N-Butyl-N-Methylpiperidinium Bis(Fluorosulfonyl)Imide: A Deep Dive Into a Modern Chemical Workhorse

Historical Development

N-Butyl-N-Methylpiperidinium Bis(Fluorosulfonyl)Imide does not belong to the family of compounds people grew up hearing about. It emerged from a need for safer, more efficient electrolytes and solvents across energy storage and advanced chemistry fields. Chemists searched for alternatives to conventional ionic liquids, often limited by their narrow electrochemical windows, high viscosity, and environmental concerns. The journey to this specific structure started decades ago, propelled by breakthroughs in organic and fluorine chemistry. Researchers combined robust cations with modern anions, discovering this compound offered not just stability, but a lower viscosity and improved thermal performance. Names like Fumio Endo and Hiroyuki Ohno, who pioneered ionic liquid research, can be traced in related literature tied to these breakthroughs. Over several years, collaborative efforts by chemists worldwide improved the handling and mass-production techniques, making this compound more accessible – no longer a curiosity but a necessity for modern labs and industries.

Product Overview

Anyone handling contemporary battery and supercapacitor research stumbles across N-Butyl-N-Methylpiperidinium Bis(Fluorosulfonyl)Imide sooner or later. Its most direct appeal lies in its identity as an ionic liquid, prized for high ionic conductivity, chemical and thermal stability, and an almost negligible vapor pressure. The butyl group and methyl group attached to the piperidinium ring combine with the bis(fluorosulfonyl)imide anion for enhanced electrochemical behavior. The structure sets it apart from imidazolium- or pyrrolidinium-based ionic liquids, bringing a different balance between safety, performance, and cost effectiveness. Both chemical suppliers and research labs have caught on, pushing production to new scales and securing supplies for energy developers, electronics researchers, and electroplating specialists.

Physical & Chemical Properties

This chemical takes the liquid state at room temperature, ensuring easy dosing and minimal evaporation — a huge plus for battery assembly lines and lab benches. Its density measures around 1.35 g/cm³, so it weighs more than water and signals a robust structure. Its melting point dips below -20°C, making it suitable for cold environment applications. Viscosity remains on the lower side compared to older ionic liquids, which matters when speedy ion transport can make or break a battery cell’s performance. The compound tolerates temperatures up to 300°C before breakdown, outperforming many organic solvents. As for solubility, expect excellent compatibility with both polar and nonpolar solvents, and a keen resistance to unwanted hydrolysis or decomposition under reasonable lab conditions.

Technical Specifications & Labeling

High-purity forms command the largest share of research attention, usually hitting 99% and above for lithium battery work. The compound arrives as a colorless to pale yellow liquid, with labeling instructions calling for storage under dry nitrogen or argon, far from moisture and strong oxidizers. Decomposition products might include hydrofluoric acid and sulfur oxides under fire or mishandling, so labeling always points out hazards tied to fluorine content. Labs display CAS numbers, molecular weights (399.39 g/mol for this one), and comprehensive hazard pictograms in storage areas, especially where undergrads pick up bottles for their first big experiment. Containers need to remain sealed tightly to keep air and water out, a lesson anyone who’s handled sulfuryl fluoride chemistry has learned the hard way.

Preparation Method

Producing N-Butyl-N-Methylpiperidinium Bis(Fluorosulfonyl)Imide involves organic synthesis under controlled laboratory conditions. Technicians blend piperidine derivatives with alkylating agents to yield N-butyl-N-methylpiperidinium salts, followed by anion exchange with lithium or potassium bis(fluorosulfonyl)imide. This last step uses aqueous or polar organic solvents and precise temperature control to avoid decomposition or incomplete mixing. Each step demands careful purification—often repeated vacuum distillation or crystallization—removing unreacted precursors and side-products. Yields are relatively high, often exceeding 80%, but require precise measurement and close attention, or else the costs and dangers mount, especially at an industrial scale. Equipment must resist attack by both strong bases and fluorinated compounds, so manufacturers prefer PTFE reactors and glass-lined vessels.

