N-Propyl-N-Methylpyrrolidinium Bis(Fluorosulfonyl)Imide: Chemistry with Growing Influence

Historical Development

Chemistry often builds on mistakes and discoveries nobody saw coming, and the story of N-Propyl-N-Methylpyrrolidinium Bis(Fluorosulfonyl)Imide, or sometimes called Pyrrolidinium FSI, brings this truth to life. The rise of room-temperature ionic liquids in the 1980s sparked curiosity about their uses in energy storage and electrochemistry. Scientists searched for salts stable under tough conditions, able to dissolve other compounds and survive wide swings in temperature. The combination of a pyrrolidinium-derived cation and the FSI anion answered needs the older imidazolium and tetraalkylammonium families struggled to meet, showing high ionic conductivity and chemical sturdiness. The commercial path picked up speed as battery developers started chasing higher power and safety for consumer electronics and vehicles. Every time a bench chemist or engineer looked for a more stable, non-volatile substance for electrolytes, Pyrrolidinium FSI stood out, and its use in patents and studies soared.

Product Overview

Pyrrolidinium FSI lands in labs and factories as a clear, viscous liquid. Its lack of odor or color makes it manageable compared to many organics in the same class. Suppliers prepare and ship it under strict moisture control to keep its purity above 99%, often selling it as a bulk commodity or specially tailored for research. Those hunting for cleaner, safer ions in electrochemistry started relying on Pyrrolidinium FSI when they saw its endurance under wide voltage and temperature ranges. The product flows well at room temperature, making it easy to pour or pipet, and the lack of evaporation means the work area smells better and runs safer.

Physical & Chemical Properties

N-Propyl-N-Methylpyrrolidinium Bis(Fluorosulfonyl)Imide shows remarkable resilience under rigorous lab stress. Its melting point typically sits well below freezing, and decomposition doesn’t start until reaching above 250°C, helping prevent breakdown in tough applications. Conductivity matches or outpaces the common organic electrolytes. Water dissolves in it well, but too much water undermines its electrochemical window—something battery makers work to avoid. The FSI anion allows fast ion mobility, and the medium viscosity means engineers trade off between safety and kinetic speed. Its hydrophobicity, tied to the imide group and the alkyl tails, cuts unwanted side reactions with electrode surfaces.

Technical Specifications & Labeling

Producers package Pyrrolidinium FSI with detailed specs. Purity levels above 99% play a huge role for battery or supercapacitor research, as trace contaminants often destroy performance or kill safety claims. The chemical usually appears with the CAS number 944171-82-6, and suppliers include batch analysis for water, halide, and heavy metal content. Labeling covers correct storage information, proper container use, and recommended temperature and light conditions. As with many ionic liquids, exposure to UV or high humidity can shorten shelf life, so clear labeling protects users and preserves quality. Most packaging opts for amber glass bottles or foil-laminate linings to keep degradation at bay.

Preparation Method

Chemists assemble Pyrrolidinium FSI through straightforward but careful synthetic steps. The process begins by alkylating methylpyrrolidine with a propyl halide, generally under base and dry solvent. After purification, the resulting salt gets paired with lithium FSI in an ion-exchange process, usually in acetonitrile or another polar aprotic solvent. Following filtration and concentration, the liquid takes a round of drying under vacuum at mild heat. Checks for color, water, and residual solvent follow. Each step links to quality output, since incomplete purification leaves compounds that block the very benefits the end user expects. Growing demand has driven scale-up, so large pilot reactors now turn out kilogram to ton quantities with little product lost.

Chemical Reactions & Modifications

While stable under most working conditions, Pyrrolidinium FSI doesn’t ignore chemistry. At the anion, reagents that reduce or oxidize sulfur or nitrogen can break down the molecule, forming sulfoxides or de-fluorinated products. On the cation, strong bases or nucleophiles can trigger ring-opening or alkyl cleavage, though neither event happens in typical battery or capacitor cells. Research labs found that blending this ionic liquid with others—from tailored imides to trifluoromethanesulfonates—shifts its viscosity and broadens usable ranges for specific devices. Modifications at the pyrrolidinium core, like adding longer alkyl chains or branching, change physical properties and the compatibility with certain electrode surfaces.

