MSDS for Octadecylbis(2-Hydroxyethyl)Methylammonium Chloride

Identification

Product Name: Octadecylbis(2-Hydroxyethyl)Methylammonium Chloride
Synonyms: Stearylbis(2-hydroxyethyl)methylammonium chloride
Chemical Formula: C25H56ClNO2
CAS Number: 68155-01-1
Recommended Use: Antistatic agent in plastics, textile conditioning, surfactant in personal care products
Manufacturer Information: Available from multiple chemical suppliers globally, emergency contact details can be found on commercial packaging

Hazard Identification

GHS Classification: Skin irritation, Eye irritation, Acute aquatic toxicity
Signal Word: Warning
Hazard Statements: Causes skin irritation, Causes serious eye irritation, Harmful to aquatic life
Pictograms: Exclamation mark, Environment
Precautionary Statements: Wear protective gloves, Wash hands after handling, Avoid release to the environment, Seek immediate medical advice in case of contact
Routes of Exposure: Inhalation, Eye/skin contact, Ingestion
Specific Hazards: Spills may create slippery surfaces, Elevated risk for dermatitis upon repeated exposure

Composition / Information on Ingredients

Chemical Name: Octadecylbis(2-hydroxyethyl)methylammonium chloride
CAS Number: 68155-01-1
Concentration: 95%-100%
Impurities/Stabilizing Additives: No specific stabilizers reported; trace byproducts may form under manufacturing or storage, usually under 1%

First Aid Measures

Eye Contact: Rinse cautiously with water for several minutes, remove contact lenses if present and easy to do, continue rinsing, seek medical attention
Skin Contact: Remove contaminated clothing, wash skin thoroughly with soap and water, seek medical advice if irritation develops
Inhalation: Move to fresh air, keep individual warm and at rest, obtain medical attention if symptoms persist
Ingestion: Rinse mouth, do not induce vomiting unless directed by medical personnel, drink water to dilute, consult a physician for advice
Most Important Symptoms: Irritation, redness, dryness, prolonged exposure can worsen dermatological response
Indication of Immediate Medical Attention: Persistent irritation, difficulty breathing after inhalation, unconsciousness, severe eye effects

Fire-Fighting Measures

Suitable Extinguishing Media: Foam, dry chemical, carbon dioxide, water spray (avoid full water jets, may spread chemical)
Unsuitable Extinguishing Media: Full water jet
Specific Hazards: Heating or fire may release toxic vapors including nitrogen oxides, hydrogen chloride
Protective Equipment for Firefighters: Full protective clothing, self-contained breathing apparatus, stay upwind
Firefighting Procedures: Cool nearby containers with water spray to reduce pressure build-up, contain run-off to prevent entry to sewers or watercourses

Accidental Release Measures

Personal Precautions: Eliminate all ignition sources, use proper personal protective equipment—gloves, goggles, respirator
Environmental Precautions: Prevent spills from entering sewers, waterways, or soil, contact local environmental authorities if large release occurs
Containment Methods: Stop further leakage if safe, dike spilled material with inert absorbent like sand or earth
Cleaning Methods: Collect with non-combustible absorbent, place in suitable containers for disposal, clean area with detergent and water

Handling and Storage

Safe Handling: Use in well-ventilated areas, avoid creating aerosols or dust, use proper protective clothing, do not eat or drink near product
Storage Conditions: Store tightly closed in original containers, keep in cool, dry place away from direct sunlight and incompatible materials like strong oxidizers
Incompatibilities: Strong acids, oxidizing agents, anionic surfactants, aluminum, zinc
Special Storage Requirements: Avoid freezing or extreme heat, ensure containers remain upright and secure

Exposure Controls and Personal Protection

Exposure Limits: No established occupational exposure limits
Engineering Controls: Ensure adequate ventilation, use local exhaust where risk of airborne exposure
Personal Protective Equipment: Chemical-resistant gloves, protective goggles or face shield, impervious clothing for skin protection, suitable respirator in cases of insufficient ventilation
Hygiene Measures: Wash hands, face, and exposed skin after handling, do not bring contaminated clothing home

Physical and Chemical Properties

Appearance: White to pale yellow waxy solid or viscous liquid
Odor: Mild, amine-like
pH: 5.0–7.0 (1% aqueous solution)
Melting/Freezing Point: 40–50°C
Boiling Point: Decomposes before boiling
Flash Point: >100°C
Solubility: Water-soluble
Vapor Pressure: Negligible at room temperature
Relative Density: 0.95–1.05
Partition Coefficient (log Pow): Estimated above 4
Decomposition Temperature: Above 200°C
Other Data: Surface-active properties, forms stable emulsions in water

Stability and Reactivity

Chemical Stability: Stable under recommended storage and handling conditions
Reactivity: Not considered reactive under normal conditions
Hazardous Reactions: May react with strong oxidizers, acids, anionic compounds
Conditions to Avoid: Strong heat, freezing temperatures, exposure to sunlight
Hazardous Decomposition Products: Nitrogen oxides, hydrocarbons, chlorine compounds, carbon monoxide under combustion

Toxicological Information

Acute Toxicity – Oral: LD50 (rat) > 2000 mg/kg, low acute toxicity
Acute Toxicity – Dermal: LD50 (rat) > 2000 mg/kg
Acute Toxicity – Inhalation: No data available; low volatility limits vapor hazard
Skin Corrosion/irritation: Causes conjunctival and skin irritation, repeated/prolonged exposure increases risk
Eye Damage/irritation: Severe irritant
Sensitization: Non-sensitizing in standard patch tests
Chronic Effects: No significant chronic or carcinogenic findings reported; not mutagenic in standard assays
Target Organs: Skin, eyes, mucous membranes

Ecological Information

Acute Aquatic Toxicity: Harmful to aquatic organisms (LC50: 1-10 mg/L for fish, daphnia)
Chronic Aquatic Toxicity: Long-term harmful effects on aquatic life may occur
Persistence and Degradability: Biodegradability moderate; persists longer under low-oxygen conditions
Bioaccumulative Potential: Log Pow suggests moderate to high potential
Mobility in Soil: Binds to organic material, moderate migration in soil environments
Other Adverse Effects: QACs have well-documented aquatic toxicity, restrict release to environment

Disposal Considerations

Product Disposal: Dispose in accordance with local, state, and federal regulations; incineration preferred for waste chemical, avoid release to natural waters
Container Disposal: Rinse thoroughly, then offer for recycling or proper landfill; do not reuse containers for other purposes
Special Precautions: Spills: absorb and contain, neutralize and dispose at approved facility
Regulatory Requirements: Check national/regional rules for handling quaternary ammonium compounds

Transport Information

UN Number: Not regulated as dangerous goods under current rules
Proper Shipping Name: Octadecylbis(2-hydroxyethyl)methylammonium chloride
Transport Hazard Class: Not classified
Packing Group: Not classified
Environmental Hazards: Avoid transporting with food or animal feed, shipment in bulk may require spill response plan
Special Precautions for User: Secure loads to prevent shifting or package breakage, comply with local in-transit hazardous substance rules

Regulatory Information

OSHA Status: Not classified as hazardous under OSHA standards
SARA 313: Not listed
TSCA: Listed on the US Toxic Substances Control Act Inventory
DSL/NDSL: Listed in Canada
REACH (EU): Pre-registered, specific registration dossier may be required for large-scale import
Labeling Requirements: GHS-compliant labeling in workplace
Other Regulatory Info: Subject to chemical-specific restrictions in some regions, user must verify local requirements prior to commercial use