1-Dodecyl-3-Methylimidazolium Chloride: Physical and Chemical Profile

What is 1-Dodecyl-3-Methylimidazolium Chloride?

1-Dodecyl-3-Methylimidazolium Chloride stands out as a unique ionic liquid with a growing reputation in chemistry labs and advanced material fields. This compound features an imidazolium ring attached to a 12-carbon dodecyl chain and a methyl group, coupled with a chloride anion. Recognizable by the formula C16H33ClN2, this chemical walks the line between traditional salts and organic solvents. Many research teams treat it as a valuable building block for innovations in catalysis, green chemistry, and surfactant science. Though it looks mild, this material transforms the performance of other substances when it enters the mix.

Chemical Structure

At the molecular level, the core carries an imidazolium cation with a single methyl group at position 3 and a long dodecyl chain at position 1. The cationic structure binds to a chloride anion, forming a solid or crystalline compound under room temperature conditions. Scientists working with the material refer to its arrangement: C16H33ClN2, molecular weight about 305.9 g/mol. Robust ionic interactions within the crystal lattice push up its melting point compared to many other organic molecules, while the long alkyl chain tunes solubility and surface properties.

Physical Properties and Appearance

The commercial and laboratory versions of 1-dodecyl-3-methylimidazolium chloride present as white to off-white flakes, sometimes as a solid powder or crystalline granules. This wide range, including pearls or even moist flakes, stems from hydration levels and manufacturing tweaks. Densities hover near 0.98 g/cm3, and while it resists easy dissolution in nonpolar solvents, it dissolves smoothly in water and many polar systems. Rarely found as a true liquid under room conditions, heating shifts the solid into a more flowable molten state—a hallmark of many ionic liquids. Bulk shipments arrive in drums or bags, often by the kilogram or liter for specific solution applications.

Key Properties and Applications

The substance’s high surface-active potential sets it apart from traditional surfactants. With its amphiphilic nature—the dodecyl tail likes oil, and the charged head loves water—it bridges polar and nonpolar phases efficiently. Many industries use it as an emulsifying agent, antistatic additive, or precursor for custom materials. Researchers prize it in the design of functional membranes, as a medium for metal ion separation, and even as a template for nanostructured materials. Analytical scientists deploy it for tuning chromatography selectivity, owing to its tailored charge and hydrophobic balance.

Specifications and Material Details

Quality control demands clear benchmarks for purity and form. Standard purity levels exceed 98%, ensuring minimal byproducts interfere with reactions. Flake, powder, crystal, and pearl forms all trace to the same molecular backbone, though some applications prefer one texture over another. The chemical needs storage in tight, moisture-proof containers to prevent clumping and hydrolysis. No matter the form, every batch comes tagged with an HS Code—typically 2925299090—aligning with international chemical tracking guidelines. Laboratories and industrial plants require certificates of analysis, covering melting range, density, and absence of hazardous contaminants like halogenated byproducts or color-forming impurities.

Safety, Hazards, and Handling

Anyone working with this compound should know it doesn’t act as a benign salt. Like many surfactants and ionic liquids, skin or eye contact triggers irritation. The cationic surfactant portion and chloride ions mean proper gloves, goggles, and dust control remain a must in labs and manufacturing spaces. Inhalation or repeated skin exposure can cause harm, so good ventilation and fume hoods help protect against splashes and dusty spills. Though not classified among the highly toxic class, the substance still falls under “harmful” if mishandled or used carelessly. Disposal demands chemical waste bins—never down the drain—given the risks to aquatic life from surface-active agents.

Raw Material Origins and Molecular Design

To produce 1-dodecyl-3-methylimidazolium chloride, chemical plants start with simple imidazole rings, react them with methylating agents, and cap with long-chain alkyl halides. Each step requires careful temperature control and reactant balance, else unwanted byproducts or incomplete chains slip through. The choice of raw materials, from high-purity imidazole to technical-grade dodecyl chloride, plays a huge role in the final quality of the ionic liquid. Structural tweaks on the alkyl chain or the methyl group let researchers create related liquids with custom melting points or unique solvent behavior.

Environmental and Regulatory Perspectives

Chemists pushing for greener technology pay attention to the environmental impact of their materials. The chloride version of this imidazolium compound brings both promise and caution—it breaks down slower than traditional surfactants but often delivers better efficiency at lower dosages. Regulatory agencies connect its HS Code and molecular profile to risk assessments and safe handling standards. Strong support for greener alternatives comes with the recommendation that any waste streams involving these ionic liquids go through controlled treatment rather than general release. Industrial users must follow national and regional chemical control lists to avoid violations and ensure worker safety.