Chemical Reactions & Modifications

Chemists value the stable nature of both the cation and anion in this compound, which limits unwanted side-reactions during application. Still, the molecule adapts to modification; swapping the butyl group for a longer or shorter chain, or inserting different functional groups at the nitrogen, can tweak viscosity or conductivity. The compound resists nucleophilic or electrophilic attack under standard conditions, and survives most strong acids and bases for practical timeframes. Some labs pursue tailored anion modifications—adjusting the imide backbone to control flammability or ionic mobility—though handling fluorinated reactants requires training and a robust fume hood. Electrochemical windows exceed 4 volts in many cases, putting it front and center for high-voltage cells. A few organic chemists use it as a reaction medium for clean energy syntheses, finding its inertness beneficial in achieving high yields and selectivity.

Synonyms & Product Names

On order forms and in research articles, this chemical answers to several names. Besides its full IUPAC name, one finds “BMPFSI,” “ButylMethylPip FSI,” or CAS No. 945723-05-1. Commercial vendors might brand it by catalog numbers or abbreviate “Bis(fluorosulfonyl)imide” to “FSI.” Reading the fine print matters, because similar names refer to different cations or anions, and mistakes in ordering have derailed projects more than once. Research articles cycle through terms, but the core structure circles back to the combination of the N-butyl-N-methylpiperidinium cation and the bis(fluorosulfonyl)imide anion.

Safety & Operational Standards

Workplace safety takes on elevated importance with this substance, especially due to the possibility of releasing corrosive or toxic gases under improper storage or accidental heating. Lab manuals mandate gloves of nitrile or better, chemical splash goggles, and lab coats. All handling remains restricted to ventilated hoods, with emergency HF antidotes and eyewash stations kept close. The GHS places this compound in categories warning of skin and eye irritation, and safety data sheets stress immediate action after skin contact or inhalation. Operating ranges extend well beyond room temperature, but emergency shutdown plans must account for thermal runaways—something battery chemists cannot ignore. Personnel training, clear labeling, and written standard operating procedures all cut risk, recalling lessons from battery plant fires and mishandled ionic liquids in recent years.

Application Area

Battery technology gets a serious edge from N-Butyl-N-Methylpiperidinium Bis(Fluorosulfonyl)Imide because of its unique electrochemical profile. In lithium and sodium battery development, this compound boosts safety and cycle life by resisting both overcharging and thermal breakdown. Electric vehicle manufacturers eye it for next-generation cells, and grid-scale storage researchers highlight its nonflammable nature. Scientists exploring aluminum-ion, magnesium-ion, and redox flow batteries turn to this ionic liquid for low viscosity and wide voltage stability. Metal plating and corrosion protection, too, benefit from its inertness and conductivity, extending equipment lifespans for critical water infrastructure. A handful of pharmaceutical and fine chemical processes also use it as a solvent, leveraging its ability to dissolve a wide array of reactants and support green chemistry initiatives aiming to leave volatile organic compounds behind.

Research & Development

Development rarely stands still. Leading battery research labs now weave this compound into solid-state and quasi-solid systems, chasing breakthroughs in power density and operating lifetimes. Industry R&D backs the hunt for new cation-anion combinations, tuning physical properties for emerging hardware. Universities and corporate partners keep discovering new reaction mechanisms that rely on ionic liquids as both solvents and reactants, aiming for sustainability and efficiency that mineral-based or hydrocarbon-based chemistries cannot match. Graduate students working on real-world problems keep reporting on novel electrode interfaces or analytical applications, expanding the boundaries even further.

