MSDS for Tetrabutyl-Ammonium Trifluoroacetate

Identification

Product Name: Tetrabutyl-Ammonium Trifluoroacetate
Chemical Formula: C16H36F3NO2
Synonyms: TBA Trifluoroacetate
Recommended Use: Chemical synthesis, laboratory research
Supplier Details: Check label or invoice for supplier contact information; manufacturers update this information as regulations shift.
Emergency Contact: Refer to local emergency response center or supplier emergency line.

Hazard Identification

GHS Classification: Causes skin and eye irritation, presents inhalation hazard, not classified as carcinogenic under IARC, may cause discomfort if swallowed
Signal Word: Warning
Hazard Statements: H315: Causes skin irritation; H319: Causes serious eye irritation; H335: May cause respiratory irritation
Precautionary Statements: Avoid breathing vapors, wash hands after handling, use proper ventilation, wear protective equipment
Pictograms: Exclamation Mark
Routes of Exposure: Inhalation, skin contact, eye contact, ingestion
Health Effects: Skin redness, stinging eyes, sore throat, headache

Composition / Information on Ingredients

Chemical Name: Tetrabutyl-Ammonium Trifluoroacetate
CAS Number: 60557-81-7
EC Number: Not assigned
Concentration: Typically >98%
Impurities: Traces of other ammonium salts (manufacturer-specific)
Other Ingredients: No significant stabilizers or additives present

First Aid Measures

Inhalation: Move person to fresh air, seek medical attention for persistent symptoms, keep warm and at rest
Skin Contact: Remove contaminated clothing, wash skin with soap and plenty of water for at least 15 minutes, consult a doctor if irritation continues
Eye Contact: Rinse with gentle stream of water for at least 15 minutes, lift eyelids occasionally, consult an ophthalmologist
Ingestion: Rinse mouth, do not induce vomiting if conscious, drink water, contact poison control or a physician
Notes for Medical Personnel: Treat symptomatically based on patient’s condition; provide supportive care as needed

Fire-Fighting Measures

Suitable Extinguishing Media: Dry chemical, foam, carbon dioxide, water spray
Unsuitable Media: Avoid direct water jets, may spread product
Hazardous Decomposition Products: Hydrofluoric acid, carbon oxides, ammonia, nitrogen oxides under fire
Special Protective Equipment: Wear self-contained breathing apparatus, fully protective gear
Fire and Explosion Hazards: Substance not classified as highly flammable, vapors may irritate respiratory tract in confined spaces
Firefighting Instructions: Cool exposed containers, avoid breathing fumes, isolate hazard area

Accidental Release Measures

Personal Precautions: Wear gloves, goggles, and lab coat; avoid contact with skin and eyes
Environmental Precautions: Prevent entry into waterways, drains, soil
Cleanup Methods: Absorb with inert materials such as sand or vermiculite, sweep up residue, dispose in closed container for waste
Spill Area Ventilation: Increase ventilation in closed spaces, evacuate non-essential personnel
Reporting: Notify supervisors and environmental authorities as required by regulations

Handling and Storage

Handling: Work in a well-ventilated space, use fume hood if possible, avoid inhaling dust or vapor; keep container closed
Storage Conditions: Store tightly sealed in a cool, dry, and well-ventilated area away from incompatible materials such as strong oxidizers and acids
Incompatible Materials: Keep away from heat, sparks, open flames, avoid storage with acids or oxidants
Storage Container: Use original packaging or chemically compatible containers

Exposure Controls and Personal Protection

Occupational Exposure Limits: No established OSHA or ACGIH exposure limits for this chemical
Engineering Controls: Ensure good general and local exhaust ventilation; use fume hood for large-scale handling
Personal Protection: Wear chemical splash goggles, nitrile gloves, lab coat, face shield when splashing risk exists
Respiratory Protection: Use approved respirator for high dust/vapor concentrations; avoid open container exposure
Hygiene Measures: Remove contaminated clothing, wash hands after handling, do not eat or drink in work area

Physical and Chemical Properties

Appearance: White to off-white crystalline powder
Odor: Very faint characteristic odor
pH: 4 - 6 (typically in 10% water solution)
Melting Point: 62 – 66°C
Boiling Point: Not applicable, decomposes on heating
Flash Point: Data not available
Solubility: Readily soluble in water, soluble in many polar organic solvents
Vapor Pressure: Negligible at room temperature
Relative Density: Approximately 1.03 g/cm³
Partition Coefficient: Not determined
Other Data: Stable under recommended storage conditions; avoid light and moisture

Stability and Reactivity

Reactivity: Stable under standard conditions
Chemical Stability: Stable if stored dry and at room temperature, decomposes on strong heating
Conditions to Avoid: High humidity, prolonged exposure to air, high temperatures
Incompatible Materials: Strong oxidizers, acids, acid chlorides, anhydrides
Hazardous Decomposition: Ammonia, hydrogen fluoride, carbon oxides, nitrogen oxides

Toxicological Information

Route of Exposure: Inhalation, skin absorption, ingestion
Acute Effects: Irritation to skin, eyes, mucous membranes; may cause headache, drowsiness
Chronic Effects: Repeated exposure may cause dermatitis, long-term respiratory conditions not well documented for this substance
LD50 (oral-rat): Data not well established, expected to have low acute toxicity
Sensitization: Not reported as sensitizer; follow precautionary measures due to lack of chronic data
Mutagenicity/Carcinogenicity: No data available; not listed under IARC, NTP, OSHA hazard categories
Other Information: Evidence on reproductive toxicity lacking, avoid exposure in sensitive groups

Ecological Information

Aquatic Toxicity: Data limited, avoid release into the environment
Persistence and Degradability: Not expected to hydrolyze rapidly, biodegradability data not comprehensive
Bioaccumulation Potential: Limited bioaccumulation suspected due to salt structure
Mobility in Soil: Water solubility may increase risk of mobility if spilled
Other Adverse Effects: Not identified, minimize discharge to surface waters or drains

Disposal Considerations

Waste Disposal: Collect in properly labeled waste containers; destroy by licensed chemical disposal contractor
Contaminated Packaging: Dispose of in accordance with regional regulations; containers should not be reused
Special Disposal Methods: Avoid landfilling, prioritize incineration where permitted
Regulatory Reference: Follow local, state, federal, and national regulations for chemical waste management

Transport Information

UN Number: Not regulated for transport under international regulations
Transport Hazard Class: None assigned
Packing Group: None assigned
Labels Required: None for land, sea or air transport under standard quantities
Special Transport Precautions: Secure container, protect from moisture, follow all local and international shipping instructions

Regulatory Information

TSCA Status: Listed or exempt
REACH Status: Not specifically listed; ensure compliance for use within EU
SARA Title III: Not listed as a reportable chemical
California Proposition 65: Not known to contain substances listed under Proposition 65
Other Regulations: Comply with all region-specific workplace safety, health, and environmental guidelines
Labelling Requirements: Include product name, hazard description, and manufacturer/distributor information on label