Material Safety Data Sheet: Methyltriethylammonium Bis((Trifluoromethyl)Sulfonyl)Imide

Identification

Product Name: Methyltriethylammonium Bis((Trifluoromethyl)Sulfonyl)Imide
Synonyms: [N-ethyl-N,N,N-trimethylethanaminium bis(trifluoromethanesulfonyl)imide]
CAS Number: 174899-83-3
Recommended Use: Electrolyte in high-performance batteries, specialty solvent applications
Manufacturer/Supplier: Contact chemical provider directly for current information
Emergency Phone Number: Available on the supplier’s official website or Section 1 of the paper MSDS

Hazard Identification

Classification: Acute oral toxicity, Skin and eye irritation, Specific target organ toxicity
GHS Label Elements: Harmful if swallowed; Causes mild to moderate skin irritation; Causes eye irritation
Hazard Statements: Can irritate eyes, skin, respiratory tract; May damage organ function if ingested
Precautionary Statements: Avoid skin/eye contact, avoid breathing dust or vapor; Wash hands after use
Routes of Exposure: Inhalation, ingestion, skin or eye contact

Composition / Information on Ingredients

Chemical Name: Methyltriethylammonium Bis((Trifluoromethyl)Sulfonyl)Imide
Concentration: 100% (pure form)
Chemical Formula: C10H20F6N2O4S2
Impurities or Stabilizing Additives: Not reported in standard analytical grades

First Aid Measures

Eye Contact: Flush cautiously with water for 15 minutes; seek medical attention if irritation persists
Skin Contact: Remove contaminated clothing; wash skin with soap and water; consult physician for persistent irritation
Inhalation: Move person to fresh air; keep at rest; seek medical advice if symptoms continue
Ingestion: Rinse mouth, do not induce vomiting, get medical help right away
Symptoms: Redness, burning, stinging sensations, respiratory distress in severe cases

Fire-Fighting Measures

Suitable Extinguishing Media: Dry chemical, foam, CO₂, water spray used for small fires
Unsuitable Extinguishing Media: Direct water stream may spread chemical
Fire Hazards: Product can emit hazardous fumes (nitrogen oxides, sulfur oxides, fluorine compounds, carbon oxides)
Protective Equipment: Firefighters need self-contained breathing apparatus, full chemical protection clothing
Special Procedures: Cool unaffected containers with water spray, keep safe distance, avoid inhaling fumes

Accidental Release Measures

Personal Precautions: Use personal protective equipment (gloves, safety goggles, lab coat, mask); avoid contact with skin and eyes
Environmental Precautions: Prevent further leakage or spillage if safe; avoid entering drains, surface water and soil
Cleanup Methods: Absorb with inert material (sand or vermiculite), scoop to labeled chemical waste container, ventilate area well
Spill Response: Report large spills to emergency services, seal area, ventilate and dispose of cleanup materials safely

Handling and Storage

Handling: Handle inside chemical fume hood or well-ventilated area; wear protective equipment; minimize aerosol and dust formation
Storage: Store in tightly sealed original container in cool, dry environment, away from moisture, oxidizing materials and sources of ignition
Incompatible Materials: Avoid contact with strong oxidizers, water, acids, and bases which may cause dangerous reactions
Other Recommendations: Ensure containers are clearly labeled; regular inspection for leaks or corrosion can reduce risks

Exposure Controls and Personal Protection

Engineering Controls: Use with local exhaust ventilation, chemical fume hood, eye wash station, and safety shower
Respiratory Protection: Approved air-purifying respirator when ventilation is not sufficient
Hand Protection: Chemical-resistant gloves (nitrile or neoprene recommended)
Eye Protection: Splash-proof safety goggles or face shield
Skin Protection: Flame-retardant laboratory coat, long sleeves, enclosed shoes
Hygiene Measures: Do not eat, drink, or smoke while handling; wash hands and face thoroughly after working; remove contaminated clothing immediately

Physical and Chemical Properties

Appearance: Colorless to pale yellow liquid or crystalline solid (depends on temperature)
Odor: Faint, chemical
Melting Point: Ranges between 13°C and 18°C
Boiling Point: Decomposes before boiling
Flash Point: >200°C
Solubility: Soluble in water, methanol, acetonitrile, and other polar solvents
Density: 1.36 – 1.41 g/cm³ at 20°C
Vapor Pressure: Negligible at room temperature
pH: Neutral to slightly acidic in water

Stability and Reactivity

Reactivity: Stable under recommended handling and storage conditions; slow hydrolysis in moist air
Chemical Stability: Stable at ambient temperature; avoid moisture, strong acids and bases for best shelf life
Hazardous Reactions: Risk of violent reaction with strong oxidizers
Decomposition: Heat or fire causes release of toxic gases such as SOx, HF, and NOx
Incompatible Materials: Strong acids, strong bases, oxidizing agents

Toxicological Information

Acute Toxicity: Oral and dermal toxicity data limited, generally considered low to moderate hazard; may be harmful by ingestion
Skin Irritation: Causes irritation; repeated exposure increases risk of dermatitis
Eye Irritation: Causes eye irritation, temporary redness, tearing, blurred vision
Sensitization: No available data for respiratory or skin sensitization
Chronic Toxicity: Long-term effects unknown; avoid repeated or prolonged exposure
Carcinogenicity, Mutagenicity, Reproductive Toxicity: No current evidence or regulatory listing as carcinogen or mutagen, reproductive toxicity data limited or unavailable

Ecological Information

Aquatic Toxicity: Toxic to aquatic organisms at higher concentrations; may cause long-term adverse effects in the aquatic environment
Degradability: Low biodegradability expected, persistent in soil and water
Bioaccumulative Potential: Significant potential for bioconcentration not established
Mobility in Soil: Moderately mobile, risk of groundwater contamination after widespread spill
Other Adverse Effects: Fluorinated compounds can persist and accumulate, causing ecosystem concerns

Disposal Considerations

Waste Disposal Methods: Dispose of contents/container at hazardous waste collection facility; incinerate only under controlled, permitted conditions
Container Disposal: Triple rinse empty containers before recycling or discarding; follow local, state, and national laws
Additional Information: Do not pour down drain; avoid release to environment

Transport Information

UN Number: Specific UN number not consistently assigned; confirm with logistics provider
Proper Shipping Name: Chemical name used as proper shipping name
Hazard Class: Not classified as dangerous good for transport by most international authorities, but verify with supplier
Packing Group: Packing group not typically assigned
Transport Precautions: Keep containers upright, secure in transit, do not ship with incompatible materials, avoid temperature extremes

Regulatory Information

Safety, Health and Environmental Regulations: Product not specifically listed by OSHA, TSCA, SARA, REACH, or other major regulatory frameworks; check local chemical regulations
Labeling Requirements: Follow GHS labeling for workplace safety
Inventory Status: Not widely registered on all national chemical inventories; importer or user may need to confirm registered status
Reporting Requirements: May require reporting if large quantities are released or disposed
Other Regulatory Notes: Review regional and national guidelines to ensure compliance