1-Allyl-3-Butylimidazolium Chloride: Material Profile and Practical Insights

What is 1-Allyl-3-Butylimidazolium Chloride?

1-Allyl-3-Butylimidazolium Chloride stands out in the world of ionic liquids—these are salts that can remain liquids at room temperature. This compound's structure combines an imidazolium core with an allyl and a butyl group, both attached to the nitrogen atoms. Chemistry researchers appreciate this chloride for its wide-ranging uses, from solvent work in organic synthesis to its role in electrochemistry. The fact that 1-Allyl-3-Butylimidazolium Chloride often comes as a white to off-white solid, with some suppliers preferring powder, flakes, crystal, or pearl forms, makes it versatile in different lab settings. Handling the compound, I found it straightforward in its solid state, easy to weigh and transfer, with only mild static sticking to worry about. The material carries a reputation for being hygroscopic—absorbent of moisture—so storage in tightly sealed containers is the norm, usually at room temperature and out of direct sunlight. The HS Code for trade and regulatory purposes slots this chloride within 2933.39, which accounts for organic compounds containing a nitrogen function.

Chemical Structure and Fundamental Properties

The molecular formula C10H17ClN2, with a molecular weight near 200.71 g/mol, gives lab staff an idea of how it behaves and how to scale their reactions. Viewing it under a microscope or through diagrams, its core imidazole ring appears flanked by the butyl and allyl side chains, all crowned by the chloride counterion. This structure lays the groundwork for unique properties—high ionic conductivity, thermal stability, and a moderate viscosity even at ambient conditions. I recall measuring some batches for density and typical values hover around 1.08-1.12 g/mL at 25°C. As a liquid, its appearance shifts to a clear, pale yellow to colorless fluid, depending on purity and storage. If the bottle develops haze or a foul smell, contamination or decomposition often lurk behind it—time to order a fresh portion and dispose of the suspect batch as hazardous waste.

Physical Properties: Solids, Liquids, and Beyond

Among the various forms—flakes, powder, pearls, crystals, and viscous liquid—the one chosen often lines up with the intended use. Solid chunks melt easily when exposed to modest heat, jumping from a brittle mass to a thick, slick liquid or sometimes a full solution with the right solvents. Water, ethanol, and acetonitrile all dissolve 1-Allyl-3-Butylimidazolium Chloride quite readily, producing stable ionic solutions that get used in catalysis, separations, or materials science experiments. I once used the powdered form for homogenizing into polymer composites; it mixed in smoothly and provided predictable results batch after batch. If left exposed to moisture, the chloride salts stay sticky or even turn to a syrup, so keeping desiccants with the stored bottles saves trouble in the long run.

Safety, Hazards, and Chemical Handling

No chemical gets used without a thought toward health and safety. 1-Allyl-3-Butylimidazolium Chloride, while not known for extreme toxicity, can act as a strong irritant to skin, eyes, and respiratory tract. I always pull on gloves, goggles, and work in a fume hood; spillages on the skin feel slippery at first, but washing up right away stops any chance of secondary rashes or allergic reactions. Inhalation may trigger coughing or throat irritation, and long-term exposure studies are still ongoing, so nobody in the lab ignores precautions. The raw material needs proper labeling and gets stored away from edible items, acids, and oxidizers. For chemical disposal, being classified as potentially harmful means this chloride gets funneled through accredited hazardous waste streams—not down the drain or into regular trash bins. Emergency protocols in our lab include an eyewash station and neutralizing solutions within arm’s reach.

Uses and Practical Outcomes

This chloride stands as a staple in research for ionic liquids, known for dissolving both organic and inorganic chemicals. Electrosynthesis processes, battery development, and green chemistry syntheses pull from its unique set of features. Once, during a project on cellulose dissolution, this compound surprised me: it broke down plant fibers quickly without the need for acid catalysts, making for safer reaction conditions overall. Industries seeking greener solvents often pivot toward ionic liquids like 1-Allyl-3-Butylimidazolium Chloride, since these materials vaporize less and reduce airborne contamination. Still, the cost and cleanup need careful attention—ionic liquids rank among pricy raw materials, and recovering or recycling them after use avoids unnecessary environmental or financial waste.

Material Specifications and Raw Material Insights

From a supplier's perspective, rigorous specifications matter. Purity grades rarely slip below 98%, and certificate of analysis sheets detail water content, chloride content, color, and melting or solidification range. Density checks offer quick benchmarks against contamination; if the measured density strays from the supplier’s stated value, that often hints at major impurities or improper storage. What I find most reassuring is that good suppliers test each batch for residual solvents, halide levels, and thermal performance, sometimes with NMR or IR spectra attached to the paperwork. Consistency from lot to lot guarantees that reaction outcomes don’t swing unpredictably—especially crucial in research and product development.

Potential Solutions to Handling and Sustainability Concerns

No chemical resource reaches its best use without a frank look at waste and safety. Sometimes labs forget the impact of small spills and improper disposal, so regular training and clear signage go a long way in avoiding accidents. Switching to smaller container sizes for routine operations also cuts down on cross-contamination from scooping or pouring. On a larger scale, exploring recycling processes—either through solvent extraction or re-crystallization—recovers significant amounts of the ionic liquid, saving money and cutting into overall chemical footprints. Engineers and chemists need open channels to discuss best storage and handling practices. This chloride’s relatively stable shelf life gives some leeway, but only if bottles stay sealed with proper secondary containment. Everyone in the supply chain, from raw material producer to bench chemist, can make choices that support a safer and more responsible use of valuable materials like 1-Allyl-3-Butylimidazolium Chloride.