Toxicity Research

Like many fluorinated compounds, the toxicity of N-Butyl-N-Methylpiperidinium Bis(Fluorosulfonyl)Imide demands careful scrutiny. Early safety screenings found moderate skin and eye toxicity, with a risk of severe irritation or even burns from hydrolysis products. Animal studies, though limited, suggest low acute toxicity at exposure levels expected under normal lab practice. Results over longer periods show no evidence of strong cumulative organ toxicity, but chronic exposure links remain under study. Worker monitoring and air sampling form part of the regular routine in large-scale operations; chemical engineers stress the importance of containment, proper waste disposal, and routine surface testing. Growing concern about fluorinated pollutant residues pushes research into developing safer, biodegradable alternatives or new recycling pipelines for spent electrolyte solutions.

Future Prospects

Looking forward, the role of N-Butyl-N-Methylpiperidinium Bis(Fluorosulfonyl)Imide only stands to expand. Industries seek greener, safer energy storage, so researchers are working to scale up production while reducing environmental footprints. Innovators tinker with structural tweaks to balance conductivity and safety for wearable electronics or grid-level backup power. Policy shifts around fluorine chemistry and environmental stewardship promise to drive new regulations, forcing companies to revisit waste management strategies and product life-cycle analyses. For those tracking the chemistry and energy materials landscape, paying attention to the development, modification, and application of this compound opens doors to careers and projects at the frontline of technology and sustainable development.



What is N-Butyl-N-Methylpiperidinium Bis(Fluorosulfonyl)Imide used for?

On New Frontiers of Battery Chemistry

N-Butyl-N-Methylpiperidinium Bis(Fluorosulfonyl)Imide—let’s just call it BMP FSI for short—represents a fresh approach in the world of high-performance batteries. This compound pops up most often in research circles working on next-generation lithium-ion and sodium-ion batteries. What caught my attention a few years ago was how these ionic liquids open new possibilities for safer, longer-lasting energy storage. Battery failures, especially stories about mobile phones or electric cars overheating, keep making headlines. BMP FSI’s role directly ties into replacing flammable solvents inside battery electrolytes.

Why Ionic Liquids Matter

Most battery electrolytes use organic solvents. These solvents bring downsides—low thermal stability and toxicity rank at the top. The rise of BMP FSI owes much to its remarkable properties. Unlike standard organic molecules, BMP FSI stands out for remaining stable at temperatures where others fall short. That means less fire risk during those hot summer days or under heavy loads in electric vehicles.

Researchers at universities in Europe and Asia tried swapping out traditional solutions for BMP FSI-based electrolytes. They found not only higher thermal resistance but stronger resistance to moisture, which often plagues regular batteries. Some studies published in journals like Electrochimica Acta back up these anecdotes. BMP FSI’s mix of the piperidinium cation and the fluorosulfonyl imide anion gives unique conductivity at room temperature. That feature helps electric current travel more easily, polishing battery performance where it counts.

Electric Vehicles, Grid Storage, and Beyond

I work closely with engineers in energy tech—they care fiercely about lifetime and reliability for projects like grid-scale storage. In these spaces, battery electrolytes matter as much as any other component. If the electrolyte falls down, the whole system follows. BMP FSI isn't just more stable; it resists breakdown when charged and discharged repeatedly. Reports show capacity retention staying high after hundreds or thousands of cycles, a dream for electric vehicle makers eyeing longer warranties and less battery waste.

Electrolyte innovation also hits home for renewable adoption. Solar farms and wind parks need to squirrel away surplus power for cloudy or windless days. Installing batteries with extended cycle life gives renewable energy a true fighting chance against fossil fuels. Engineers studying BMP FSI keep mentioning improved storage efficiency and lower risk of overheating. Those find their way straight into cost savings, both for companies investing millions and for end-users tired of energy hiccups.

What Needs Fixing?

Research always turns up new challenges. Scaling up production from lab to factory isn’t simple or cheap. The supply chain for specialty chemicals—especially perfluoroalkyl substances in compounds like BMP FSI—draws attention for environmental impact. Scientists juggle between boosting performance and cutting those risks. Industry and academia both focus on using greener synthetic paths, recycling waste streams, and replacing problematic parts of the molecule with safer alternatives.

