MSDS for N-Hexyl Pyridinium Bromide

Identification

Product Name: N-Hexyl Pyridinium Bromide
Synonyms: 1-Hexylpyridinium bromide
Chemical Formula: C11H18BrN
CAS Number: 14326-38-2
Intended Use: Laboratory chemicals, research, industrial processes
Manufacturer: Laboratory supplier names and contact details needed for tracking and emergency support
Emergency Phone: Emergency number typically provided by local regulatory authorities for hazardous material incidents

Hazard Identification

GHS Classification: Acute toxicity (oral, dermal, inhalation), skin and eye irritation, aquatic toxicity
Signal Word: Warning
Hazard Statements: May cause respiratory irritation, may cause eye and skin irritation, toxic to aquatic life with long-lasting effects
Precautionary Statements: Avoid breathing dust, mist, or fumes; wash thoroughly after handling; use only outdoors or in a well-ventilated area; avoid release to the environment
Pictograms: Exclamation mark, Environment
Routes of Exposure: Inhalation, ingestion, skin and eye contact; exposure leads to local irritation and potential systemic effects
Target Organs: Lungs, eyes, skin

Composition / Information on Ingredients

Chemical Name: N-Hexyl Pyridinium Bromide
CAS Number: 14326-38-2
EC Number: 238-249-2
Concentration: 100% (pure substance used in research or synthesis applications)

First Aid Measures

Inhalation: Move exposed person to fresh air, provide oxygen if breathing is difficult, seek medical attention for persistent symptoms
Skin Contact: Wash area with soap and plenty of water, remove contaminated clothing, seek medical advice if long-lasting irritation occurs
Eye Contact: Rinse patiently with water for several minutes, lift eyelids to clear all residues, seek medical advice if pain or vision issues remain
Ingestion: Rinse mouth, never induce vomiting, get immediate medical attention, monitor for nausea or stomach discomfort
Note to Physician: Treat symptomatically, monitor respiratory and cardiac functions; no specific antidote identified

Fire-Fighting Measures

Suitable Extinguishing Media: Water spray, dry chemical powder, carbon dioxide, foam depending on fire location
Specific Hazards: Combustion produces hazardous gases including hydrogen bromide, nitrogen oxides, carbon monoxide; dense smoke; containers heated by fire may burst
Protection for Firefighters: Full protective gear, self-contained breathing apparatus; prevent runoff from entering drains and watercourses
Firefighting Instructions: Remove containers from fire area if safely possible, cool uneffected containers with water spray

Accidental Release Measures

Personal Precautions: Evacuate area, limit access, wear suitable protective equipment including gloves, goggles, and respiratory protection
Environmental Precautions: Prevent product from entering water systems, spills into drains or soil must be contained immediately
Cleanup Methods: Contain and collect spillage with inert absorbent material (sand, earth), place in a chemical waste container, ventilate area, wash remaining residues with copious water, dispose of contaminated material following regulations

Handling and Storage

Handling: Use in a chemical fume hood, avoid formation of dust, avoid direct contact with eyes, skin, and clothing, never eat, drink, or smoke in areas where chemicals are handled
Storage: Store tightly closed in a cool, dry, and well-ventilated area, keep away from incompatible materials such as acids and oxidizing agents, store in containers clearly labeled, protect from sunlight and heat sources, keep out of reach of children and unauthorized personnel

Exposure Controls and Personal Protection

Engineering Controls: Use local exhaust ventilation, chemical fume hoods to minimize exposure
Respiratory Protection: Approved filter respirators for fumes and dust if airborne exposure may occur
Eye Protection: Tight-fitting safety goggles or face shield
Skin Protection: Chemical-resistant gloves (nitrile or neoprene), laboratory coat, long sleeves
Hygiene Measures: Wash hands, face, and exposed skin thoroughly after handling, remove contaminated clothing and wash before reuse
Exposure Limits: No occupational exposure limits established, minimize exposure as much as practical following ALARA (As Low As Reasonably Achievable) principle

