1-(Ethoxycarbonyl)Methyl-3-Methylimidazolium Bis(Trifluoromethylsulfonyl)Imide: Everyday Chemistry with Real-World Consequences

What Is 1-(Ethoxycarbonyl)Methyl-3-Methylimidazolium Bis(Trifluoromethylsulfonyl)Imide?

1-(Ethoxycarbonyl)Methyl-3-Methylimidazolium Bis(Trifluoromethylsulfonyl)Imide comes up often in laboratories focused on research around ionic liquids and advanced chemical materials. The long name says a lot about the structure, but to break it down for practical understanding: this compound features a core of imidazolium, known for its stability, tweaked by an ethoxycarbonyl group tied to a methyl side chain. Its partner, bis(trifluoromethylsulfonyl)imide, brings in strong electron-withdrawing trifluoromethyl groups, which influence both the liquid's resistance to break down and its interactions with other substances. To someone who's worked in a lab, just the mention of this dual nature—an organic cation matched to a large, non-coordinating anion—signals a pathway to unique chemical properties.

Products, Structure, and Properties

People new to this compound tend to notice its physical state first. Depending on the batch and purity, it can appear as white to off-white flakes or powder, sometimes sold as crystalline pearls, or even dissolved as a concentrated liquid solution for laboratory convenience. The molecular formula, C11H15F6N3O5S2, packs quite a punch on the periodic table. Its crystalline structure can be confirmed by X-ray diffraction, and that structure underpins its resistance to high temperatures, low volatility, and remarkable solubility in polar organic solvents. Most lab folks handling this look for its ability to stay stable under a variety of temperatures and not change form easily.

Density makes a real difference in lab applications, and you'll find solid samples measured at somewhere between 1.39 and 1.45 g/cm3. It doesn't act like your average salt in water: these ionic liquids bring low vapor pressure, almost no measurable smell, and a high boiling point, outlasting many common organic solvents on the hotplate. These traits stem from its imidazolium ring and the heavy, fluorinated imide counterion, which together resist decomposition and repel unwanted moisture—hugely valuable for sensitive chemical syntheses or battery research.

Specifications and Practical Information

Manufacturers ship this material by weight, listed in grams or kilograms, sometimes dissolved in solution packed in glass bottles to keep the atmosphere out. Purity specifications reach 99% for research-grade supply, and quality control involves measureable water content (Karl Fischer method) and a cut on halide impurities. As a raw material, researchers use this ionic liquid for electrochemical studies, as a solvent for polymer electrolytes, or as a specialty medium for catalytic reactions. While some people try to name each new ionic liquid a "designer solvent," in hands-on lab work this one offers a balance between chemical resistance, thermal stability, and ionic conductivity.

Safe, Hazardous, and Harmful Qualities

Practical matters guide safety decisions. The bis(trifluoromethylsulfonyl)imide group grants the compound high chemical inertness, but I always check the relevant safety data before working with it. Some ionic liquids may get hyped as "green solvents" because they don’t evaporate, but no one should rush to pour them down the drain. Prolonged contact with the skin or mucous membranes can be harmful, and there's a risk of eye or respiratory irritation if fine dust disperses in air. Storage needs consistent, cool, dry conditions, out of sunlight and away from open flames, even if the compound isn’t flammable in the usual sense. Gloves and goggles give peace of mind. The long-term effects of many ionic liquids on health and environment still require more unbiased studies. I trust the hazardous material symbols: the HS Code for this substance—often 2933.99 on international customs listings—flags it as a chemical for controlled handling.

Why This Compound Matters Beyond the Lab

It’s easy to get lost in the alphabet soup of molecular names, but the character of 1-(Ethoxycarbonyl)Methyl-3-Methylimidazolium Bis(Trifluoromethylsulfonyl)Imide matters far outside narrow research groups. It shows up in research projects aimed at safer lithium-ion batteries, advanced supercapacitors, and greener industrial reactions where toxicity and evaporation rates of old-fashioned solvents matter more than ever. My own work included testing new battery electrolytes and realizing how the slow fade of capacity often traced back to impurities the old solvents allowed, not to mention accident risks from flammable chemicals. This ionic liquid lowers those risks, and the industry’s pivot toward less hazardous, higher-performing alternatives relies on these advances.

Possible Solutions and Ways Forward

Continued reliance on potentially harmful raw materials poses a challenge for people who work with chemicals every day. Manufacturers can invest in even purer grades and transparent safety protocols. Labs can improve ventilation and training so exposure stays minimal. Governments and academic groups need to keep sharing research on environmental breakdown products, making sure solutions touted as “safe” actually hold up in field studies. I’ve seen missed opportunities in the past, where promising materials got sidelined by unaddressed health concerns, only for safer versions to arise after more data. Everyone wins when research follows that cautious optimism—pushing ahead but checking each step carefully. For now, keeping up with evolving findings about the long-term impact of trifluoromethyl groups and their fate in the environment grows more important each year.