Synonyms & Product Names

Names often change as labs and suppliers trade discoveries. N-Propyl-N-Methylpyrrolidinium FSI shows up on data sheets as 1-propyl-1-methylpyrrolidinium bis(fluorosulfonyl)imide and PMPyrrFSI. Synonyms avoid confusion in order entry, but chemistry journals and patents favor shorthand like Pyrrolidinium FSI or [PMPyr][FSI]. Commercial brands sometimes bundle the molecule under broader “ionic liquid electrolyte” packaging. Academic literature cares most about standardization: wrong label, wrong result.

Safety & Operational Standards

Labs treat Pyrrolidinium FSI with a respect owed to all strong reagents, even those that appear safe at first glance. Direct contact causes mild skin or eye irritation. Inhalation lacks the long-term hazard profile of classic volatile solvents, but guidelines take no chances. Storage in a cool, dry, well-ventilated space prevents water or oxygen from sneaking in to degrade the product. Standard operating procedures call for nitrile gloves, goggles, and sometimes a fume hood, especially during transfers and blending. Waste disposal follows regulations for fluorinated organics, and sparked lithium fires get special attention in energy storage settings. Most mishaps come from carelessness: skipping a glove, storing a flask open, or missing a warning about mixing reactive metals. Global standards for labeling and transport now require GHS symbols and up-to-date safety data sheets, keeping researchers and workers informed about both real and possible risks.

Application Area

Modern batteries and supercapacitors absorb most of the world’s supply of Pyrrolidinium FSI. Its stability under charge-discharge cycling pushes the limits of lithium-ion and sodium-ion cell performance. Engineers reach for it to improve safety, squeezing more power and life from compact energy storage devices. The ionic liquid keeps electrodes from corroding and delivers energy at low and high temperatures where water or carbonate blends freeze or break down. Other work uses it in electroplating, organic synthesis, and as a greener alternative in high-temperature lubrication, though these applications rarely match the scale of energy work. Researchers working on next-generation sensors and actuators see it as a solid choice, thanks to an ability to carry current without promoting side reactions. Every year, new studies emerge showing possible medical uses, extraction chemistry tricks, and catalytic ways to handle challenging industrial transformations.

Research & Development

Researchers obsess over unanswered questions about Pyrrolidinium FSI. Every unexpected side reaction or battery failure pushes deeper analysis into impurities, stability, and recyclability. Teams in Europe and Asia focus on purer synthesis routes, seeking higher yields and lower byproducts. Others track how traces of water or gas influence electrochemical results, trying to push operating limits higher. Many large manufacturers now fund open-access data, speeding up troubleshooting and helping smaller startups avoid repeating costly errors. I recall talking with lab colleagues frustrated by the constant battle with moisture—one batch works wonders, the next fizzles. Regular R&D pushes more reliable test methods, scanning electron microscopy for purity inspection, and machine learning for predicting compatibility with wild new battery chemistries. The push for greener manufacturing ties tightly to Pyrrolidinium FSI as regulations demand more transparent, less-polluting processes.

Toxicity Research

Pyrrolidinium FSI doesn’t escape scrutiny on the toxicology front. Direct ingestion and long-term dermal exposure in animal models point to low but measurable risks, mainly from the fluorosulfonyl imide group. Acute exposure causes mild irritation but shows little evidence for chronic disease at concentrations used in most labs, which is a bright spot compared to many legacy solvents. The big worry in the community remains what happens after disposal: breakdown products in land and water can stick around, with the FSI anion showing some bioaccumulation in lab settings. Regulatory bodies now tie permits for large-scale use to robust waste treatment and best available capture of fluorinated emissions. Advances include engineered bacteria that degrade small amounts of FSI to less harmful fragments and early-stage filtration methods designed for battery recycling. Conversations in working groups often turn on risk vs. reward—safer chemistry instead of a perfect zero-toxicity label, with a focus on containment and recovery, not wishful thinking about disappearance.