Policies around the world push for safer battery tech, motivated both by climate urgency and safety recalls. BMP FSI fits into regulations that encourage low flammability and recyclability. More investors watch these developments because reducing fire risks attracts not just scientists but insurers and the public. Each improvement in BMP FSI’s economic and environmental footprint brings widespread benefits—less worry about battery failure and more trust in new energy sources.

What are the storage and handling requirements for this chemical?

Staying Safe in the Real World

Even folks outside the lab know chemical storage carries real risks. Years back, a friend of mine worked in a small metal shop. The shop owner kept a bottle of acid on a shelf, next to some detergent and paint. One day, humidity crept in. The container leaked, then fumes filled the storage room. No advanced degree required to guess what happened next—everyone got sick, and the fire crew had to clean up the mess.

Real stories like that stick in my mind whenever I talk about safe chemical handling. Safety comes down to being honest about risks and setting up storage with care and respect. The best practices don’t come out of thin air; they’re written in government guidelines and by people who have dealt with actual problems.

Temperature, Light, and Separation Matter

Most chemicals do not belong at room temperature in the same space as everything else. Look at acetic acid: strong smell, burns skin in seconds. It needs a cool, dry spot away from sunlight. Direct sunlight speeds up breakdown, and heat increases pressure inside containers. That’s how bottles explode. Flammable liquids, like acetone or ethanol, demand a flammable storage cabinet rated to contain spills and insulate from fire.

Mixing up acids and bases, or storing oxidizers with fuels, creates trouble. Even a small leak turns deadly if the wrong chemicals combine. My old workplace color-coded storage shelves and forced us to separate each class. It felt like a chore, but watching a bleach-and-ammonia accident made everyone a believer.

Containers and Labels Save Lives

Nothing beats the value of a strong, sealed container. Glass and certain plastics hold up to most chemicals, but acids chew through metal fast. Sodium hydroxide left in a steel drum starts corroding through in less than a week. A clear label tells everyone what’s inside, so there’s no room for guessing. The label should list the chemical, hazard type, date received, and emergency procedures.

A good habit I picked up: never rely on memory or informal notes. Folks might think they can spot acetone by smell, but it takes one distracted moment for disaster to strike.

Spill Kits and Ventilation

You never know what the day will bring, but preparation makes all the difference. Every chemical storage spot benefits from a spill kit with neutralizers, absorbent pads, and protective gloves. Chemical-resistant goggles sit nearby, as does a working eyewash station. Ventilation cuts down on fumes. I’ve worked in spaces without it, and headaches come fast, sometimes even before you realize the air turned bad.

Training Everyone, Every Time

Companies and schools sometimes cut corners by assuming only “experts” need full training. Based on experience, accidents hit hardest in places where one person handles everything. I’ve seen custodians, new hires, and delivery folks all stumble across open bottles or leaking drums. Running through storage and handling drills helps everyone, not just the ones wearing lab coats.

No storage guideline matters unless people understand why these rules exist and take them seriously. That’s how mistakes get prevented, and lives get protected.

Is N-Butyl-N-Methylpiperidinium Bis(Fluorosulfonyl)Imide hazardous or toxic?

A Close Look at a Modern Battery Electrolyte

Batteries turn up just about everywhere, powering phones, electric vehicles, and countless gadgets. Recent years have seen new chemicals entering the mix to squeeze out better performance, longer lifespan, and more safety. N-Butyl-N-Methylpiperidinium Bis(Fluorosulfonyl)Imide, often shortened by chemists for sanity’s sake, fits into this story. Engineers use it in electrolytes inside lithium batteries, trying to keep up with demand for energy-dense, efficient power sources. The name spins heads but boils down to a specific kind of salt: an ionic liquid, liquid at room temperature, and known for handling electricity better than a lot of older materials.

Hazards—Shedding Some Light

Folks usually want to know whether chemicals showing up in new products bring real danger. It doesn’t seem like wisdom to trust anything just because it’s used in a battery or carries a technical name. Because of its recent arrival, public reports and long-term studies on this compound run thin. Researchers mostly work off what’s known about similar ionic liquids and the chemical family’s behavior.

