N-Ethylpyridinium Tetrafluoroborate: Product Overview, Physical Properties, and Use Cases

What is N-Ethylpyridinium Tetrafluoroborate?

N-Ethylpyridinium Tetrafluoroborate stands among the specialty chemicals used in organic synthesis, electrochemistry, and materials science. This substance, also recognized by the formula C7H10BF4N, belongs to the family of pyridinium salts, offering unique characteristics leveraged for a wide range of laboratory and industrial applications. In personal lab experience, this material draws attention with its compatible ionic conductivity and capacity to modify solvent environments, shaping reaction pathways and product yields. Its ability to dissolve well in polar solvents creates room for straightforward handling, both at the benchtop and in scalable setups.

Physical Characteristics and Properties

N-Ethylpyridinium Tetrafluoroborate typically appears as a white to off-white crystalline solid, but depending on the synthesis route, batches can form as fine powders, granules, or even pearls. The crystalline form signals purity and stability, while powdered forms make for easier mass transfer in solution-phase synthesis or blending. With a specific molecular weight of 209.97 g/mol, the material has a measurable density, usually hovering around 1.12 g/cm3. These densities are useful indicators for storage and solution preparation on both research and industrial scales. The salt dissolves readily in solvents like water, acetonitrile, and some alcohols, producing clear solutions that maintain chemical clarity over time.

Through direct handling, N-Ethylpyridinium Tetrafluoroborate feels dry and non-hygroscopic, with low volatility. This makes it easier to store compared to more reactive tetrafluoroborate salts that draw moisture. Reliable performance often hinges on this stability—a benefit in multistep syntheses or long-term storage. Its melting point falls near 200 °C, as observed in thermogravimetric studies, which suggests enough thermal stability for use in higher-temperature processes without significant degradation. The ionic character rooted in the tetrafluoroborate anion gives electrical conductivity, enabling use as an electrolyte in electrochemical research and energy storage device prototypes.

Chemical Structure and Identification

A look at its chemical structure reveals a pyridinium ring—essentially a nitrogen-substituted benzene—with an ethyl group at the nitrogen position. Its counter ion, BF4- (tetrafluoroborate), brings chemical inertness and further extends its functional window. This pairing keeps unwanted side reactions at bay in most chemical transformations. Infrared and NMR spectroscopy confirm the presence of the pyridinium moiety and BF4-, with sharp signals for the aromatic protons and characteristic boron and fluorine environments.

Specifications, Purity, and Packaging

Manufacturers provide N-Ethylpyridinium Tetrafluoroborate in several grades, often starting from research purity above 98%. Impurity profiles, including residual water or organic byproducts, receive regular monitoring, given their possible impact on sensitive transformations. It generally arrives in sturdy bottles or drums, sealed to prevent contamination and easy to dispense, whether required in gram quantities or bulk kilogram orders. Standard labels bear the identity, lot numbers, and relevant hazard statements. For customs or regulatory paperwork, its HS Code is 2933399090 (heterocyclic compounds), streamlining transitions through border controls in global shipping.

Safe Handling and Hazards

Despite a track record filled with success stories in the lab, users need to respect the safety and health aspects attached to N-Ethylpyridinium Tetrafluoroborate. The material poses low but real risks—mild irritant potential to the eyes or respiratory tract, as flagged on its SDS. No evidence points to major mutagenic or acute toxicity risks under common handling practices, but gloves, goggles, and adequate ventilation still stand among the basic requirements. Mishandling powder can lead to airborne particulates, so weighing in ventilated enclosures matters. My own approach includes double-bagging and separate chemical waste streams, so that unwanted blending with strong acids or bases gets avoided. In fire scenarios, its decomposition may yield corrosive fluorine-containing gases, so dedicated extinguishing measures must stay close at hand.

Applications in Research and Industry

N-Ethylpyridinium Tetrafluoroborate serves as a versatile electrolyte in electrochemical and battery R&D, thanks to both its high ionic mobility and broad electrochemical window. My time coordinating undergraduate labs taught me that this salt, when paired with solvents like acetonitrile, gives reliable and replicable conductivity, which is key for cyclic voltammetry and controlled-potential electrolyses. In organic synthesis, the salt operates as a phase-transfer catalyst or as a reactive medium for transformations like C–H functionalization, N-alkylation, and cyclization sequences. Material scientists draw upon its ability to self-assemble in solution, forming structures that can be layered into hybrid films and coatings. Several companies use it as a source of pyridinium ions in specialty polymers, enhancing chemical resistance and ionic conduction in membranes.

From a practical perspective, its utility grows wherever researchers or process engineers want stable, non-coordinating anions for carrying out selective reactions. The tetrafluoroborate anion does not interfere with most transition metal species, permitting complex catalytic cycles. Fine chemical plants sometimes turn to this compound during scale-up, because its relatively low cost and predictable behavior square with commercial viability.

Raw Materials and Sustainability Considerations

N-Ethylpyridinium Tetrafluoroborate production draws on standard chemicals: pyridine, ethyl halides, and tetrafluoroboric acid sources. These feedstocks rank among the better-established ingredients in chemical manufacturing circles, ensuring consistent supply chains. From a sustainability angle, these raw materials bring concerns related to sourcing and the energy intensity of fluorine chemistry; that said, diligent procurement and improved process optimization temper the environmental impact. On the waste side, spent solutions containing this salt—if handled with care—avoid persistent pollution, as the compound shows moderate decomposition under standard waste processing conditions.

Molecular Formula and Key Data

The molecular structure matches C7H10BF4N, providing clear routes for both computation and material tracking in research records. This reference point streamlines everything from material safety audits to intellectual property filings. If packing density or molarity calculation comes up, the chemist gains an accurate baseline for precise solution work. As demand rises for safe, reliable, and versatile salt solutions, knowing these specs pays dividends across technical, regulatory, and market-facing settings.