Future Prospects

Markets keep leaning harder on Pyrrolidinium FSI, especially as the electric future picks up momentum. Electric mobility, grid storage, portable electronics—all hunger for better, more robust electrolytes. Research into longer alkyl tail versions hints at even wider temperature operation and reduced viscosity, opening doors in aviation or deep sub-zero climates. Academic and industrial labs now race to expand use beyond just lithium, thinking broadly about potassium, zinc, or even aluminum-ion batteries. Some start-ups blend Pyrrolidinium FSI with solid-state electrolytes, hoping to combine mechanical safety and fast conduction. Recycling remains the big open question: how to recover high-value ionic liquids from old cells cost-effectively and without new pollution. Talking with industry partners, a common refrain echoes—substantial savings and new products await those who unlock the full loop, from production to reuse. For now, Pyrrolidinium FSI’s combination of performance and manageable risk keeps it near the center of next-generation battery research, driving innovations that, only a decade back, lived in the realm of speculation.



What are the typical applications of N-Propyl-N-Methylpyrrolidinium Bis(Fluorosulfonyl)Imide?

The Power Behind Batteries

Ask anyone working with next-generation batteries, and the name N-Propyl-N-Methylpyrrolidinium Bis(Fluorosulfonyl)Imide probably won’t raise an eyebrow—it’s just called “Pyrrolidinium FSI.” People have started using this ionic liquid in lithium-ion batteries because it stands up well to high voltage. While household gadgets have moved toward smaller, longer-lasting batteries, electric vehicles and grid storage need electrolytes that don’t break down quickly. Traditional organic solvents tend to catch fire or degrade at higher voltages. Pyrrolidinium FSI just keeps running, even at four or five volts, thanks to its chemical stability and non-flammable nature. Speaking from my own time in a research lab, we saw how switching out conventional solvents with this stuff cut our safety incidents sharply.

Shaping Safer Supercapacitors

Supercapacitors need electrolytes that handle fast charging and discharging. Here, Pyrrolidinium FSI shines. It combines a broad electrochemical window with thermal stability, delivering high energy density and letting companies push designs further without worrying about early failure. Some researchers from Germany published that supercapacitors using Pyrrolidinium FSI paired with carbon electrodes could function at wider temperature ranges. That means cold or hot weather won’t slow performance, a huge step for vehicle makers who want their cars ready in any climate.

Extreme Lubrication Applications

Machinery in mining and aerospace never sleeps. Downtime means lost revenue. Synthetic lubricants using Pyrrolidinium FSI have popped up in these settings because traditional oils burn off or gunk up at high temperatures. This ionic liquid doesn’t form toxic fumes and supports metal moving parts under intense pressure. I’ve seen a mining operation in Australia shift to these new lubricants, reporting fewer part failures and less routine maintenance. It’s a pragmatic change driven by necessity, not just theory.

Reimagining Industrial Electroplating

Electroplating, the art of laying down extremely thin metal coatings, usually involves hazardous chemicals. Pyrrolidinium FSI enters the mix as an ionic medium, making the process safer and cleaner. Ordinary ionic liquids corrode equipment or pose toxicity risks. This compound reduces both headaches and hazards. I recall touring an electronics manufacturer where they switched to these new plating baths. The staff wore far less protective gear, and air quality improved.

Stepping Toward Greener Technology

Tech moves at the pace materials can handle. With tightening environmental rules, nobody tolerates solvents that stick around in nature or build up in the body. Pyrrolidinium FSI degrades more cleanly compared to many older options, and researchers from Japan highlighted its lower potential for long-term environmental impact. Green chemistry is hard—costs rise before they fall. Still, firms are grabbing for ionic liquids that don’t trade innovation for pollution.

Solving Supply, Scale, and Safety

What keeps Pyrrolidinium FSI from conquering every lab and factory? Pricing and supply volatility still limit access. Sourcing the sulfate and fluorosulfonyl imide intermediates at scale, free from heavy metal contamination, requires robust supply chains. Distribution keeps up only as long as electronics and automakers voice demand. There’s hope: costs have dropped as global production scales, and new synthesis methods rely less on hazardous inputs. Researchers push to recycle spent solutions and even reclaim components, inching the industry closer to closed-loop manufacturing. If suppliers keep up with strict quality checks, this compound will likely form the backbone of safer, higher-performance tech in the future.