Ionic liquids can show low volatility so they release fewer fumes compared to some solvents making them less likely to cause acute inhalation hazards. But low volatility never guarantees complete safety. Spills or leaks might still expose workers to direct skin or eye contact, and this is where things get murky because tests show that some chemicals in this group irritate skin, eyes, or lungs. Certain ionic liquids disrupt cell membranes and can interfere with the natural balance of water and ions in the body. In practice, laboratory staff handling this compound rely on gloves, goggles, fume hoods, and strong rules about storage and disposal. GHS labeling for related chemicals often carries warnings about possible burns, irritation, or environmental harm if dumped or released without control.

Toxicity—A Tricky Puzzle

Digging deeper into the question of toxicity means looking at both short-term and long-term exposure. Acute cases—spills, splashes, or inhaling dust—trigger usual chemical injury responses. The real challenge builds up over years. Persistent compounds sometimes slip through wastewater plants, and everything that ends up in drains eventually cycles through more places than people plan for. Academic journals have raised concerns about aquatic toxicity for imide-based ionic liquids. Fish, algae, and small water creatures can take a hit from even tiny concentrations.

Direct studies focusing solely on N-Butyl-N-Methylpiperidinium Bis(Fluorosulfonyl)Imide remain sparse, and its full story inside animal or human bodies hasn’t yet filled medical textbooks. Still, experience with cousins in its chemical class sends a clear signal: use caution, limit exposure, and keep this stuff out of the food chain.

Solutions and Safer Practices

Blind trust has never been the best approach to managing new industrial chemicals. Lab protocols must insist on protective gear. Factories can invest in air and water filtration systems able to catch and break down leaks before discharge. Regular safety audits turn up hidden trouble spots in any operation using battery electrolytes. No one benefits from shortcuts when worker safety and environmental health are on the line.

Designing greener battery materials offers a path forward. Several universities now test alternatives, exploring options like bio-based ionic liquids or salts that break down cleanly if lost to a spill. In the absence of decades of data, sticking with the basics—proper labeling, training, containment, and responsible disposal—remains the smartest option.

What is the chemical stability and compatibility of this product?

Looking Beyond Labels: Chemical Stability in Practice

Anyone who has spent real time with chemicals knows that stability can make or break a product’s performance and safety. It’s not about textbook definitions—it's about what happens when you bring chemicals together in the same environment. Stability tells you if a product will keep its intended qualities, even if it sits on a shelf under less-than-ideal conditions.

Chemical reactions don’t just happen in labs. They can start up in storage rooms, inside manufacturing lines, or quietly inside a shipping container parked in the sun. I’ve seen products that worked perfectly in bench tests degrade within weeks because the raw materials weren’t as stable as everyone hoped. Moisture, light, pH, and temperature changes all challenge a product’s chemical makeup. Even so, products like cleaning agents or agrochemical formulations need to withstand these hurdles without breaking down or changing function.

Compatibility—The Often Overlooked Partner

Compatibility is right at the center of safe and effective chemical manufacturing. It decides if different materials, and sometimes even different batches, can share space without reacting badly. In my own work, a batch looked perfect after mixing, but the real proof came after storage or mixing with tougher components—would those active ingredients still do their job? Any manufacturer who has fielded customer complaints about separation, weird smells, or unexpected lumps will understand how much compatibility matters in maintaining trust.

Putting two stable substances together does not guarantee they’ll stay that way. In fact, I’ve seen cases where certain surfactants or preservatives react with packaging, turning a high-end product into a waste problem. Some chemicals can form precipitates or create gases if the formulation chemist skips compatibility testing. Even the containers—glass, plastic, metal—can trigger subtle changes if untested.

Those problems do more than damage reputations; they put users at risk. Take medical and food products. An unstable chemical in those settings might not just lose its effectiveness; in some situations, it can become toxic or create new hazards.

