N-Ethylimidazolium Bis(Trifluoromethylsulfonyl)Imide: Product Description, Structure, and Practical Considerations

What is N-Ethylimidazolium Bis(Trifluoromethylsulfonyl)Imide?

N-Ethylimidazolium Bis(Trifluoromethylsulfonyl)Imide belongs to the growing family of ionic liquids. Its chemical fingerprint, C7H11F6N3O4S2, marks off a compound where N-ethylimidazolium stands as the cation and bis(trifluoromethylsulfonyl)imide as the anion. With these long chemical names, the substance looks complicated, but its structure boils down to a simple principle: an organic salt that stays liquid at room temperature or below, skipping the usual boundaries of salts. This property puts it in a class by itself, opening up doors in electrochemistry, catalysis, and material science where dryness, temperature stability, and ionic conductivity carry weight.

Physical Properties, Appearance, and Key Data

In the jar or bottle, N-Ethylimidazolium Bis(Trifluoromethylsulfonyl)Imide usually shows up as a colorless or faintly yellow liquid, sometimes semi-viscous, though it can also appear in solid forms such as flakes, powder, pearls, or crystalline chunks, depending on ambient temperature and moisture. Density hovers around 1.45 – 1.52 g/mL at 25°C, a figure that surpasses water, which gives you an immediate sense for the mass packed into this material. Common packaging includes small jars, drums, or sealed ampoules, ranging from milliliters and grams up to multi-liter scales for industrial users. Its melting point sits below standard room temperatures, often near or below zero Celsius, so it may pour like syrup even on cold mornings. The material shines under an NMR, and FTIR spectra will read clear signals for its imidazolium ring and the striking bis(trifluoromethylsulfonyl)imide component, giving chemists confidence in batch consistency.

Chemical Structure and Molecular Formula

The backbone of N-Ethylimidazolium Bis(Trifluoromethylsulfonyl)Imide includes a fused imidazolium ring—nitrogen and carbon linked in a five-membered aromatic loop, with an ethyl group bonded to one nitrogen. The anion, bis(trifluoromethylsulfonyl)imide, draws attention with two CF3SO2− groups attached to a bridging nitrogen. Structural diagrams show strong charge separation, driving solubility in polar and some non-polar solvents. Hydrogen bonds don’t form as easily here as in water-based salts, and it’s not flammable, which wins points for lab safety. Yet, its fluorinated side groups offer thermal resilience up to 300°C before breakdown. That means this ionic liquid can handle demanding synthetic environments without falling apart.

Applications in Industry and Science

Chemists who work with electrochemical cells or energy storage recognize the value in N-Ethylimidazolium Bis(Trifluoromethylsulfonyl)Imide. In my experience with research on ionic liquids, materials like this lower the risk of side reactions and make for safer, more efficient batteries and supercapacitors. Pharmaceutical chemists use it to develop greener routes for chemical separations, since volatility is extremely low—no strong smells, no rapid evaporation, and no cloud of hazardous vapor during use. Laboratory reports show high ionic conductivity, making it reliable in high-voltage and sensor projects, while thermal stability lets engineers substitute it in environments where organic solvents would catch fire or react. Its ability to dissolve a range of organic or inorganic materials—salts, organic compounds, polymers—means more flexibility in designing reaction systems with fewer byproducts or environmentally hazardous waste.

Specifications and Storage

N-Ethylimidazolium Bis(Trifluoromethylsulfonyl)Imide often arrives with a minimum purity of 98% or higher, checked by GC, NMR, and water content below 100 ppm for high-end applications. The HS Code for trade and customs generally falls under 2933999099 for organic nitrogen compounds, although some countries use variations based on granular or liquid form. Packaging requires air-tight containers, since trace water can change the melting point and affect conductivity. In the warehouse, storing it away from acids, bases, and oxidizers keeps its chemical stability intact, and dry environments maintain low water uptake. While the compound shines for durability, standard practice involves gloves, goggles, and chemical fume hoods during ranging from gram-scale synthesis to bulk handling. Spill cleanup stays straightforward because of its low vapor pressure, but contact with the skin should be avoided, since ionic liquids can irritate on prolonged exposure.

Safety, Hazards, and Environmental Impact

Concerns about safety usually start with the chemical’s low toxicity, but handling protocols need respect. N-Ethylimidazolium Bis(Trifluoromethylsulfonyl)Imide is classified as a chemical material with signals for skin and eye irritation on direct contact, and ingestion should never occur. Studies show it does not release fumes at typical working temperatures, and the risk of flammability or explosion stays very low due to its ionic nature. On the environmental front, ionic liquids like this do not break down rapidly in soil or water, so disposal through incineration or licensed chemical waste routes makes for best practice. Discussions in chemistry circles keep circling back to the need for greener routes to manufacture such salts and plans for safe reuse or recycling. I've seen push-back from researchers who want all the thermal and electrochemical advantages without increasing ecological burden, and the push to develop new, biodegradable ionic liquids will likely change the product lineup over time.

Raw Materials, Sourcing, and Future Outlook

Manufacture of this chemical draws from basic organic building blocks, including imidazole, ethyl halides, and reagents for the trifluoromethylsulfonyl group. Production remains centralized in specialty chemical plants with strict quality oversight, and raw material sourcing focuses on purity to avoid metal or halide residue that could interfere with sensitive electrochemical tests. Price trends follow demand in electronics, battery research, and specialty synthesis. Efforts from both academia and industry keep pushing research into less costly production methods, waste reduction, and new applications—especially as governments press for sustainable materials in energy storage and sensors. Personal experience working within collaborative materials chemistry groups shows the greatest leaps come from sharing data and testing new recipes, not just pushing existing molecules harder. Future versions of N-Ethylimidazolium Bis(Trifluoromethylsulfonyl)Imide may see better biodegradability, recyclability, or tuning for specific high-tech demands, echoing a broader shift in the chemicals market toward safety, sustainability, and efficiency.