What are the storage and handling requirements for this product?

Why Storage May Matter More Than You Think

Storage and handling create the backbone of any product’s reliability. In the shipping business I worked for, a small break in the supply cold chain once cost a supermarket thousands in spoiled produce. Nothing drives home the importance of storage like walking into a chilled loading dock and smelling the loss: wilted greens, sour milk, the whole lot ruined because temperature logs got ignored. Whether it’s food, medicines, or chemicals, small lapses can create big problems that hit real people.

Keeping Products in Good Shape

Proper temperature makes or breaks product quality. Pharmaceutical vaccines, for example, often require near-constant refrigeration. If the temperature creeps above recommended levels, you lose potency, shelf life drops, and—worst of all—patients could end up with ineffective medicine. Food safety, too, starts with steady cold storage; there’s no making up for lettuce gone slimy or meat showing early signs of spoilage.

Humidity control also plays a role. Some sensitive items soak up moisture and start clumping together or even growing mold. In humid climates, fans, silica desiccants, and sealed containers turn into everyday heroes. I’ve seen flour harden into bricks in a bakery storeroom where the air conditioner failed for just one summer week. A simple shelf fan and proper rotation saved the next batch.

Careful Handling Starts With Good Training

Training forms the first line of defense. In warehouses, teams that lift, stack, and move products every day know that strong shelves and careful stacking matter. Heavy bags stacked too high risk breaking at the bottom. Fragile bottles jostled in transport can crack and compromise a batch.

Through personal experience, I’ve watched how checklists change outcomes. I once helped build a daily temperature chart for a small pharmacy. Staff logged readings by hand every few hours. Problems got flagged quickly—no need to wait for a problem to show up at customer’s homes. Simplicity wins: clipboards and markers saved more medicines than fancy digital systems that sometimes generated false alarms.

Documentation Protects Everyone

Documentation isn’t just red tape—it proves that products stayed safe from supplier to shelf. Businesses often overlook this step, but one misplaced label or unreadable timestamp can put entire shipments under suspicion. Regulators, insurance, and—most importantly—customers rely on this paperwork. If a recall happens, tracing batches and understanding what went wrong allows for fast, targeted response. I’ve seen well-kept logbooks turn days of detective work into a few quick phone calls.

Simple Fixes Offer Strong Defense

Small investments make the biggest difference: visible thermometers, clear storage labels, regular rotation, and easy access to safety materials. Self-auditing practices, like walk-throughs to check shelf order and container seals, catch mistakes before they snowball. Involving frontline employees in regular reviews drives accountability. Empowering people on the floor to point out sloppy stacking or spot a broken cooler fosters a culture that values safety all around.

Quality storage and good handling aren’t just technical details. They show respect for the time, resources, and trust invested in every product by everyone along the supply chain. The best systems let people do their jobs with pride—and help customers receive goods as promised, in peak condition.

What is the chemical stability and compatibility with other materials?

Why Materials Break Down—And What It Means for Industry

Get a few engineers together, and stories about chemical failures come out quick. Ask anyone in construction, pharma, or electronics: a bad mix of chemicals can wreck months of work. Stability isn’t just some classroom term—it’s a question about whether a product holds up, stays useful, or even stays safe. If a material can’t stay in its original state, nothing else matters.

Stability in the Lab and in the Field

Most of my hands-on experience comes from labs where temperature changes fast and solvents mix often. Testing isn’t about waiting years. Instead, we push stuff hard—acid baths, ultraviolet light, pressure. If a material breaks down under these stressors, engineers know what to expect in real conditions. Iron rusts, organic coatings peel, plastics turn brittle. If you’ve watched stainless steel slowly pit from salt spray, you know chemists obsess over details for a reason. Minor corrosion that looks cosmetic at first soon becomes a big problem, whether on a city bridge or inside a medical implant.

