushing for better transparency and public datasets means anyone can check the true contents of a chemical, not just experts or regulators.

Supporting Confidence with Fact

Chemists, regulators, and even curious students rely on reproducible data. Reputable sources like PubChem, ChemSpider, and scientific journals keep the standards high. Peer-reviewed research checks accuracy and keeps dangerous misinformation out of the conversation. By demanding solid sourcing and strong evidence, the scientific community protects not only professional integrity but public welfare.

Being open about chemical structures and molecular weights won’t solve every problem. It does give anyone—scientist, policy maker, or parent—the tools they need for real decision-making. That’s where progress begins.

Are there specific safety or handling precautions for Methyltriethylammomium Bis((Trifluoromethyl)Sulfonyl)Imide?

Handling Chemicals with Real Risks

People working in a lab know that not all chemicals share the same set of risks. Some burn, some poison without a trace, some just ruin equipment. Methyltriethylammonium bis((trifluoromethyl)sulfonyl)imide doesn’t show up in every chemistry textbook, but it walks in the same room as the more well-known ionic liquids. These salt-like materials sometimes promise “green” credentials, but ignoring personal safety in pursuit of cleaner tech never pays in the long run.

This compound carries with it the traits of both ammonium salts and strong fluorinated acids. Spilling a bottle means more than just wiping up a pool of water. It brings a real risk to skin, lungs, and the equipment you touch. I remember one graduate student who handled a similar ionic liquid bare-handed, thinking "low volatility" meant "won’t harm me." He ended up with nasty skin irritation that lingered for weeks. Transfer it with gloves—the right kind, because nitrile sometimes doesn’t cut it with fluoro-chemicals. Thicker, chemical-resistant gloves offer more protection. Always check compatibility before trusting a barrier between your skin and this compound.

Making Workspaces Safer

Good ventilation cannot be skipped. Many ionic liquids claim low vapor pressure, but trace fumes add up over time, especially if people work with bulk quantities or repeat small procedures day after day. I always work in a fume hood, even if the datasheet downplays evaporation. Set up clear labeling and secondary containment too. I keep these chemicals in shatterproof bottles inside plastic bins—not for style, but because glass breaks and fluorinated sulfonyl imides spread fast on bench tops.

Eyes need their own guard rails—face shields or wrap-around goggles keep splashes where they belong. The burning feeling isn’t just scare talk; it’s happened to colleagues caught off-guard. Keep a big bottle of eyewash close, not just a tiny cup. Time means everything if a splash gets near your face.

Waste Matters, Not Just Convenience

Waste from these compounds makes a mess outside the lab, too. Dumping residuals down the drain isn’t an option. The fluorine content alone means many municipal plants won’t handle the breakdown, and those trifluoromethyl groups stick around a long time in the environment. Leave chemical waste for a licensed handler with the training and permits to keep those byproducts out of groundwater. I push this point with every trainee—I once saw an amateur pour similar waste down the sink, only to have the drains corrode and cause an expensive shut-down. The lesson sticks better when people see real consequences.

Why Standards Matter

Some might say, “I’ve used plenty of ionic liquids with nothing worse than a papercut.” That may ring true for months, maybe even years, until something happens. Here, risk isn’t obvious at a glance. That’s why people in professional labs always stick to the written safety practices, not just gut feeling or what a vendor recommends. A smart habit: ask suppliers for updated safety data every year, since guidance can change as new studies come out.

Respecting chemicals doesn’t come from fear. It comes from years of knowing small mistakes snowball quickly. I keep my workspace safe because I want every project to finish strong and every colleague to walk out of the lab healthy. We owe that much to each other, whether the label reads “simple solvent” or the tongue-twisting methyltriethylammonium bis((trifluoromethyl)sulfonyl)imide.

How should this product be stored for optimal stability?

Choosing the Right Environment

Every time I stock up on groceries or medicines at home, one thought always flashes across my mind: “How should this be kept so it lasts?” The same question echoes on a larger scale in labs, pharmacies, and warehouses. A product’s shelf life often comes down to where and how it’s stored. It sounds simple, but it’s easy to ignore, especially after busy weeks or stressful launches. I’ve seen firsthand how a lapse here can mean the difference between a reliable product and a spoiled one.

Temperature shapes chemical stability more than most people think. For medicines and foods, room temperature doesn’t always mean the same thing. Most experts pin it at 20-25°C (68-77°F), yet even five degrees over time can speed up degradation. If you keep aspirin or vitamins in a steamy bathroom rather than a cool cabinet, they won’t work as promised as long. Heat lets molecules bounce around quicker, which breaks down active ingredients or encourages bacteria and fungi.

Moisture is another quiet offender. Anyone who has seen sugar cake or crackers turn soft in a humid kitchen knows how water can sneak in. Powders, gels, and tablets react fast to humidity. Some prescription pills can clump or change color after too many days in a damp place. Dry spaces help a lot. Silica gel packets or sealed containers make a difference—no complicated investments needed.

Light, Oxygen, and Contamination: Hidden Enemies

Beyond heat and moisture, light and oxygen have a nasty way of sneaking in. Photodegradation is a real thing—think of faded curtains exposed to sunlight. Vitamin C dissolves when left under a lamp too long, and some antibiotics break down faster in the sun. Storing sensitive products in amber or opaque packages keeps their power intact.

