MSDS for N-Decyl-N,N-Dimethylbenzylammonium Chloride

Identification

Product Name: N-Decyl-N,N-Dimethylbenzylammonium Chloride
Chemical Formula: C23H42ClN
Synonyms: Benzalkonium chloride (C10), Benzyldimethyldecylammonium chloride
CAS Number: 139-07-1
Recommended Use: Disinfectant, sanitizer, algaecide, cleaning agent
Manufacturer Details: Always check current supplier documentation for emergency contact and phone numbers, address, and information on preparation and updates.

Hazard Identification

GHS Classification: Acute toxicity (oral and dermal), Skin corrosion, Severe eye damage, Environmental hazard (aquatic acute and chronic)
Hazard Statements: Harmful if swallowed or absorbed through skin, causes burns to skin and eyes, very toxic to aquatic life with long lasting effects
Pictograms: Corrosive (GHS05), Exclamation mark (GHS07), Environment (GHS09)
Signal Word: Danger
Precautionary Statements: Avoid skin and eye contact, do not breathe mist/vapors, keep out of reach of children, wash hands thoroughly after handling, wear protective gloves, clothing, and eye/face protection.

Composition / Information on Ingredients

Chemical Name: N-Decyl-N,N-Dimethylbenzylammonium Chloride
Concentration: 80–100% active ingredient
Impurities: May contain trace amounts of other benzalkonium homologs or water depending on formulation
Other Information: Purity details and complete ingredient ranges should be listed on current supplier's certificate of analysis.

First Aid Measures

Inhalation: Move victim to fresh air, keep at rest, seek medical attention if symptoms persist such as coughing or shortness of breath
Skin Contact: Remove contaminated clothing, wash exposed area with plenty of water and soap, seek medical attention if irritation or burning occurs
Eye Contact: Rinse cautiously with water for several minutes, remove contact lenses if present and easy to do, continue rinsing, obtain medical advice immediately
Ingestion: Do not induce vomiting, rinse mouth with water, if conscious give small quantities of water to drink, call a poison control center or doctor immediately
Most Important Symptoms: Burns, irritation, blistering, respiratory tract irritation, eye damage.

Fire-Fighting Measures

Suitable Extinguishing Media: Water spray, foam, dry chemical, carbon dioxide
Unsuitable Extinguishing Media: Avoid direct water jet which may spread substance or fire
Specific Hazards: May produce toxic and corrosive fumes such as hydrogen chloride, nitrogen oxides, carbon monoxide, and ammonia on combustion
Protective Equipment for Firefighters: Wear self-contained breathing apparatus and full protective gear, keep containers cool with water spray
Advice for Firefighters: Approach from upwind, avoid run-off to sewers, fight fire from a safe distance.

Accidental Release Measures

Personal Precautions: Evacuate unnecessary personnel, ventilate area, put on protective equipment—gloves, goggles, boots, coveralls
Environmental Precautions: Prevent product from entering drains, sewers, streams, or soil, contain spillage with non-combustible absorbent materials such as sand or earth
Spill Cleanup Methods: Collect spilled material with shovel or absorbent, place in labeled container for disposal, decontaminate area with water with plenty of ventilation, dispose collected material following local and national regulations.

Handling and Storage

Handling: Use only in well-ventilated areas, avoid contact with skin, eyes, and clothing, do not eat, drink, or smoke when working, avoid generating mist or aerosols
Storage: Store in tightly closed original container in a cool, dry, well-ventilated area away from incompatible substances like acids and oxidizers, protect from freezing and direct sunlight, always keep away from food, feed, and out of children's reach
Storage Class: Corrosive liquid storage area with secondary containment, proper signage, eye-wash station and emergency shower nearby.

Exposure Controls and Personal Protection

Exposure Limits: No specific OSHA or ACGIH exposure limits established for this compound; minimize airborne concentrations
Engineering Controls: Use local exhaust ventilation, general ventilation, or fume hood for bulk handling
Respiratory Protection: If ventilation is insufficient, use NIOSH-approved respiratory protection
Skin Protection: Wear chemical-resistant gloves (nitrile, neoprene), apron, and impervious shoes
Eye/Face Protection: Safety goggles or face shield
Hygiene Measures: Wash hands before breaks and after handling, avoid wearing contaminated clothing, shower after work if significant exposure occurred.