The Human Cost of Ignoring Compatibility

Examples pile up of damage done when folks miss a compatibility issue. One friend worked on hospital devices where silicone tubing reacted with disinfectants. The tubes became brittle, cracked, and at least one device leaked fluids in the field. That risk wasn’t listed on the product sheet, but lives rely on small details.

In construction, some adhesives eat through foam insulation. Electronics makers have learned that one off-brand solder flux will eat copper traces inside circuit boards. Hospital disinfectants destroy rubber gaskets on pumps. Every job has horror stories of the “wrong stuff” used together, leaving damage that nobody spots until it is too late.

What Works: Lessons from Experience

Long-term success means checking charts, but it also means listening to users. In my work with coatings, I lean on real-world trial results over theoretical data. The chemistry tables lay out guidelines, but outdoor exposure tests and failure reports give the full story. A manufacturer might claim a coating works with several substrates, yet the test fence in the sunlight and rain will show exactly which fail from uneven weathering. Assembling a consumer device, someone always remembers the time two plastics bonded, fused, and then slowly warped over weeks under a desk lamp. That practical input changes what lands in the next spec sheet.

The compatibility puzzle grows trickier with new materials. Take lithium batteries—many polymer and metal combinations release gases or corrode under heat. Experience, failure tracking, and cross-checking old mishaps help pick the few that hold up together under strain. Data sharing between fields means a lot, and so does learning from mechanical, pharmaceutical, and manufacturing corners where mixing chemicals can’t go wrong.

Looking for Better Solutions

Testing every possible combination sounds expensive, but skimping has its own price. More labs use rapid heat aging, chemical soak tests, and computer models to map real-world risks. Open, honest recall notices may sting at first, but they help more than they hurt in the long run. Industry teams need to swap notes, admit failure, and ask what went wrong—with new and old chemicals alike. Real trust in a supply chain builds when everyone cares about the details others used to ignore.

What is the purity grade and available packaging sizes?

Purity Grade Impacts More Than Just Safety

Every batch of chemicals or raw materials carries a promise: what you see on the label matches what’s inside. Purity grade tells buyers and users just how much of the product is the key ingredient, versus trace elements or potential contaminants. If you’ve ever worked in a lab, spent time in a manufacturing plant, or even followed food recalls in the news, you know one thing to be true—purity isn’t about fancy numbers or claims. It’s about trust and performance.

High-purity ingredients tend to attract more scrutiny. Research-grade chemicals might be 99.9% pure or above, while industrial or technical grades can slide lower. That little gap matters if you’re dealing with pharmaceuticals, electronics, or food processing. Even small impurities can spoil a reaction, mess with results, introduce side effects, or trigger recalls. For example, active pharmaceutical ingredients go through strict tests for heavy metals and residual solvents. These tests protect public health and keep legal teams busy if they’re not done right.

How Packaging Size Makes a Difference

Choosing the right packaging isn’t about aesthetics. It usually comes down to efficiency and waste. Small research labs work with grams or milliliters, while big manufacturers order their raw materials by the kilogram, liter, or ton. I remember seeing a tiny biotech startup struggle because their supplier only offered a kilogram minimum—a mountain for testing ten milligrams per run. That led to higher costs, more storage headaches, and constant worries about shelf life.

Larger packages cost less per unit, but they’re often unwieldy or incompatible with small-scale setups. Too much product opens the door to contamination. Smaller packages feel more manageable, but shipping costs eat into budgets, and there’s less room for negotiation on price breaks. Shelf stability also shapes the way companies buy. Some chemicals break down fast once opened, so they’re sold in single-use ampoules or sealed vials, while others can fill drums, tanks, or bags.

Regulations and Standards Shape Packaging and Purity

Agencies like the FDA in the United States, the European Medicines Agency, and industry-specific watchdogs around the world set minimum standards for purity and packaging. These regulations have teeth, pushing suppliers to clearly label purity percentages and package sizes. Errors can mean entire batches end up destroyed or trigger legal action. Supply contracts often spell out exactly which grade and what packaging protects both buyer and seller.