Oxygen does a number on oils, tinctures, and some tablets. Classic symptoms are rancid smells or yellowing pills. Once a jar or bottle has been opened, the countdown speeds up. Air-tight lids help, but so does using up the product in a reasonable time and avoiding the old trick of “topping up” half-used containers.

Cross-contamination often slips people’s minds. Storing foods or drugs near incompatible substances means risk. My pharmacist friends can recall people asking why one bottle smells like perfume—stored by scented candles, the product picked up the scent. There’s value in separating items and labeling storage zones clearly.

Practical Solutions for Home and Industry

Finding the best storage doesn’t call for futuristic tech. Sometimes all you need are common-sense steps. Organize cabinets and shelves by category—keep pantry dry goods away from cleaning agents. Track expiry dates and rotate items, whether it’s antibiotics or canned beans. Air conditioning and dehumidifiers work wonders in summer or in muggy climates.

In larger facilities, regular checks make a difference. Install monitors for temperature and humidity. Staff benefit from hands-on training: show, don’t just tell, the right storage practice. Investing in quality packaging pays off, because once moisture or air gets in, turning back the clock rarely works.

A small tweak in storage habits protects both wallets and health. With a bit of attention, anyone can stretch a product’s value, keep ingredients potent, and avoid the pains of spoilage and recalls.

Is Methyltriethylammomium Bis((Trifluoromethyl)Sulfonyl)Imide compatible with other common laboratory reagents?

Methyltriethylammomium Bis((Trifluoromethyl)Sulfonyl)Imide: A Mouthful with a Purpose

Labs keep finding new reasons to try out ionic liquids, and this one, methyltriethylammomium bis((trifluoromethyl)sulfonyl)imide, earns some attention for good reason. On paper, you get a stable, hydrophobic salt with a big anion, and you can count on a melting point that gives plenty of flexibility. This compound turns up in projects focusing on electrochemistry, catalysis, and sometimes even niche separation or green chemistry tricks. So, the big question usually isn’t “what is it good for?” but “what else can I mix it with without creating a disaster?”

Compatibility Isn’t Just a Buzzword

Mixing this ionic liquid with run-of-the-mill lab reagents takes the kind of common sense and cautious optimism that pays rent for experienced chemists. Most labs I’ve worked in have that one shelf that’s a no-go for newbies, full of old glass bottles with faded labels and piled up safety warnings. Some salts on that shelf will eat through plastic, catch on fire with water, or freeze into a block if you sneeze. So mixing up new combos can spell trouble or point the way to something clean and efficient.

Looking at methyltriethylammomium bis((trifluoromethyl)sulfonyl)imide, I don’t just read hazard statements—I watch for what it does in real glassware. In most organic solvents, especially ones without much hydrogen bonding, this salt doesn’t fall apart or do anything crazy, which lets you build up electrochemical systems that need a strong, non-coordinating ionic medium. I've seen electrochemical cells with ILs like this survive long runs without corroding, foaming, or jamming up valves, something that isn’t common if you pick the wrong partners.

A story from last semester: one grad student at our bench tried it with strong reducing agents in a makeshift glovebox. No explosion, but the mix looked like chocolate milk after a few hours. Turns out, under strong nucleophilic conditions, that fancy anion can start to decompose. Write down any changes in color or viscosity, because some failures teach more chemistry than any success.

Reacting with the Usual Suspects: Acids, Bases, and Water

With this salt, acids and weak bases rarely start anything dramatic, but strong bases might chop off pieces of the anion after some time. Bases that aren’t afraid of dropping the pH far below 7 can cause slow degradation, which explains the brown goop you sometimes find after an overnight reaction. Mixing with water mostly leaves things fine at first. In the long term, though, you might see hydrolysis—especially if your humidity hovers near tropical—thanks to the highly fluorinated anion. Keeping caps tight and adding some desiccant in the storage bin can buy peace of mind.

I learned fast to check for incompatibilities the old-fashioned way: small-volume tests, done behind a splash shield. No matter what the spec sheet promises, not every lot of starting material comes as pure as you want. Impurities in either the IL or a partner reagent can kick off unpredictable chemistry.

Factoring in Scale-Up and Waste

Labs that scale up these ionic liquids to multi-gram batches already know they need proper disposal plans. Those fluorinated anions don’t just vanish down the drain, and they tend to resist many standard waste treatment steps. Disposal usually means treating the whole mix as hazardous, since burning it could release nasty fluorinated gases. The solvent you pick for extractions or washes with this salt adds another layer of compatibility problems, so it pays to pick a routine that gives both high yield and a minimal disposal headache.

Getting Safer and Smarter in the Future

Compatibility isn’t only about “does it explode or not.” It’s about handling, mixing, storing, and cleaning up. Sharing bench notes with colleagues, paying attention to near-misses, and checking updated chemical safety data shortens the learning curve. Sometimes the only fix for an annoying incompatibility is to swap out the reagent for a newer, less want-to-be-dangerous cousin—chemists find new ionic liquids all the time. Methyltriethylammomium bis((trifluoromethyl)sulfonyl)imide plays well in many systems, but it never hurts to give new combos a cautious, respectful test before signing off on routine use.

Methyltriethylammomium Bis((Trifluoromethyl)Sulfonyl)Imide