Physical and Chemical Properties

Appearance: White to off-white crystalline powder
Odor: Characteristic, faintly musty
Odor Threshold: Data unavailable
pH: 5–7 (1% solution in water)
Melting Point: 125–130°C
Boiling Point: Decomposes before boiling
Flash Point: Not determined
Evaporation Rate: Not measured due to solid form
Flammability: Not classified as flammable
Vapor Pressure: Negligible
Relative Density: About 1.3 g/cm³
Solubility: Soluble in water, ethanol, methanol
Partition Coefficient (log Kow): No definitive data
Auto-ignition Temperature: No data
Decomposition Temperature: Above 150°C
Viscosity: Not applicable usually due to solid state

Stability and Reactivity

Chemical Stability: Stable under recommended storage conditions
Reactivity: Does not display hazardous reactivity with standard laboratory materials
Hazardous Reactions: Incompatible with strong oxidizers and strong acids causing decomposition reactions
Hazardous Decomposition Products: Hydrogen bromide, nitrogen oxides, carbon monoxide and carbon dioxide on combustion
Conditions to Avoid: Excess heat, open flame, moisture, direct sunlight, exposure to acidic or oxidizing materials

Toxicological Information

Acute Toxicity: Harmful if swallowed, irritant to skin and eyes, moderate toxicity by inhalation
Skin Corrosion/Irritation: Causes redness, burning, and dryness after prolonged or repeated contact
Serious Eye Damage/Irritation: Eye contact leads to pain, tearing, temporary injury
Sensitization: Potential to trigger allergic skin response on repeated exposure
Mutagenicity: No conclusive data, exercise caution with all pyridinium salts
Carcinogenicity: No classification by IARC, OSHA, or NTP
Reproductive Toxicity: Not listed as reproductive toxin; data insufficient for a final assessment
Inhalation Symptoms: Coughing, shortness of breath, possible respiratory irritation
Ingestion Risks: Gastrointestinal discomfort, nausea, vomiting, abdominal pain
Delayed and Immediate Effects: High concentrations lead to symptoms after latency period, prompt medical attention essential

Ecological Information

Aquatic Toxicity: Greatly toxic to aquatic organisms, risk of persistent environmental effects
Degradability: Limited biodegradation by standard environmental bacteria, persistent in surface waters
Bioaccumulative Potential: Evidence indicates moderate potential due to cationic surface activity
Mobility in Soil: Moderately mobile but adsorbs to soils with high organic matter
Other Adverse Effects: Avoid uncontrolled discharge into the environment, impacts in surface water persist and harm aquatic invertebrates

Disposal Considerations

Product Disposal: Dispose as hazardous waste following national and local regulations; incineration at high-temperature facilities recommended
Contaminated Packaging: Triple rinse containers, deliver to hazardous waste program authorities
Special Precautions for Landfill or Incineration: Prevent leaching into soil or watercourses, never dispose by drain or regular trash routes

Transport Information

UN Number: 3077
Shipping Name: Environmentally hazardous substance, solid, n.o.s. (N-Hexyl Pyridinium Bromide)
Transport Hazard Class: 9 (Miscellaneous dangerous substance)
Packing Group: III
Environmental Hazard Mark: Marine pollutant
Transport Conditions: Secure packaging, compatible containers, provide documentation and hazard communications per ADR, IATA, IMDG regulations

Regulatory Information

Labelling Requirements: Comply with GHS, CLP, OSHA HCS
TSCA Status: Listed or meets the criteria for research exempt substances
REACH Registration: Use only for exempt laboratory purposes unless registered
SARA/EPCRA: Not listed in Sections 302, 313, or 304, but chemical management programs may apply
Other Regulations: Observe workplace and environmental safety regulations per local, regional, and national authorities, maintain up-to-date safety procedures and emergency response plans