Physical and Chemical Properties

Appearance: Clear to slightly yellowish liquid (commercial formulation); white crystalline solid (pure)
Odor: Faint almond or aromatic
pH: Typically 6–9 (10% solution in water)
Melting Point/Freezing Point: 160–164 °C (pure)
Boiling Point: Decomposes before boiling
Flash Point: Not flammable in aqueous solution
Solubility: Soluble in water and ethanol; insoluble in most organic solvents
Density: 0.98–1.01 g/cm³ (at 20°C, solution)
Vapor Pressure: Negligible at room temperature
Viscosity: Low; depends on concentration and form.

Stability and Reactivity

Chemical Stability: Stable under recommended storage conditions; decomposes at high temperatures
Possibility of Hazardous Reactions: Exothermic reaction with strong oxidizing agents, incompatible with anionic surfactants, acids
Conditions to Avoid: Excessive heat, sunlight, freezing, incompatible materials
Incompatible Materials: Strong acids, anionic detergents, strong oxidizing agents, reducing agents
Hazardous Decomposition Products: Hydrogen chloride, benzyl chloride, nitrogen oxides, and other toxic gases upon combustion or thermal decomposition.

Toxicological Information

Acute Toxicity: Oral LD50 (rat): 240–400 mg/kg, Dermal LD50 (rabbit): 3,420 mg/kg
Skin Corrosion/Irritation: Causes severe burns and irritation
Serious Eye Damage/Eye Irritation: Causes eye burns, possible irreversible damage
Respiratory Effects: Can cause coughing, headache, respiratory tract irritation if inhaled
Sensitization: Rare, but may cause allergic skin reactions in sensitive individuals
Chronic Toxicity: No comprehensive data for carcinogenicity, mutagenicity, or reproductive effects in humans, but prolonged exposure to high concentrations may lead to dermatitis or respiratory issues.

Ecological Information

Toxicity to Aquatic Life: Highly toxic to fish, daphnia, and algae; LC50 (fish) ~ 0.5 mg/l (96h)
Persistence and Degradability: Some biodegradability in the environment, but breakdown depends on conditions; persistent in anaerobic conditions
Bioaccumulative Potential: Low to moderate; potential for accumulation in aquatic organisms
Mobility in Soil: Tends to bind to soil and sediments, limited mobility through ground
Other Adverse Effects: Product spillage can cause toxic effects to aquatic ecosystems and disrupt wastewater treatment plants.

Disposal Considerations

Waste Treatment Methods: Collect and deliver to approved chemical waste disposal facility in compliance with local, regional, and national regulations
Disposal of Packaging: Rinse containers thoroughly, dispose at authorized facilities, do not reuse empty containers, never dispose into drains or water bodies
Special Precautions: Handle waste with appropriate personal protection, document and label waste clearly, avoid mixing with incompatible substances.

Transport Information

UN Number: UN 2922
UN Proper Shipping Name: Corrosive Liquid, Toxic, N.O.S. (Contains: N-Decyl-N,N-Dimethylbenzylammonium Chloride)
Transport Hazard Class: Class 8 (Corrosive), Class 6.1 (Toxic)
Packing Group: II
Hazard Labels: Corrosive, Toxic
Environmental Hazards: Marine pollutant
Special Transport Precautions: Transport in upright, tightly closed containers, ensure vehicle signage as required by regulations, avoid transport with food or feed.

Regulatory Information

TSCA Status: Listed on the US Toxic Substances Control Act Inventory
EU Classification: Classified under Regulation (EC) No 1272/2008 as hazardous, REACH registration may apply
EPA Status (US): Registered antimicrobial substance, subject to FIFRA regulations
Canada DSL/NDSL: Listed
Workplace Exposure: Covered by OSHA Hazard Communication Standard, requires Safety Data Sheet and worker training
Other Regulations: Subject to restrictions under national, state, and local environmental, transportation, and health and safety regulations; users must consult legislation regularly as requirements change.