1-Propylsulfonic-3-Ethylimidazolium Inner Salt: Structure, Properties, and Safe Handling

What is 1-Propylsulfonic-3-Ethylimidazolium Inner Salt?

1-Propylsulfonic-3-Ethylimidazolium Inner Salt draws interest among chemists for its layered composition as an organic salt where the ethylimidazolium cation bonds to a propylsulfonate anion in a single molecular structure. Bringing together hallmark features of imidazolium-based ionic compounds and sulfonic acid derivatives, its value stretches across diverse chemical processes. As a raw material, it shows potential for catalysis, ion exchange, and organic synthesis, each relying on stable ionic frameworks and the distinctive behavior offered by sulfonic acid groups firmly attached to the imidazolium ring. The underlying innovation here takes root in combining both hydrophobic and hydrophilic properties into a single molecule, advancing practical applications in modern chemistry.

Chemical Structure and Properties

Looking at the molecular structure, the salt carries the backbone of 1-propylsulfonic acid fused to a 3-ethylimidazolium ring, forming an inner salt where the sulfonate group closes the charge loop with the imidazolium. Its molecular formula, C9H16N2O3S, and molecular weight around 232.3 g/mol reflect relative simplicity beside other ionic liquids. The structural design grants it high polarity and robust solubility in water and select polar solvents, powering efficient mixing in laboratory and industrial settings. Solid forms like powder, flakes, pearls, and crystalline material come from this tight ionic packing, offering a range of tactile feels from gritty powder to glassy crystal. Density typically hovers between 1.2 to 1.35 g/cm³, depending on temperature and moisture content, quite dense for an organic ionic compound. Since the structure avoids extended aromaticity, the chemical stays stable in acid-base shifts, ideal where shifts in pH would destabilize less robust molecules. Its melting point often occurs between 80-110°C, making it solid at room temperature but easy to work with under moderate heating.

Physical Characteristics and Forms

Users find 1-Propylsulfonic-3-Ethylimidazolium Inner Salt as colorless to slightly yellow flakes, crystalline powders, small pearls, or granular solids, each supporting specific handling methods. Liquid solutions have been prepared with a density close to that of water, and this flexibility as a stock solution or as a direct-use solid expands its toolkit role. Handling density by liter remains critical in scale-up, especially when monitoring solution concentration for process accuracy. The physical state selected—fluffy powder, compacted flake, free-flowing pearls—balances comfort for the operator with high reactivity for the chemist, since surface area changes reaction speed and product purity. High purity usually comes with careful manufacturing controls, and visual clarity in crystals often signals fewer impurities, reassuring researchers or quality teams tracking batch-to-batch consistency.

Product Specifications and HS Code

In international shipping, regulatory bodies assign the Harmonized System (HS) Code based on chemical class and intended use. For 1-Propylsulfonic-3-Ethylimidazolium Inner Salt, classification often depends on its function as an organic salt, with codes generally tracing to specific families of sulfonic acids or imidazolium derivatives. Proper code assignment improves transparency on origin, regulatory requirements, and customs handling, a real concern for global trade. Documented product specifications shy away from ambiguous purity claims, focusing instead on grade, moisture level, melting point, solubility, particle size, and trace impurity thresholds, each listed on an up-to-date certificate of analysis. Reliable suppliers publish these regularly, keeping safety and product performance front and center.

Safety, Hazards, and Responsible Use

Handling chemicals with sulfonic acid groups calls for respect and training, as their reactivity brings both opportunity and risk. 1-Propylsulfonic-3-Ethylimidazolium Inner Salt, in particular, tends to non-volatile low-toxicity profiles when used with gloves and eye protection in ventilated spaces. Direct skin or eye exposure can lead to irritation, owing to the salt’s acidity and ionic power. Breathing dust over extended periods remains a risk, and inhalation should be avoided with dust masks or respirators when transferring powders or blending solutions. Spill management calls for water and absorbent material disposal as per local chemical hygiene plans, never drain disposal unless approved for biodegradability. Fire risk stays low given the absence of flammable organic groups, but heating above set decomposition points may evolve hazardous gases, making fume hoods and fire extinguishers important during thermal treatments. Waste streams from synthesis or cleaning should be treated as hazardous, staged in labeled secondary containers until qualified waste contractors verify safe neutralization or incineration. Anyone with allergies or respiratory conditions benefits from closed setup handling and proper PPE.

Applications and Raw Material Sourcing

This imidazolium inner salt keeps showing up in research labs and pilot plants as a solid acid catalyst, supporting esterification, alkylation, and resin synthesis, thanks to the wealth of protons on its sulfonic side chain. Its ionic character dissolves and transports charges, making it valuable as an electrolyte or as an ion-exchange medium. Sustainable manufacturing companies favor it since the chemical avoids heavy metals and supports efficient, high-yield reactions. The raw materials for its synthesis—imidazoles, sulfonic acid sources, primary alkyl bromides—travel from industrial chemical supply chains, each batch tracked for trace impurities, supplier certifications, and batch integrity. Responsible sourcing means full documentation on safety, environmental footprint, and end-of-life disposal pathways. Using this salt for green chemical transformations reduces the load of corrosive mineral acids and supports the industry’s push for mild, selective, and robust catalytic systems.

Potential Concerns and Solutions

Major hurdles stem from operator safety, environmental impact, and regulatory compliance. Worker safety stays at the front, with training for correct PPE, spill cleanup, and first aid responses written into standard operating procedures. Environmental agencies ask for lifecycle analysis, tracking fate from raw material all the way to post-reaction waste, highlighting ways to reuse or recycle rather than landfill. Regular audits and environmental monitoring help companies spot leaks or exposure before harm builds up. Digital inventory systems flag any incoming lots with overdue certifications or unexpected impurity levels, locking usage until corrective action. For end users, easy-to-understand pictograms, clear hazard statements, and open access to updated safety data sheets make informed handling the norm, not the exception. Peer groups in industry and research communities encourage the sharing of near-misses and best practices, keeping everyone a little safer, more efficient, and ahead of shifting regulations on chemicals of emerging concern.