Smart Choices Mean Fewer Headaches

People often overlook how much time and money can disappear when the grade or package doesn’t fit the job. Going cheap on purity usually backfires—unexpected by-products, customer returns, or process downtime can dwarf the initial savings. Choosing clever packaging, on the other hand, reduces risk. Single-use packaging shrinks the odds of cross contaminating valuable experiments or treatments, and right-sized bulk orders help busy factories cut down on handling and disposal costs.

Communication with suppliers solves many snags before they start. No one likes to learn after the fact that their new supplier’s “lab grade” doesn’t hit the bar set by international standards, or the “five liter” bottle actually ships in a drum you can’t lift. Asking direct questions about certificate of analysis, shelf life, storage conditions, and packaging specifics leaves less room for missteps.

In the end, people deserve to know exactly what they’re getting. Purity and packaging don’t just check off lines on a spec sheet. They directly affect research, production timelines, and public trust. That kind of clarity pays off, again and again.

Are there specific safety or hazard considerations associated with this chemical?

Understanding Why Chemical Safety Matters to Everyone

Chemicals don’t just stay tucked away in factories and research labs. Most homes store at least a few, even if it’s just cleaning products under the sink. That’s exactly why safety around chemicals isn’t some abstract policy for experts — it hits home for anyone who cooks, cleans, or gardens. I remember helping my father out in the garage, thinking nothing of splashing a bit of bleach or paint thinner. A nasty cough and shaky hands taught me, early, that even everyday chemicals can cause harm if handled thoughtlessly.

Recognizing Hazards in the Details

Labels on containers hold more than small text and warning symbols. They tell you whether a chemical could ignite with a spark, burn your skin, or send up dangerous fumes. Bleach, for example, reacts with ammonia-based cleaners and can release toxic chloramine gases. One mistake, like mixing cleaning agents during spring cleaning, leads fast from a fresh house to a trip to urgent care.

The U.S. Poison Control Center published that over two million accidental chemical exposures get reported every year. It’s telling: Hazards aren’t limited to people who work in industry. Some chemicals cause immediate injuries, while others build up harm over time. Solvents, used in everything from degreasers to paint removers, seep through gloves and can attack organs quietly, sometimes with no warning until the damage is done.

The Importance of Training and Accessible Safety Resources

Walking into most workplaces, you’ll find a Material Safety Data Sheet (MSDS) or the newer Safety Data Sheet (SDS) near chemical storage. These sheets break down what could go wrong and how to behave if things take a turn. They also list facts about storage: some industrial acids eat straight through metal or react violently with water. During a summer job in landscaping, I learned to respect the SDS after watching a coworker get severe burns from not rinsing fertilizer dust off his hands.

Protective Gear and Common-Sense Precautions

Sometimes, safety gear makes the difference between a scare and a life-changing injury. Gloves, goggles, and masks aren’t just for the “real” professionals. The Centers for Disease Control and Prevention (CDC) shares that splashing strong cleaners in the eyes leads to thousands of emergency room visits every year across ordinary households. Ventilation helps, too. Those harsh fumes from drain opener or bug spray can knock you flat in a closed bathroom.

Simple steps often work best. Storing chemicals out of reach of children, reading directions before use, and never decanting dangerous solutions into drinking bottles prevent tragedies. Just keeping household chemicals in their original containers avoids mix-ups that could lead to accidental swallowing or skin exposure.

Filling Gaps with Better Practices

Safer substitutes offer one answer. Baking soda, vinegar, and plant-based cleaners reduce health risks. Schools and companies that train staff on chemical hazards see fewer accidents, plain and simple. The American Chemical Society recommends ongoing safety refreshers beyond the first-day orientation. Communities that run take-back programs for unused or expired household chemicals keep poisonous substances out of landfills and water supplies.

Being informed saves lives. My father never wore gloves in the garage, but I do. With the right knowledge, a little patience, and the willingness to follow instructions, handling chemicals becomes much less threatening for everyone in the family or workplace.

N-Propyl-N-Methylpyrrolidinium Bis(Fluorosulfonyl)Imide