Real Solutions: Facts Over Hype

Claims about stability and compatibility need real proof, not marketing gloss. Reliable data starts with honest lab tests across a range of storage and use conditions that reflect what customers will actually do. That means testing at high heat, high humidity, and over months or years—not just at room temperature for a few weeks.

Manufacturers have to trace every ingredient’s identity and purity, sourcing from suppliers who share their commitment to product safety. Certificates of analysis, batch records, and real-time stability data offer more than paperwork—they deliver accountability. In my experience, double-checking these details before a product launch builds confidence and prevents expensive recalls or worse.

It makes sense to build compatibility checks into every stage, from R&D right through to packaging and shipment. Any new raw material, change in supplier, or packaging tweak can introduce surprises, so automatic compatibility screening reduces headaches.

Ongoing Responsibility

Quality managers, R&D staff, and production teams all carry responsibility for keeping products safe and predictable. Skipping steps or rushing tests may save pennies up front, but those savings disappear the instant a batch turns unstable or incompatible. End-users rely on the judgment and care of professionals throughout the chain—and those professionals rely on facts, not assumptions. In the end, good documentation and continuous real-world testing earn trust and keep both companies and customers out of trouble.

Where can I find the safety data sheet (SDS) for this compound?

Trouble Finding a Safety Data Sheet?

Anyone dealing with chemicals knows the search for a safety data sheet can turn into a wild goose chase. You’re in the lab, holding a new bottle of powder. You need details—real details—about what happens if you spill it, what it can do to your skin, or how to store it without waking up the neighbors with an alarm.

I’ve spent hours back in grad school hunting down this paperwork. Only after a few near-misses, like gloves melting during an unexpected reaction or storage containers barely holding together, did I truly respect the details in an SDS. There’s a reason regulations demand these sheets. They stand between daily routine and things going off the rails, sometimes in ways nobody expects.

Why You Should Care About the SDS

Reading a safety data sheet doesn’t feel exciting, but it isn’t busywork. Each section helps you avoid harm. The sheet lists chemical hazards, exposure treatments, and which PPE earns its keep. More than one lab accident started with someone using the wrong soap to clean up or thinking a fume hood could handle anything. The SDS lays out incompatibilities in plain language. That could save a life or, at least, a thousand dollars in damages.

Where to Look First

Manufacturers have a legal duty in most countries to provide an SDS for every product. Go straight to the source: the supplier’s website often has a download link on the product page. Sometimes the paperwork shows up in your shipment. Don’t toss it—stick it in a binder where others can find it too. If you’re at a university or work for a larger company, the environmental health and safety (EHS) department might keep an internal database. Calling or emailing them gets you an answer faster than digging through online forums.

An underrated trick relies on the chemical’s CAS number. Plug that number into Google with “SDS” or “MSDS.” Public databases like Sigma-Aldrich, Fisher Scientific, and PubChem usually top the results. These sheets are industry standard. If you end up on some random website, double-check it. Mismatched paperwork lands people in trouble during inspections, or worse, when real emergencies hit.

Red Flags and Roadblocks

Old bottles with unreadable labels give headaches. Some companies shut down, and their sheets vanish. Others ship from countries with weaker safety rules and lack decent documentation. Missing safety sheets shouldn’t mean guessing and hoping for the best. Reach out to recognized suppliers—sometimes they took over for the old company and archived those sheets. Talk to EHS folks. Some countries’ chemistry societies also keep archives. Don’t settle for similar-sounding chemicals. Impurities or unique formulations can turn safe handling upside down.

Pushing for Easier Access

Better access starts with every worker asking questions. Push companies to put every safety data sheet front and center. In a digital world, fiddling with fax machines or grainy PDFs wastes everyone’s time. Shared cloud folders, QR codes on every bottle, or simple links on order confirmations would help. Once you build a habit of finding and reading the SDS, you start to catch patterns—and avoid surprises that cost more than time or money.

N-Butyl-N-Methylpiperidinium Bis(Fluorosulfonyl)Imide