Chemical Name: N-Butyl-N-Methyl-Piperidinium Hexafluorophosphate
Synonyms: BMPyPF6, 1-butyl-1-methylpiperidinium hexafluorophosphate
Molecular Formula: C10H22NPF6
Manufacturer: Information supplied by responsible chemical vendor/distributor
Recommended Use: Electrolyte in research labs, ionic liquids applications, advanced battery technologies
Emergency Number: Local poison control, medical facility, or chemical safety expert
GHS Classification: Skin irritant (Category 2), Eye irritant (Category 2A), Specific target organ toxicity, acute (Category 3)
Signal Word: Warning
Hazard Statements: Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Pictograms: Exclamation mark
Precautionary Statements: Wear protective gloves/eye protection. Avoid breathing vapors/mist. Wash hands thoroughly after handling. Use only outdoors or in a well-ventilated area.
Potential Health Effects: Skin redness, eye watering or burning, coughing, possible headache or dizziness if inhaled in significant amounts
Chemical: N-Butyl-N-Methyl-Piperidinium Hexafluorophosphate
Concentration: > 98% (typical purity in laboratory settings)
CAS Number: 622129-54-8
Impurities: Trace moisture, residual solvents as per manufacturer specification, no substances classified as hazardous above relevant thresholds
Inhalation: Move person to fresh air; keep comfortable for breathing. Medical attention if symptoms persist.
Skin Contact: Remove contaminated clothing, rinse skin with plenty of water and soap. Seek attention if irritation or redness develops.
Eye Contact: Flush gently with water for at least 15 minutes, lifting eyelids. Remove contact lenses if present and easy. Call for assistance if irritation continues.
Ingestion: Rinse mouth. Never induce vomiting. Get medical help right away. Flush mouth with water if conscious.
Most Important Symptoms: Redness, irritation, coughing, watering eyes
Note to Physicians: Symptomatic treatment; no specific antidote known
Suitable Extinguishing Media: Dry chemical, CO2, foam, water spray. No direct water jet on burning chemical.
Fire Hazards: Emits toxic or corrosive fumes under combustion, especially hydrogen fluoride and phosphorus oxides
Protective Equipment: Self-contained breathing apparatus, full protective gear; avoid inhalation of gases produced in fires
Specific Hazards: Decomposition releases irritating, corrosive and toxic gases. Containers can burst at high temperature.
Firefighting Instructions: Keep unaffected containers cool, control runoff, prevent release to drains
Personal Precautions: Use gloves, goggles, and suitable face protection. Ventilate area. Avoid breathing vapor and contact with skin.
Environmental Precautions: Prevent material from entering drains or waterways. Notify regulatory authorities if spill pollutes environment.
Cleanup Methods: Small spills: absorb with inert material like vermiculite, sand, or earth. Transfer to chemical waste container. Clean contaminated surface with detergent and plenty of water.
Emergency Procedures: Restrict access. Use non-sparking tools. Dispose according to local, state, and federal regulations
Handling: Minimize direct contact. Prevent vapor buildup. Use with adequate ventilation or in fume hood. Avoid splashing.
Storage: Store tightly closed in a cool, dry, well-ventilated place away from acids, bases, moisture, and direct sunlight. Use corrosion-proof containers.
Keep Away From: Strong oxidizers, acids, bases, strong reducing agents, sources of ignition.
Other Precautions: Ensure containers remain labeled. Only trained personnel use product. Maintain good hygiene – no food or drink near chemicals.
Engineering Controls: Laboratory fume hood or local exhaust ventilation. Use closed systems for larger uses.
Exposure Limits: Not established specifically for this ionic liquid, default to employer guidelines and best practice for unlisted compounds.
Personal Protection: Chemical-resistant gloves (nitrile, neoprene), goggles or full-face shield, lab coat, long sleeves. For significant airborne levels, respiratory protection (filter mask).
Environmental Exposure: Use spill containment if handling large amounts. Minimize release to environment.
Physical State: Liquid
Color: Clear to pale yellow
Odor: Slight, ammoniacal or sweet
Melting Point: Varies, typically below 25°C
Boiling Point: Decomposes before boiling
Flash Point: Not easily flammable, but combustible properties apply
Density: Approximately 1.15–1.18 g/cm3 at 20°C
Solubility: Slightly soluble in water, miscible with many polar organic solvents
Vapor Pressure: Negligible at ambient temperatures
pH: Not applicable (non-aqueous)
Partition Coefficient: Not available
Decomposition Temperature: >200°C, with toxic products
Chemical Stability: Stable under normal storage and handling conditions, but hydrolyzes in presence of strong moisture
Reactivity: Reacts with strong acids, bases, and oxidizers
Hazardous Reactions: Decomposes at high temperature — produces HF, PF5, and other hazardous fluorine compounds
Incompatible Materials: Water, moisture, oxidizing agents, strong bases and acids
Decomposition Products: Fluorine-containing gases, phosphorus oxides, carbon oxides
Other Reactivity Notes: Prolonged exposure to light or heat increases decompositional risk
Acute Toxicity: Not fully characterized, but data show low to moderate toxicity by dermal and inhalation exposure
Skin Corrosion/Irritation: Causes irritation after direct contact, redness and possible blistering with prolonged exposure
Serious Eye Damage/Irritation: Causes burning, watering, redness
Respiratory Sensitization: Vapors and aerosols can irritate mucous membranes and lungs
Chronic Effects: No established chronic toxicity data; avoid repeated exposures
Carcinogenicity: Not listed by major agencies as known or suspected carcinogen
Mutagenicity and Teratogenicity: No reliable data available, handle as potentially hazardous
Route of Exposure: May enter body through skin, eyes, inhalation, or, rarely, ingestion
Ecotoxicity: Not fully tested; ionic liquids can be harmful to aquatic environments. Avoid uncontrolled release.
Persistence and Degradability: Likely persistent in soil and water; difficult to biodegrade
Bioaccumulative Potential: No established bioaccumulation data
Mobility in Soil: Ionic, may travel through soils if released
Other Adverse Effects: Toxic decomposition products released if incinerated or in fire
Special Notes: Always prevent discharge into drains and water sources
Waste Disposal Methods: Collect unused product and contaminated spill debris in sealed containers for hazardous waste disposal. Use approved facilities.
Contaminated Packaging: Rinse thoroughly; dispose as hazardous waste.
Regulatory Compliance: Observe all state and local environmental regulations on chemical disposal. Specialist disposal agencies handle this class of substance.
Other Recommendations: Do not dump into surface water, soil, or regular trash. Consult environmental agency for region-specific guidelines.
UN Number: Not assigned specifically; may be shipped as a non-regulated liquid depending on purity and amount. Always check local transport requirements.
Transport Hazard Class: Not classified by most international regulations, but packaging should prevent leakage.
Proper Shipping Name: Chemical, N.O.S. (N-Butyl-N-Methyl-Piperidinium Hexafluorophosphate)
Packing Group: Not assigned
Special Transport Notes: Use chemical-resistant secondary containment. Emergency response guide available from supplier.
OSHA: Not specifically regulated, default to general chemical safety regulations
TSCA Status: Not listed or restricted
SARA/EPCRA: Not designated as extremely hazardous
REACH Status (EU): May require notification and registration for handling in Europe
Other Listings: Not subject to routine occupational exposure monitoring. Refer to supplier SDS and notify safety officials before large-scale use or importation
Labeling Requirements: Ensure GHS-compliant hazard labeling; provide access to SDS for all users.
