1-Octodecyl-3-Methylimidazolium Bromide: Description, Properties, and Practical Insights

What is 1-Octodecyl-3-Methylimidazolium Bromide?

1-Octodecyl-3-methylimidazolium bromide stands out in the world of specialty chemicals with its imposing structure and unique set of physical traits. Recognized by its IUPAC name and commonly classified under ionic liquids, this compound combines an imidazolium core methylated at the third position and an octodecyl group extending eighteen carbons on the first nitrogen. The presence of a bromide counterion contributes to its chemical reactivity, solubility, and interaction within a variety of environments, both organic and aqueous.

Chemical Structure and Formula

The structural backbone of 1-Octodecyl-3-methylimidazolium bromide centers around C22H45BrN2. Its molecular formula illustrates a hefty alkyl side chain matched with the robust imidazolium cation, widely employed in ionic liquid chemistry. Chemists appreciate this molecule for its balance between hydrocarbon length and water dissociation potential. The imidazolium core brings stability, while the elongated octodecyl group adds hydrophobic character and surface activity, opening doors in phase transfer catalysis, surface modification, and green chemistry.

Physical Properties: Appearance, Density, and Forms

Witnessing 1-Octodecyl-3-methylimidazolium bromide in a lab, the material often appears as white or off-white flakes, powder, or as pearls depending on how it’s processed or stored. It can crystallize under appropriate cooling conditions, giving way to easily handled solid granules. Density sits around 1.06 g/cm3 at 25°C, which means it weighs roughly as much as water while being far less volatile. In practice, this makes the compound manageable from storage to synthesis, as it avoids sticking and unwanted clumping. Its melting point is typically above room temperature, which engineers and formulators prefer when stability is key. Practically, converting it into a liter of solution, the ionic liquid blends into water or polar solvents, creating a translucent medium for further processing.

Raw Material and Sourcing

Viewed as a specialty raw material, 1-Octodecyl-3-methylimidazolium bromide emerges from a reaction between 1-methylimidazole and 1-bromooctadecane. The synthesis takes care, as using impure reactants leads to inconsistent product properties, which downstream industries cannot afford. Its reach spreads from the world of surfactants and emulsifiers to catalysis, nanomaterials, and even solar cell construction. Recent years show growing demand as more scientists hunt for alternatives to volatile organic solvents, choosing ionic liquids for their safer and greener profile. From my work with mixed surfactant systems, plenty of traditional materials failed to keep dispersion stable, but this imidazolium salt offered lasting results with minimal additive interference.

Product Specifications and HS Code

Chemicals like this require strict specifications, especially relating to purity, moisture content, and particle size. The accepted purity for advanced research is 98% or above, limiting random byproducts that reduce performance in sensitive applications. Trace metals, organic residues, and water are tightly controlled, since ionic liquids like this are sensitive to impurities, which impact everything from conductivity to reactivity. The harmonized system (HS) code helps customs and logistics teams keep shipments smooth; typically, this molecule falls in the 2921 group for quaternary ammonium salts, though local regulations might detail it further. Sourcing from reliable suppliers often prevents delays, as one mishandled shipment of a hazardous or harmful chemical halts production across continents.

Safety, Hazards, and Handling

This compound's safety profile remains under review, but general experience shows a need for caution. Skin irritation and eye contact issues lead to policies mandating gloves and goggles among lab workers, as with many bromide salts. Dust can trigger respiratory irritation, so working under a fume hood always helps. Chronic exposure data is still being gathered; from what’s available, minimizing inhalation and direct skin contact is best practice. Material safety data sheets recommend storing solid, flake, powder, or pearl forms in airtight containers away from strong oxidizers and moisture. Unintentional spills call for careful collection—ionic liquids might harm aquatic environments or prove tough to remediate if released. While regulations around shipping dangerous goods require hazard labeling, smart engineering controls and routine PPE often keep teams safe.

Applications and Industry Impact

1-Octodecyl-3-methylimidazolium bromide's primary draw relates to its surfactant and phase transfer capabilities. As industries move toward greener processes, ionic liquids continue to displace volatile organics in solvents and specialty reagents. This trend runs strongest in chemical and pharmaceutical manufacturing, where handling losses and off-gassing matter for both cost and worker well-being. My collaborations with formulation teams show the value of ingredients that bring both stability and functionality—this compound's surface tension reduction and emulsifying power build emulsions and dispersions no routine surfactant manages. Its solid and powdered forms let operators dose with accuracy, and those pearls or crystal variants simplify weighing without raising dust levels.

Solutions and Future Directions

Reliance on safe handling and reliable sourcing helps organizations avoid pitfalls—constant training, redundant packaging, and shared material safety data all help. On a broader scale, communication between chemical producers, regulatory bodies, and end users bridges the gap from scientific research to industrial reliability. Developing eco-friendlier raw materials builds momentum toward sustainability goals, and engineered purities with batch-to-batch consistency give end users confidence. For teams looking to use 1-Octodecyl-3-methylimidazolium bromide, detailed documentation and supply-chain transparency often head off surprises, so expect strong relationships to matter more as this field expands.